Set forth herein are processes for making lithium-stuffed garnet oxides (e.g., Li.sub.7La.sub.3Zr.sub.2O.sub.12, also known as LLZO) that have passivated surfaces comprising a fluorinate and/or an oxyfluorinate species. These surfaces resist the formation of oxides, carbonates, hydroxides, peroxides, and organics that spontaneously form on LLZO surfaces under ambient conditions. Also set forth herein are new materials made by these processes.

A hydraulic binder including (in % by dry weight); A. at least 50 of at least one ground and granulated blast-furnace slag; B. more than 5 of at least one calcium aluminate cement and/or of at least one calcium sulfoaluminate cement; C. more than 5 of at least one source of sulfate ions; D. between 1 and 5 of Ca(OH).sub.2 and/or Portland cement; E. between 0.01 and 1 of at least one alkali metal carbonate; F. and at least one alkalifying reagent consisting of at least one alkali metal carbonate and/or bicarbonate, different from E; under the following conditions: (i) amount of C allows sulfate ions of C to react with B and A; (ii) the amount of F sufficiently causes a reaction with D in water resulting in a wet formulation with a pH not less than 12, for a water-to-mortar mixing rate between 10 and 35% by weight.

A hydraulic binder including (in % by dry weight); A. at least 50 of at least one ground and granulated blast-furnace slag; B. more than 5 of at least one calcium aluminate cement and/or of at least one calcium sulfoaluminate cement; C. more than 5 of at least one source of sulfate ions; D. between 1 and 5 of Ca(OH).sub.2 and/or Portland cement; E. between 0.01 and 1 of at least one alkali metal carbonate; F. and at least one alkalifying reagent consisting of at least one alkali metal carbonate and/or bicarbonate, different from E; under the following conditions: (i) amount of C allows sulfate ions of C to react with B and A; (ii) the amount of F sufficiently causes a reaction with D in water resulting in a wet formulation with a pH not less than 12, for a water-to-mortar mixing rate between 10 and 35% by weight.

Set forth herein are processes for making lithium-stuffed garnet oxides (e.g., Li.sub.7La.sub.3Zr.sub.2O.sub.12, also known as LLZO) that have passivated surfaces comprising a fluorinate and/or an oxyfluorinate species. These surfaces resist the formation of oxides, carbonates, hydroxides, peroxides, and organics that spontaneously form on LLZO surfaces under ambient conditions. Also set forth herein are new materials made by these processes.

Set forth herein are processes for making lithium-stuffed garnet oxides (e.g., Li.sub.7La.sub.3Zr.sub.2O.sub.12, also known as LLZO) that have passivated surfaces comprising a fluorinate and/or an oxyfluorinate species. These surfaces resist the formation of oxides, carbonates, hydroxides, peroxides, and organics that spontaneously form on LLZO surfaces under ambient conditions. Also set forth herein are new materials made by these processes.

The invention concerns a method for fluidifying wet concrete or industrial mortar compositions comprising: (a) at least one hydraulic binder, (b) at least one water reducing polymer, (c) at least one accelerator in the form of a salt containing at least one kosmotropic ion, (d) water, and (e) possibly one or more supplementary cementitious materials, and (f) possibly one or more filler materials, the method comprising a step of adding at least one salt (ch) including at least one chaotropic ion to the concrete or industrial mortar composition.

The invention concerns a method for fluidifying wet concrete or industrial mortar compositions comprising: (a) at least one hydraulic binder, (b) at least one water reducing polymer, (c) at least one accelerator in the form of a salt containing at least one kosmotropic ion, (d) water, and (e) possibly one or more supplementary cementitious materials, and (f) possibly one or more filler materials, the method comprising a step of adding at least one salt (ch) including at least one chaotropic ion to the concrete or industrial mortar composition.

A system and method are disclosed for lowering the internal relative humidity inside of a concrete structure by applying a pressurized gas and forcing such pressurized gas into the concrete structure, in turn driving moisture in the pores of the concrete to the exterior of the structure. Pressurized gas is supplied to a network of sealed cavities extending into the face of the concrete structure, ultimately causing the gas to move into the concrete structure through pores and capillaries through the structure, in turn driving moisture in the concrete structure toward the surface. Optionally, a competitive inhibiting agent, such as lithium nitrate, may also be provided to stabilize the concrete structure against future deleterious expansions caused by moisture uptake in the existing ASR gel.

A system and method are disclosed for lowering the internal relative humidity inside of a concrete structure by applying a pressurized gas and forcing such pressurized gas into the concrete structure, in turn driving moisture in the pores of the concrete to the exterior of the structure. Pressurized gas is supplied to a network of sealed cavities extending into the face of the concrete structure, ultimately causing the gas to move into the concrete structure through pores and capillaries through the structure, in turn driving moisture in the concrete structure toward the surface. Optionally, a competitive inhibiting agent, such as lithium nitrate, may also be provided to stabilize the concrete structure against future deleterious expansions caused by moisture uptake in the existing ASR gel.

Hexavalent chromium-free slurries are provided that are capable of achieving a full cure at temperatures as low as 330-450 degrees F., thus making the coatings especially suitable for application on temperature sensitive base materials. The slurries are suitable in the production of protective coating systems formed by novel silicate-based basecoats that are sealed with novel phosphate-based topcoats. The coating systems exhibit acceptable corrosion and heat resistance and are capable of replacing traditional chromate-containing coating systems.