The present disclosure relates to methods and compositions for making bio-based, biodegradable, and non-bioaccumulating lubricating base oils generated by esterifying alkoxylated polyols (average alkoxylation ≥3) with long-chain (≥C14) saturated and unsaturated fatty acids (FA) or fatty acids modified using industry recognized techniques.

A process for producing isomerized olefins, branched aldehydes, branched alcohols, branched surfactants and other branched derivatives through isomerization, hydroformylation, hydrogenation, surfactant forming reactions and other derivative forming reactions.

A process for producing isomerized olefins, branched aldehydes, branched alcohols, branched surfactants and other branched derivatives through isomerization, hydroformylation, hydrogenation, surfactant forming reactions and other derivative forming reactions.

A process is described for the preparation of polyglycerol fatty acid esters from a reaction mixture to which a metallic catalyst is added, as well as to a method for the purification of an intermediate synthesis product which contains excess fatty acid in addition to polyglycerol fatty acid esters. Compared with the prior art, a significantly improved yield and a higher process speed is obtained along with more economic use of raw materials, auxiliary materials, solvents and energy.

A process is described for the preparation of polyglycerol fatty acid esters from a reaction mixture to which a metallic catalyst is added, as well as to a method for the purification of an intermediate synthesis product which contains excess fatty acid in addition to polyglycerol fatty acid esters. Compared with the prior art, a significantly improved yield and a higher process speed is obtained along with more economic use of raw materials, auxiliary materials, solvents and energy.

The present disclosure relates to methods and compositions for making bio-based, biodegradable, and non-bioaccumulating lubricating base oils generated by esterifying alkoxylated polyols (average alkoxylation ≥3) with long-chain (≥C14) saturated and unsaturated fatty acids (FA) or fatty acids modified using industry recognized techniques.

A process is described for the preparation of polyglycerol fatty acid esters from a reaction mixture to which a metallic catalyst is added, as well as to a method for the purification of an intermediate synthesis product which contains excess fatty acid in addition to polyglycerol fatty acid esters. Compared with the prior art, a significantly improved yield and a higher process speed is obtained along with more economic use of raw materials, auxiliary materials, solvents and energy.

A process is described for the preparation of polyglycerol fatty acid esters from a reaction mixture to which a metallic catalyst is added, as well as to a method for the purification of an intermediate synthesis product which contains excess fatty acid in addition to polyglycerol fatty acid esters. Compared with the prior art, a significantly improved yield and a higher process speed is obtained along with more economic use of raw materials, auxiliary materials, solvents and energy.

Provided is a method of lubricating a sliding part by applying a lubricating base oil containing an ester compound to the sliding part. The ester compound contains a mixture of one or more compounds represented by a general formula (1) wherein R.sup.1 and R.sup.2 independently represent a hydrogen, a methyl, a benzoyloxy, a naphthoyloxy, or general formula (2) (—O—C(═O)—R.sup.5), R.sup.3 and R.sup.4 independently represent a benzoyloxy group, a naphthoyloxy group, or general formula (2), and R.sup.5 represents a linear C5-21 alkyl group, a branched chain C9-21 alkyl group, or a C5-21 cycloalkyl group that may also be substituted with an alkyl chain. The mixture contains a compound in which at least one among R.sup.1 to R.sup.4 is general formula (2), and the proportion, in the mixture, of a compound in which at least one among R.sup.1 to R.sup.4 is a benzoyloxy group or a naphthoyloxy group is 5-100 mole %.

Provided is a method of lubricating a sliding part by applying a lubricating base oil containing an ester compound to the sliding part. The ester compound contains a mixture of one or more compounds represented by a general formula (1) wherein R.sup.1 and R.sup.2 independently represent a hydrogen, a methyl, a benzoyloxy, a naphthoyloxy, or general formula (2) (—O—C(═O)—R.sup.5), R.sup.3 and R.sup.4 independently represent a benzoyloxy group, a naphthoyloxy group, or general formula (2), and R.sup.5 represents a linear C5-21 alkyl group, a branched chain C9-21 alkyl group, or a C5-21 cycloalkyl group that may also be substituted with an alkyl chain. The mixture contains a compound in which at least one among R.sup.1 to R.sup.4 is general formula (2), and the proportion, in the mixture, of a compound in which at least one among R.sup.1 to R.sup.4 is a benzoyloxy group or a naphthoyloxy group is 5-100 mole %.