Disclosed herein are a polyimide film for graphite sheets, a method of fabricating the same, and a graphite sheet fabricated using the same. The polyimide film is fabricated by imidizing a polyamic acid formed by reaction between a dianhydride monomer and a diamine monomer, wherein the reaction is carried out in the presence of particles of a metal compound having an average particle diameter (D.sub.50) of about 1 μm to about 6 μm.

Disclosed herein are a polyimide film for graphite sheets and a graphite sheet manufactured using the same. The polyimide film is fabricated by imidizing a precursor composition including: a polyamic acid prepared by reacting a dianhydride monomer with a diamine monomer; and an organic solvent, wherein the diamine monomer includes about 30 mol % to about 70 mol % of 4,4′-methylenedianiline and about 30 mol % to about 70 mol % of 4,4′-oxydianiline based on the total number of moles of the diamine monomer, 4,4′-methylenedianiline and 4,4′-oxydianiline being present in total in an amount of about 85 mol % or more based on the total number of moles of the diamine monomer.

The disclosure relates to a Fe.sub.3C-doped graded porous carbon polymer potassium ion anode material as well as a preparation method and application thereof. In the method, previously prepared Fe.sub.2O.sub.3 is added into phenylamine, pyrrole, thiophene and cellulose acetate solutions, the above mixture is evaporated at the low temperature of 65-100° C., and then the evaporated product is calcinated to obtain a potassium battery anode material. This material consists of carbon nano sheets having different pore diameters, and has a graded porous structure of micropores, mesopores and macropores. Physical characterization results show that this material has the characteristics of large interlayer spacing, high specific surface area, rich defects and the like; electrochemical testing results show that this material has high reversible capacity and excellent cycle stability and rate performance.

The disclosure relates to a Fe.sub.3C-doped graded porous carbon polymer potassium ion anode material as well as a preparation method and application thereof. In the method, previously prepared Fe.sub.2O.sub.3 is added into phenylamine, pyrrole, thiophene and cellulose acetate solutions, the above mixture is evaporated at the low temperature of 65-100° C., and then the evaporated product is calcinated to obtain a potassium battery anode material. This material consists of carbon nano sheets having different pore diameters, and has a graded porous structure of micropores, mesopores and macropores. Physical characterization results show that this material has the characteristics of large interlayer spacing, high specific surface area, rich defects and the like; electrochemical testing results show that this material has high reversible capacity and excellent cycle stability and rate performance.

The disclosure relates to a Fe.sub.3C-doped graded porous carbon polymer potassium ion anode material as well as a preparation method and application thereof. In the method, previously prepared Fe.sub.2O.sub.3 is added into phenylamine, pyrrole, thiophene and cellulose acetate solutions, the above mixture is evaporated at the low temperature of 65-100° C., and then the evaporated product is calcinated to obtain a potassium battery anode material. This material consists of carbon nano sheets having different pore diameters, and has a graded porous structure of micropores, mesopores and macropores. Physical characterization results show that this material has the characteristics of large interlayer spacing, high specific surface area, rich defects and the like; electrochemical testing results show that this material has high reversible capacity and excellent cycle stability and rate performance.

Composites of silicon and various porous scaffold materials, such as carbon material comprising micro-, meso- and/or macropores, and methods for manufacturing the same are provided. The compositions find utility in various applications, including electrical energy storage electrodes and devices comprising the same.

Composites of silicon and various porous scaffold materials, such as carbon material comprising micro-, meso- and/or macropores, and methods for manufacturing the same are provided. The compositions find utility in various applications, including electrical energy storage electrodes and devices comprising the same.

A porous carbon that has an extremely high specific surface area while being crystalline, and a method of manufacturing the porous carbon are provided. A porous carbon has mesopores 4 and a carbonaceous wall 3 constituting an outer wall of the mesopores 4, wherein the carbonaceous wall 3 has a portion forming a layered structure. The porous carbon is fabricated by mixing a polyamic acid resin 1 as a carbon precursor with magnesium oxide 2 as template particles; heat-treating the mixture in a nitrogen atmosphere at 1000° C. for 1 hour to cause the polyamic acid resin to undergo heat decomposition; washing the resultant sample with a sulfuric acid solution at a concentration of 1 mol/L to dissolve MgO away; and heat-treating the noncrystalline porous carbon in a nitrogen atmosphere at 2500° C.

A porous carbon that has an extremely high specific surface area while being crystalline, and a method of manufacturing the porous carbon are provided. A porous carbon has mesopores 4 and a carbonaceous wall 3 constituting an outer wall of the mesopores 4, wherein the carbonaceous wall 3 has a portion forming a layered structure. The porous carbon is fabricated by mixing a polyamic acid resin 1 as a carbon precursor with magnesium oxide 2 as template particles; heat-treating the mixture in a nitrogen atmosphere at 1000° C. for 1 hour to cause the polyamic acid resin to undergo heat decomposition; washing the resultant sample with a sulfuric acid solution at a concentration of 1 mol/L to dissolve MgO away; and heat-treating the noncrystalline porous carbon in a nitrogen atmosphere at 2500° C.

A porous carbon that has an extremely high specific surface area while being crystalline, and a method of manufacturing the porous carbon are provided. A porous carbon has mesopores 4 and a carbonaceous wall 3 constituting an outer wall of the mesopores 4, wherein the carbonaceous wall 3 has a portion forming a layered structure. The porous carbon is fabricated by mixing a polyamic acid resin 1 as a carbon precursor with magnesium oxide 2 as template particles; heat-treating the mixture in a nitrogen atmosphere at 1000° C. for 1 hour to cause the polyamic acid resin to undergo heat decomposition; washing the resultant sample with a sulfuric acid solution at a concentration of 1 mol/L to dissolve MgO away; and heat-treating the noncrystalline porous carbon in a nitrogen atmosphere at 2500° C.