C07C2523/78

CATALYST FOR METHANATION OF CARBON OXIDES, PREPARATION METHOD OF THE CATALYST AND PROCESS FOR THE METHANATION

Disclosed is a catalyst for methanation reaction producing methane with high conversion by reaction of hydrogen with carbon dioxide, or a gas mixture of carbon dioxide and carbon monoxide, or a gas mixture containing these compounds as the main components. The catalyst is prepared by the steps of mixing (A) aqueous zirconia sol with salts of (B) stabilizing element(s), which is selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca and Mg, and (C) iron group element(s), drying and calcining the mixture to obtain a catalyst precursor, and subsequent reduction of the precursor. The catalyst comprises, by atomic %, A: 18-70%, B: 1-20% and C: 25-80% based on the elemental states of the metals. The catalyst is characterized by multiple oxide of tetragonal zirconia structure, in which not only the stabilizing element(s) but also a part of the iron group element(s) is incorporated, and on which the iron group element(s) in the metallic state is supported.

Catalyst for methanation of carbon oxides, preparation method of the catalyst and process for the methanation

Disclosed is a catalyst for methanation reaction producing methane with high conversion by reaction of hydrogen with carbon dioxide, or a gas mixture of carbon dioxide and carbon monoxide, or a gas mixture containing these compounds as the main components. The catalyst is prepared by the steps of mixing (A) aqueous zirconia sol with salts of (B) stabilizing element(s), which is selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca and Mg, and (C) iron group element(s), drying and calcining the mixture to obtain a catalyst precursor, and subsequent reduction of the precursor. The catalyst comprises, by atomic %, A: 18-70%, B: 1-20% and C: 25-80% based on the elemental states of the metals. The catalyst is characterized by multiple oxide of tetragonal zirconia structure, in which not only the stabilizing element(s) but also a part of the iron group element(s) is incorporated, and on which the iron group element(s) in the metallic state is supported.

IMPROVED CATALYST FOR DEHYDROGENATING HYDROCARBONS
20170073284 · 2017-03-16 ·

The present invention relates to a catalyst for the dehydrogenation of hydrocarbons which is based on iron oxide and a process for producing it. The catalyst comprises at least one iron compound, at least one potassium compound and from 11 to 24% by weight of at least one cerium compound, calculated as CeO.sub.2, wherein the at least one iron compound and the at least one potassium compound are at least partly present in the form of one or more K/Fe mixed oxide phases of the general formula K.sub.xFe.sub.yO.sub.z, where x is from 1 to 17; y is from 1 to 22 and z is from 2 to 34, and comprises at least 50% by weight, based on the total catalyst, of the K/Fe mixed oxide phases, and also a process for producing it.

Methane upgrade to ethane and ethylene within ceramic membrane reactors

A ceramic membrane for oxidative coupling of methane can include a perovskite oxide and catalyst material on a surface of the membrane.

INTEGRATED DIRECT AIR CAPTURE AND CONVERSION TO HYDROCARBONS

A multifunctional material may include a solid inorganic sorbent. The multifunctional material may include a metal catalyst component, wherein the solid inorganic sorbent and metal catalyst component are integrated into a single material.

Iron-doped potassium-titanate nanotube catalysts and methods of making and using same

The disclosure relates to iron-doped potassium titanate nanotube catalysts, and methods of making and using such catalysts. The catalysts can be used in the hydrogenation of carbon dioxide (CO.sub.2) for the production of light olefins.

Catalyst for CO2 methanation reaction having high activity and long term stability and process thereof

The present invention relates to a novel heterogeneous catalyst for selective carbon dioxide methanation reaction having high activity and long-term stability, wherein the catalyst comprising of at least one alkali promoter metal, active metals selected from Nickel and Iron and a stable support for active metals having combination of CeO.sub.2-Al.sub.2O.sub.3. Further, the present invention provides a process for synthesis of said catalyst. Secondly, the present invention also provides a sustainable process for synthesis of methane using said novel heterogenous catalyst. The benefits of present invention are that it provides a sustainable CO.sub.2 methanation process as the novel outstanding catalyst having high performance and long-term stability and totally eliminates catalyst regeneration or reloading step due to its very long-term stability for >1000 h.

PROCESS FOR THE CONVERSION OF CARBON DIOXIDE INTO VALUE-ADDED PRODUCTS BY MEANS OF A PROCESS OF MECHANOCHEMICAL ACTIVATION OF INDUSTRIAL PROCESSING SCRAPS

The present invention relates to a method for converting carbon dioxide (CO.sub.2) into high added value chemical products by means of a mechanochemical process under gas flow and continuous conditions. In particular, said process converts CO.sub.2 into a mixture of high added value chemical compounds comprising solid products of mineral carbonation, mainly Mg, Fe and Ca carbonates, and/or low molecular weight hydrocarbons, mainly methane, ethylene and ethane. Said CO.sub.2 conversion is achieved, in particular, by applying said mechanochemical process to slags from steelmaking processes and/or basalt scraps.

Nanostructured hybrid iron-zeolite catalysts

The present invention relates to a hybrid iron nanoparticle catalyst comprising: i) 1 to 50 wt. % nanoparticles comprising iron and at least one of a metal M selected from the group consisting of alkali metals, alkaline earth metals, transition metals of groups 3 to 7 and 9 to 11 of the Periodic Table of Elements, lanthanides and combinations of M thereof; and ii) 50 to 99 wt. % of an aluminosilicate or silicoaluminophosphate zeolite, based on the total weight of the catalyst, wherein said nanoparticle has a diameter of about 2 to 50 nm. The present invention also relates to a method of preparing the hybrid iron nanoparticle catalyst and a process for the production of light olefins using the hybrid iron nanoparticle catalyst.