Provided is a method of producing a sulfide solid electrolyte which brings low costs, and large sulfur reducing effect, the method comprising heat-treating material for a sulfide solid electrolyte at a temperature no less than a melting point of elemental sulfur while vibrating the material.

A method for producing sulfide-based glass ceramics including crystallizing a glass solid electrolyte, wherein the glass solid electrolyte includes: sulfide-based glass comprising at least a sulfur element and a lithium element; and a nitrile compound incorporated into the sulfide-based glass.

Provided are a method for producing a sulfide solid electrolyte having a high Li ion conductivity, in which the production time can be greatly reduced, and a sulfur-based material that can be used in the production method for a sulfide solid electrolyte. The invention relates to a method for producing a sulfide solid electrolyte containing a lithium element, a sulfur element, a phosphorus element, an iodine element and a bromine element, which includes mixing and grinding lithium sulfide and lithium bromide followed by adding phosphorus sulfide and lithium iodide thereto and reacting them, and relates to a sulfur-based material.

Gradient refractive index (GRIN) materials can include multi-phase composites having substances with differing refractive indices disposed non-uniformly within one another. Particular glass composites having a gradient index of refraction can include: an amorphous phase, and a phase-separated region disposed non-uniformly within the amorphous phase. The glass composites include a mixture containing: GeZ.sub.2 and A.sub.2Z.sub.3 in a combined molar ratio of about 60% to about 95%, and CsX and PbZ in a combined molar ratio of about 5% to about 40%, where A is As, Sb or Ga, X is Cl, Br or I, and Z is S or Se. When A is As, the glass composites include PbZ in a molar ratio of about 15% or less. The amorphous phase and the phase-separated region have refractive indices that differ from one another. More particularly, A is Ga or As, X is Cl, and Z is Se.

The present invention provides an infrared-transmitting glass that is a chalcogenide glass, has a reduced Ge content, can sufficiently cover atmospheric windows, is free from highly toxic elements, such as Se and As, and is suitable for mold forming. Specifically, the present invention provides an infrared-transmitting glass suitable for mold forming, comprising, in terms of molar concentration: 0 to 2% of Ge, 3 to 30% of Ga, 10 to 40% of Sb, 45 to 70% of S, 3 to 30% of at least one member selected from the group consisting of Sn, Ag, Cu, Te, and Cs, and 0 to 30% of at least one member selected from the group consisting of Cl, Br, and I.

To provide an infrared transmitting glass that is easy to vitrify, has excellent thermal stability, and can achieve desired optical properties. An infrared transmitting glass contains: in mol %, from 25% to 90% of S+Se+Te, from 0.1% to 30% of Sn, from 0.1% to 15% of Ag, and from 1% to 30% of Ge+Sn, in which (Ge+Sn)/(S+Se+Te) is 0.3 or less.

A solid electrolyte glass at least including: at least one alkali metal element; a phosphorus (P) element; a sulfur (S) element; and one or more halogen elements selected from I, Cl, Br and F; wherein the solid electrolyte glass has two exothermic peaks that are separated from each other in a temperature range of 150 C. to 350 C. as determined by differential scanning calorimetry (in a dry nitrogen atmosphere at a temperature-elevating speed of 10 C./min from 20 to 600 C.).

A solid electrolyte glass at least including: at least one alkali metal element; a phosphorus (P) element; a sulfur (S) element; and one or more halogen elements selected from I, Cl, Br and F; wherein the solid electrolyte glass has two exothermic peaks that are separated from each other in a temperature range of 150 C. to 350 C. as determined by differential scanning calorimetry (in a dry nitrogen atmosphere at a temperature-elevating speed of 10 C./min from 20 to 600 C.).

A method for producing a sulfide glass ceramic, including reacting a lithium compound, a phosphorus compound and a halogen compound in a solvent that contains a hydrocarbon and an ether compound to produce a sulfide glass that contains a Li element, a P element, a S element and one or more halogen elements, and heating the sulfide glass to produce a sulfide glass ceramic.

Provided is a glass production method that can suppress devitrification of glass and increase the productivity of the glass. A glass production method according to the present invention includes the steps of: pouring a melt 11 obtained by melting a raw material of a glass 18 into a mold 13; and cooling the melt 11 to obtain the glass 18, wherein the mold 13 has a bottom surface 14a and a side surface 15a and, in the step of cooling the melt 11, the mold 13 is cooled from a direction of the bottom surface 14a.