Patent classifications
C07C29/1516
METHOD FOR EFFICIENT CO2 DEGASIFICATION
A method including acidifying a solution including dissolved inorganic carbon; vacuum stripping a first amount of a carbon dioxide gas from the acidified solution; stripping a second amount of the carbon dioxide gas from the acidified solution; and collecting the first amount and the second amount of the carbon dioxide gas. A system including; a first desorption unit including a first input connected to a dissolved inorganic carbon solution source to and a second input coupled to a vacuum source; and a second desorption unit including a first input coupled to the solution output from the first desorption unit and a second input coupled to a sweep gas source.
Continuous Capture of Carbon Dioxide From Exhaust Gas and Conversion Thereof to Useful Chemistries
A method including collecting exhaust gas comprising carbon dioxide (CO.sub.2) at a wellsite to provide a collected exhaust gas, separating CO.sub.2 from the collected exhaust gas to provide a separated CO.sub.2, and forming an alcohol product utilizing at least a portion of the separated CO.sub.2. The alcohol product can include methanol, ethanol, a precursor thereof, or a combination thereof.
Continuous Capture of Carbon Dioxide From Exhaust Gas and Conversion Thereof to Useful Chemistries
A method including collecting exhaust gas comprising carbon dioxide (CO.sub.2) at a wellsite to provide a collected exhaust gas, separating CO.sub.2 from the collected exhaust gas to provide a separated CO.sub.2, and forming an alcohol product utilizing at least a portion of the separated CO.sub.2. The alcohol product can include methanol, ethanol, a precursor thereof, or a combination thereof.
Oxygenate synthesis and homologation
The invention relates to processes for oxygenate synthesis and homologation, to equipment and materials useful in such processes, and to the use of such oxygenate for producing olefin and polyolefin.
Oxygenate synthesis and homologation
The invention relates to processes for oxygenate synthesis and homologation, to equipment and materials useful in such processes, and to the use of such oxygenate for producing olefin and polyolefin.
PROCESS FOR PREPARING ALKENES
A process can be used to prepare alkenes by catalytic conversion of synthesis gas to a first mixture comprising alkenes and alcohols. The alcohols present in the first mixture are converted to the corresponding alkenes by dehydration in a subsequent step. At least one alkene having two to four carbon atoms is obtained as isolated product from a product mixture by processing thereof and/or separation steps. In the catalytic conversion, a catalyst is preferably used that comprises grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p of 1-20 nm. An average distance D between individual cobalt nanoparticles in the grains is 2-150 nm. A combined total mass fraction ω of metal in the grains is from 30%-70% by weight of a total mass of the grains such that 4.5 dp/ω>D≥0.25 dp/ω.
PROCESS FOR PREPARING ALKENES
A process can be used to prepare alkenes by catalytic conversion of synthesis gas to a first mixture comprising alkenes and alcohols. The alcohols present in the first mixture are converted to the corresponding alkenes by dehydration in a subsequent step. At least one alkene having two to four carbon atoms is obtained as isolated product from a product mixture by processing thereof and/or separation steps. In the catalytic conversion, a catalyst is preferably used that comprises grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p of 1-20 nm. An average distance D between individual cobalt nanoparticles in the grains is 2-150 nm. A combined total mass fraction ω of metal in the grains is from 30%-70% by weight of a total mass of the grains such that 4.5 dp/ω>D≥0.25 dp/ω.
Process for the multistage production of methanol
Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example 2-stage, heterogeneously catalyzed methanol synthesis, wherein the product stream of a synthesis stage is applied to the downstream synthesis stage as a feed stream or after removal of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention a substream is removed from the synthesis gas fresh gas and introduced into the second methanol synthesis reactor as a bypass stream.
Sulphur-Assisted Carbon Capture and Utilization (CCU) Methods and Systems
Disclosed herein is a system and method for sulphur-assisted carbon capture and utilization. The system includes a sulphur depolarized electrolyser (SDE) for receiving electricity, H.sub.2O and SO.sub.2 and for electrolysing the H.sub.2O and SO.sub.2 to produce hydrogen and sulphuric acid (H.sub.2SO.sub.4), a decomposition reactor for receiving and decomposing the H.sub.2SO.sub.4 into SO.sub.3 and H.sub.2O, wherein the H.sub.2O is recycled to the SDE, a sulphur submerged combustor for converting the SO.sub.3 to SO.sub.2 and producing S.sub.n vapor, a sulphur power plant for combusting S.sub.n vapor to produce SO.sub.2, electricity and heat and for supplying the SO.sub.2 and the electricity to the SDE and for supplying the heat to the decomposition reactor. The hydrogen is delivered to a carbon capture and utilization facility. An optional Flue Gas Desulphurisation (FGD) regenerable system removes SO.sub.2 from flue gas, a CO.sub.2 converter generates COS, and a separator separates the COS from the flue gas.
Sulphur-Assisted Carbon Capture and Utilization (CCU) Methods and Systems
Disclosed herein is a system and method for sulphur-assisted carbon capture and utilization. The system includes a sulphur depolarized electrolyser (SDE) for receiving electricity, H.sub.2O and SO.sub.2 and for electrolysing the H.sub.2O and SO.sub.2 to produce hydrogen and sulphuric acid (H.sub.2SO.sub.4), a decomposition reactor for receiving and decomposing the H.sub.2SO.sub.4 into SO.sub.3 and H.sub.2O, wherein the H.sub.2O is recycled to the SDE, a sulphur submerged combustor for converting the SO.sub.3 to SO.sub.2 and producing S.sub.n vapor, a sulphur power plant for combusting S.sub.n vapor to produce SO.sub.2, electricity and heat and for supplying the SO.sub.2 and the electricity to the SDE and for supplying the heat to the decomposition reactor. The hydrogen is delivered to a carbon capture and utilization facility. An optional Flue Gas Desulphurisation (FGD) regenerable system removes SO.sub.2 from flue gas, a CO.sub.2 converter generates COS, and a separator separates the COS from the flue gas.