A coated article (20;60) includes a substrate (22) and a coating (24;62) on the substrate. The coating includes at least a first layer (30). The first layer has: a matrix (50); and a filler (52) at 2.0% to 40% by volume in the first layer. The first layer is selected from alkaline earth or transition metal (M) tungstates (MWO4); alkaline earth molybdates (MMoO.sub.4); rare earth (RE) phosphates (REPO.sub.4); and combinations thereof.

A coated article (20;60) includes a substrate (22) and a coating (24;62) on the substrate. The coating includes at least a first layer (30). The first layer has: a matrix (50); and a filler (52) at 2.0% to 40% by volume in the first layer. The first layer is selected from alkaline earth or transition metal (M) tungstates (MWO4); alkaline earth molybdates (MMoO.sub.4); rare earth (RE) phosphates (REPO.sub.4); and combinations thereof.

According to some embodiments, a curable mixture configured to set in the presence of water, wherein the mixture comprises magnesium oxide, a primary cementitious component and at least one accelerant. A proportion by weight of the primary cementitious component is 80% to 120% of a proportion of magnesium oxide by weight.

According to some embodiments, a curable mixture configured to set in the presence of water, wherein the mixture comprises magnesium oxide, a primary cementitious component and at least one accelerant. A proportion by weight of the primary cementitious component is 80% to 120% of a proportion of magnesium oxide by weight.

The invention provides novel methods and novel additive compositions and use thereof in a wide range of concrete production for improving properties of concrete materials, such as durability and aestheticity. The methods and compositions of the invention may be applied in a variety of cement and concrete components in the infrastructure, construction, pavement and landscaping industries.

An article has a substrate and a layer atop the substrate. The layer has: a matrix comprising at least one of hafnium silicate (HfSiO.sub.4) and ytterbium disilicate (Yb.sub.2Si.sub.2O.sub.7); and barium magnesium alumino silicate (BMAS).

An article has a substrate and a layer atop the substrate. The layer has: a matrix comprising at least one of hafnium silicate (HfSiO.sub.4) and ytterbium disilicate (Yb.sub.2Si.sub.2O.sub.7); and barium magnesium alumino silicate (BMAS).

An article includes a ceramic-based substrate and a barrier layer on the ceramic-based substrate. The barrier layer includes a matrix of SiO2 and a dispersion of silicon oxycarbide particles in the matrix. The silicon oxycarbide particles have Si, O, and C in a covalently bonded network, and a dispersion of barium-magnesium alumino-silicate particles in the matrix. The barium-magnesium alumino-silicate particles have an average maximum dimension that is between about 10-40% of an average maximum dimension of the silicon oxycarbide particles. A composite material and a method of applying a barrier layer to a substrate are also disclosed.

An article includes a ceramic-based substrate and a barrier layer on the ceramic-based substrate. The barrier layer includes a matrix of SiO2 and a dispersion of silicon oxycarbide particles in the matrix. The silicon oxycarbide particles have Si, O, and C in a covalently bonded network, and a dispersion of barium-magnesium alumino-silicate particles in the matrix. The barium-magnesium alumino-silicate particles have an average maximum dimension that is between about 10-40% of an average maximum dimension of the silicon oxycarbide particles. A composite material and a method of applying a barrier layer to a substrate are also disclosed.

According to some embodiments, a curable mixture configured to set in the presence of water, wherein the mixture comprises magnesium oxide, a primary cementitious component and at least one accelerant. A proportion by weight of the primary cementitious component is 80% to 120% of a proportion of magnesium oxide by weight.