A curable glass coating composition including 5-70 wt % aliphatic polycarbonate diol, 5-60 wt % crosslinker, 1-20 wt % extender, 4-20 wt % fatty alcohol, and 2-30 wt % crystalline or amorphous powder filler material, and optionally 2-20 wt % aliphatic polyester polyol and 2-20 wt % cycloaliphatic epoxy. The coating composition can be applied to a glass substrate and cured to form a decorative cured polyurethane coating layer on the substrate that has improved caustic and UV resistance.

The present invention is directed to a method of inkjet printing an image on a glass container comprising the steps of: a) manufacturing a glass container having a CEC layer; b) removing at least part of the CEC layer to a level wherein the remaining CEC layer has a thickness of less than 20 nm by washing the CEC from the glass container with an aqueous solution containing nonionic surfactant, rinsing with water and blowing the water from the container by means of a pressurized air stream, c) inkjet printing an image on the glass container.

The present invention is directed to a method of inkjet printing an image on a glass container comprising the steps of: a) manufacturing a glass container having a CEC layer; b) removing at least part of the CEC layer to a level wherein the remaining CEC layer has a thickness of less than 20 nm by washing the CEC from the glass container with an aqueous solution containing non-ionic surfactant, rinsing with water and blowing the water from the container by means of a pressurized air stream, c) inkjet printing an image on the glass container.

A coated glass article includes a glass article comprising a glass having a surface. The surface has an adhesion promoting region comprising a nanostructure formed at the surface of the glass. The adhesion promoting region is constructed of materials that are the same as one or more constituents of a glass composition of the glass. The coated glass article further includes a coating disposed on the adhesion promoting region formed at the surface of the glass. The coating incudes one or more polymer coating materials. The adhesion promoting region improves adhesion of the coating to the glass while also eliminating the use of titania or other adhesion promoting compounds that can adversely affect the optical properties of the coatings.

The present invention relates to a method for marking a container comprising at least a transparent wall comprising the following steps: a) applying at least one spot of ink on an outer surface of said transparent wall, b) heating said transparent wall, c) engraving a data matrix in the spot of ink of said transparent wall. The invention also relates to a marked container and to a method for identifying such a marked container.

This disclosure describes substrate(s) having a three-dimensional (3D) feature formed thereon and methods of forming the features. One method involves applying a first layer of UV-curable material on a surface of the glass container around a circumference of the container and curing the first layer of UV-curable material to produce a first cured material layer that forms at least a portion of a first 3D feature. The method further comprises applying a second layer of UV-curable material on the surface of the glass container, spaced apart from the first 3D feature, around the circumference of the container, and curing the second layer of UV-curable material to produce a second cured material layer that forms at least a portion of a second 3D feature. The portion of the glass container between the first and second 3D features has a circumference less than that of the first or second 3D features.

The present invention is directed to a glass container having an outer glass surface with an inkjet printed image provided on said surface, characterized in that an at least partially water soluble CEC with a thickness from 0.002 to 10 micrometer is present between the outer glass surface and the inkjet printed image.

Such glass container is preferably a one-way beverage bottle.

In addition, the present invention is directed to a method of inkjet printing an image on a glass container comprising the steps of: a) manufacturing a glass container having an at least partially water soluble CEC layer with a thickness from 0.002 to 10 micrometer, b) inkjet printing an image on the glass container.

Disclosed herein are delamination resistant glass pharmaceutical containers which may include an aluminosilicate glass having a Class HGA 1 hydrolytic resistance when tested according to ISO 720-1985 testing standard. The glass containers may also have a compressive stress layer with a depth of layer of greater than 25 μm. A surface compressive stress of the glass containers may be greater than or equal to 350 MPa. The delamination resistant glass pharmaceutical containers may be ion exchange strengthened and the ion exchange strengthening may include treating the delamination resistant glass pharmaceutical container in a molten salt bath for a time less than or equal to 5 hours at a temperature less than or equal to 450° C.

Disclosed herein are embodiments of a glass pharmaceutical package with unique composition. The pharmaceutical package includes a glass container with a first and second surface, the first surface being an outer surface of the glass container. The glass container is formed from a borosilicate glass composition, the glass composition including: at least 75 mol % SiO.sub.2; at least 10 mol % B.sub.2O.sub.3; and Al.sub.2O.sub.3 in an amount such that sum of SiO.sub.2, B.sub.2O.sub.3, and Al.sub.2O.sub.3 is at least 90 mol %. The glass container has at least two of the following: a hydrolytic resistance of class HGA 1 according to ISO 720:1985, a base resistance of class A1 or class A2 according to ISO 695:1991, and an acid resistance of class S2 or class S1 according to DIN 12116 (2001).

A spray coating apparatus that applies a coating material onto outer surfaces of glass objects includes a coating material source that includes a coating material. A spray nozzle assembly includes a spray nozzle fluidly connected to the coating material source. The spray nozzle is arranged and configured to direct the coating material in a first direction toward the glass object and provide an overspray amount of the coating material by the glass object such that the overspray amount bypasses a non-line of sight area of the glass object. A turn nozzle assembly includes a turn nozzle fluidly connected to a pressurized gas source. The turn nozzle is arranged and configured to direct pressurized gas in a second direction different than the first direction toward the non-line of sight area of the glass package to redirect the coating material onto the non-line of sight area.