Patent classifications
C07C209/18
Surfactant-Enabled Transition Metal-Catalyzed Chemistry
In one embodiment, the present application discloses mixtures comprising (a) water in an amount of at least 1% wt/wt of the mixture; (b) a transition metal catalyst; and (c) one or more solubilizing agents; and methods for using such mixtures for performing transition metal mediated bond formation reactions.
RUTHENIUM COMPLEX, METHOD FOR PRODUCING SAME, AND USE OF SAME
The present invention provides a novel ruthenium complex that is easy to produce and handle and that can be supplied relatively inexpensively, a method for producing this ruthenium complex, a method for producing alcohols and the like using this ruthenium complex as a catalyst, a method for producing carbonyl compounds using this ruthenium complex as a catalyst, and a method for producing N-alkylamine compounds using this ruthenium complex as a catalyst. The present invention pertains to a ruthenium complex represented by general formula (1) RuX.sup.1X.sup.2(PNP) (NHC).sub.m(Solv).sub.n(1) (in general formula (1), X.sup.1 and X.sup.2 each independently represent a monovalent anionic monodentate ligand; PNP represents a tridentate aminodiphosphine ligand, NHC represents an N-heterocyclic carbene derived from a nitrogen-containing heterocyclic ring, and Solv represents a coordinating solvent; and m represents an integer from 1 to 3, n represents an integer from 0 to 2, and 1m+n3.), a method for producing the same, a catalyst including the same, and methods for producing various organic compounds using this catalyst.
RUTHENIUM COMPLEX, METHOD FOR PRODUCING SAME, AND USE OF SAME
The present invention provides a novel ruthenium complex that is easy to produce and handle and that can be supplied relatively inexpensively, a method for producing this ruthenium complex, a method for producing alcohols and the like using this ruthenium complex as a catalyst, a method for producing carbonyl compounds using this ruthenium complex as a catalyst, and a method for producing N-alkylamine compounds using this ruthenium complex as a catalyst. The present invention pertains to a ruthenium complex represented by general formula (1) RuX.sup.1X.sup.2(PNP) (NHC).sub.m(Solv).sub.n(1) (in general formula (1), X.sup.1 and X.sup.2 each independently represent a monovalent anionic monodentate ligand; PNP represents a tridentate aminodiphosphine ligand, NHC represents an N-heterocyclic carbene derived from a nitrogen-containing heterocyclic ring, and Solv represents a coordinating solvent; and m represents an integer from 1 to 3, n represents an integer from 0 to 2, and 1m+n3.), a method for producing the same, a catalyst including the same, and methods for producing various organic compounds using this catalyst.