C07C69/54

Reactor and process for producing alkyl (meth)acrylates

A novel process can be used for a heterogeneously catalysed oxidation reaction, in the presence of a pulverulent noble metal-containing catalyst, where (meth)acrolein, an alkyl alcohol, in particular methanol, and an oxygen-containing gas are converted to an alkyl (meth)acrylate, in particular methyl (meth)acrylate. A corresponding reactor suitable for performing the reaction is also useful. The process allows for an effective retention of the particulate catalyst and the continuous discharge of fines fractions of the catalyst powder which are present, particularly in a fresh catalyst batch as a consequence of its preparation. Such fines fractions may also be produced by abrasion during the reaction. The process allows for effective recycling, recovery, and utilization of these discharged catalyst fractions.

Reactor and process for producing alkyl methacrylates
20220380293 · 2022-12-01 · ·

A process produces methyl methacrylate by direct oxidative esterification of methacrolein. Methyl methacrylate is used in large amounts for producing polymers and copolymers with other polymerizable compounds. An optimized workup of the reactor discharge from the oxidative esterification of methacrolein allows for co-discharged fine catalyst particles to be very efficiently separated and optionally removed or recycled. In addition, this process can reduce the formation of byproducts in extended continuous operation compared to known variant. A reactor system contains stirrer configurations which allow virtually abrasion-free operation and thus a catalyst on-stream time of several years.

Reactor and process for producing alkyl methacrylates
20220380293 · 2022-12-01 · ·

A process produces methyl methacrylate by direct oxidative esterification of methacrolein. Methyl methacrylate is used in large amounts for producing polymers and copolymers with other polymerizable compounds. An optimized workup of the reactor discharge from the oxidative esterification of methacrolein allows for co-discharged fine catalyst particles to be very efficiently separated and optionally removed or recycled. In addition, this process can reduce the formation of byproducts in extended continuous operation compared to known variant. A reactor system contains stirrer configurations which allow virtually abrasion-free operation and thus a catalyst on-stream time of several years.

Display device

A display device includes: a base substrate; a light emitting element on the base substrate; a thin film encapsulation layer on the light emitting element to encapsulate the light emitting element; a touch member on the thin film encapsulation layer; a color filter layer on the touch member; and a planarization layer on the color filter layer to cover the color filter layer, wherein the planarization layer includes a light absorber represented by Formula 1:
X—Ar—Y.  Formula 1

Display device

A display device includes: a base substrate; a light emitting element on the base substrate; a thin film encapsulation layer on the light emitting element to encapsulate the light emitting element; a touch member on the thin film encapsulation layer; a color filter layer on the touch member; and a planarization layer on the color filter layer to cover the color filter layer, wherein the planarization layer includes a light absorber represented by Formula 1:
X—Ar—Y.  Formula 1

Method for preparing keto-functionalized aromatic (meth)acrylates

The invention relates to a method for preparing keto-functionalized aromatic (meth)acrylates.

Method for preparing keto-functionalized aromatic (meth)acrylates

The invention relates to a method for preparing keto-functionalized aromatic (meth)acrylates.

Simplified workup of the reactor output from an oxidative esterification
20220363625 · 2022-11-17 · ·

A process can be used for preparing methyl methacrylate by direct oxidative esterification of methacrolein. Methyl methacrylate is used in large amounts for preparing polymers and copolymers with other polymerizable compounds. In addition, methyl methacrylate is an important synthesis unit for a variety of specialty esters based on methacrylic acid (MAA) which can be prepared by transesterification with the appropriate alcohol. There is consequently a great interest in very simple, economic and environmentally friendly processes for preparing this starting material. A corresponding optimized workup of the reactor output from the oxidative esterification of methacrolein, through which unconverted methacrolein (MAL) can be recycled very efficiently, is useful. In addition, the process can be carried out in a manner which compared to known variants is markedly more energy- and water-saving.

Simplified workup of the reactor output from an oxidative esterification
20220363625 · 2022-11-17 · ·

A process can be used for preparing methyl methacrylate by direct oxidative esterification of methacrolein. Methyl methacrylate is used in large amounts for preparing polymers and copolymers with other polymerizable compounds. In addition, methyl methacrylate is an important synthesis unit for a variety of specialty esters based on methacrylic acid (MAA) which can be prepared by transesterification with the appropriate alcohol. There is consequently a great interest in very simple, economic and environmentally friendly processes for preparing this starting material. A corresponding optimized workup of the reactor output from the oxidative esterification of methacrolein, through which unconverted methacrolein (MAL) can be recycled very efficiently, is useful. In addition, the process can be carried out in a manner which compared to known variants is markedly more energy- and water-saving.

PHOTOPOLYMERIZABLE BLOCK POLYMERS AND METHODS OF PRODUCING AND USING THE SAME

Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, and telechelic block polymers and methods of using such polymers in curable compositions to produce medical devices such as orthodontic appliances comprising the polymeric compositions comprising the telechelic block polymers.