Compositions and methods for producing materials for construction and for dust control utilizing enzyme producing cells, an amount of a nitrogen source such as urea, and an amount of calcium such as calcium chloride. Calcium contributes to the formation of calcium carbonate which creates a solid structure, layer or shield. One or more compositions containing components of the invention can be sprayed or otherwise applied to surfaces for erosion control, foundation support, prevention of sink hole formation, prevention of dust formation, or other applications. Ammonia, water and other by-products of the process can be recycled and re-utilized for the same or other purposes including, for example, as fertilizers and energy sources, or independently fermented from selectively cultivated microorganisms.

Systems and methods are provided for making aggregate from comingled waste plastics. For example, there is provided a method of making a preconditioned absorptive resin aggregate, the method including: obtaining a supply of granulated mixed plastic waste treated with a preconditioning agent that comprises at least one of calcium oxide and calcium hydroxide; mixing the supply of granulated mixed plastic waste treated with the calcium oxide preconditioning agent with one or more additives to form a plastic waste mixture, the one or more additives comprising pozzolans; hot extruding the plastic waste mixture to form an extruded product comprising waste plastic material; cooling the extruded product; and processing the extruded product to form an aggregate. Products incorporating such aggregates, such as, for example, lightweight construction blocks, are also provided. Also provided are methods of forming a waste plastics feedstock.

Systems and methods are provided for making aggregate from comingled waste plastics. For example, there is provided a method of making a preconditioned absorptive resin aggregate, the method including: obtaining a supply of granulated mixed plastic waste treated with a preconditioning agent that comprises at least one of calcium oxide and calcium hydroxide; mixing the supply of granulated mixed plastic waste treated with the calcium oxide preconditioning agent with one or more additives to form a plastic waste mixture, the one or more additives comprising pozzolans; hot extruding the plastic waste mixture to form an extruded product comprising waste plastic material; cooling the extruded product; and processing the extruded product to form an aggregate. Products incorporating such aggregates, such as, for example, lightweight construction blocks, are also provided. Also provided are methods of forming a waste plastics feedstock.

Systems and methods are provided for making aggregate from comingled waste plastics. For example, there is provided a method of making a preconditioned absorptive resin aggregate, the method including: obtaining a supply of granulated mixed plastic waste treated with a preconditioning agent that comprises at least one of calcium oxide and calcium hydroxide; mixing the supply of granulated mixed plastic waste treated with the calcium oxide preconditioning agent with one or more additives to form a plastic waste mixture, the one or more additives comprising pozzolans; hot extruding the plastic waste mixture to form an extruded product comprising waste plastic material; cooling the extruded product; and processing the extruded product to form an aggregate. Products incorporating such aggregates, such as, for example, lightweight construction blocks, are also provided. Also provided are methods of forming a waste plastics feedstock.

A cementitious composition including recycled superabsorbent polymer (RSAP) and a cementitious material. The RSAP has a purity level of at least 85 percent by weight of the RSAP. Also provided is a cementitious composition where the RSAP has substantially low levels of one or more residual drug entities. Also provided is a method for the construction of a self-sealing cement sheath, the method comprising: supplying a self-sealing slurry of a cementitious composition including cementitious material, an aqueous fluid, and RSAP into an underground geological formation, and allowing the self-sealing slurry of the cementitious composition to cure, thereby forming the self-sealing cement sheath. The RSAP is capable of swelling in the presence of fluid to seal any cracks formed in the self-sealing slurry during curing.

A cementitious composition including recycled superabsorbent polymer (RSAP) and a cementitious material. The RSAP has a purity level of at least 85 percent by weight of the RSAP. Also provided is a cementitious composition where the RSAP has substantially low levels of one or more residual drug entities. Also provided is a method for the construction of a self-sealing cement sheath, the method comprising: supplying a self-sealing slurry of a cementitious composition including cementitious material, an aqueous fluid, and RSAP into an underground geological formation, and allowing the self-sealing slurry of the cementitious composition to cure, thereby forming the self-sealing cement sheath. The RSAP is capable of swelling in the presence of fluid to seal any cracks formed in the self-sealing slurry during curing.

A cementitious composition including recycled superabsorbent polymer (RSAP) and a cementitious material. The RSAP has a purity level of at least 85 percent by weight of the RSAP. Also provided is a cementitious composition where the RSAP has substantially low levels of one or more residual drug entities. Also provided is a method for the construction of a self-sealing cement sheath, the method comprising: supplying a self-sealing slurry of a cementitious composition including cementitious material, an aqueous fluid, and RSAP into an underground geological formation, and allowing the self-sealing slurry of the cementitious composition to cure, thereby forming the self-sealing cement sheath. The RSAP is capable of swelling in the presence of fluid to seal any cracks formed in the self-sealing slurry during curing.

Preparing hybrid-treated plastic particles from waste plastic includes combining waste plastic particles with bio-oil to yield a mixture, irradiating the mixture with microwave radiation to yield oil-treated plastic particles, and contacting the oil-treated plastic particles with carbon-containing nanoparticles to yield hybrid-treated plastic particles. The hybrid-treated plastic particles have a bio-oil modified surface and a coating comprising carbon-containing nanoparticles on the bio-oil modified surface of the plastic particle. In some examples, a diameter of the plastic particle is in a range between 250 m and 750 m, and a thickness of the coating is in a range of 1 nm to 20 nm. A modified binder includes an asphalt binder or a concrete binder and a multiplicity of the treated plastic particles. The modified binder typically includes 5 wt % to 25 wt % of the hybrid-treated plastic particles.

Preparing hybrid-treated plastic particles from waste plastic includes combining waste plastic particles with bio-oil to yield a mixture, irradiating the mixture with microwave radiation to yield oil-treated plastic particles, and contacting the oil-treated plastic particles with carbon-containing nanoparticles to yield hybrid-treated plastic particles. The hybrid-treated plastic particles have a bio-oil modified surface and a coating comprising carbon-containing nanoparticles on the bio-oil modified surface of the plastic particle. In some examples, a diameter of the plastic particle is in a range between 250 m and 750 m, and a thickness of the coating is in a range of 1 nm to 20 nm. A modified binder includes an asphalt binder or a concrete binder and a multiplicity of the treated plastic particles. The modified binder typically includes 5 wt % to 25 wt % of the hybrid-treated plastic particles.

Expansive cements for use in cementing subterranean wells comprise water, an inorganic cement and one or more particulate materials that swell upon contact with a water immiscible fluid. The cements may further comprise a water immiscible fluid. Such cements are designed to seal microannuli arising from the presence of water immiscible fluids on casing surfaces, borehole wall surfaces or both.