The present invention relates to thermoplastic polyamides (PA) comprising recurring units derived from a PFPE dicarboxylic acid (PFPA-DA) or a PFPE diamine (PFPE-NN) in a defined weight amount with respect to other units derived from the other monomers used in the course of polymerization. Polyamides (PA) are endowed with improved surface properties, chemical resistance and reduced brittleness and do not require the addiction of impact modifiers.

Some embodiments of the invention include inventive catalysts (e.g., compounds of Formula (I) or (Ia)). Other embodiments include compositions comprising the inventive catalysts. Some embodiments include methods of using the inventive catalysts (e.g., in hydrofluorination of an organic compound). Further embodiments include methods for making the inventive catalysts. Additional embodiments of the invention are also discussed herein.

Some embodiments of the invention include inventive catalysts (e.g., compounds of Formula (I) or (Ia)). Other embodiments include compositions comprising the inventive catalysts. Some embodiments include methods of using the inventive catalysts (e.g., in hydrofluorination of an organic compound). Further embodiments include methods for making the inventive catalysts. Additional embodiments of the invention are also discussed herein.

A polymerizable composition, a prepolymer, a phthalonitrile resin, or a composite provided herein has excellent heat resistance and does not cause defects that may adversely affect physical properties. In addition, the polymerizable composition exhibits appropriate curing properties, processing temperatures and process windows and to be capable of forming a composite of excellent physical properties.

Methods of CH bond fluorination using non-heme manganese catalyst are described herein. For example, a method comprises providing a reaction mixture including a non-heme manganese catalyst, a substrate comprising an sp.sup.3 CH bond and a fluorinating agent and converting the sp.sup.3 CH bond to a CF bond in the presence of the non-heme manganese catalyst or a derivative thereof.

Methods of CH bond fluorination using non-heme manganese catalyst are described herein. For example, a method comprises providing a reaction mixture including a non-heme manganese catalyst, a substrate comprising an sp.sup.3 CH bond and a fluorinating agent and converting the sp.sup.3 CH bond to a CF bond in the presence of the non-heme manganese catalyst or a derivative thereof.

A method for producing a halogenated organic pigment comprising a halogenation step of halogenating an organic pigment with a halogenating agent, wherein the halogenating agent comprises one or more N-haloimide compounds selected from the group consisting of trichloroisocyanuric acid, a metal salt of dichloroisocyanuric acid, tribromoisocyanuric acid, and a metal salt of dibromoisocyanuric acid. According to the present invention, a method for producing a halogenated organic pigment which does not use high toxic raw materials, does not generate a large amount of unfavorable by-products such as hydrogen halide gas and succinimide, and is excellent in terms of safety and productivity can be provided.

A method for producing a halogenated organic pigment comprising a halogenation step of halogenating an organic pigment with a halogenating agent, wherein the halogenating agent comprises one or more N-haloimide compounds selected from the group consisting of trichloroisocyanuric acid, a metal salt of dichloroisocyanuric acid, tribromoisocyanuric acid, and a metal salt of dibromoisocyanuric acid. According to the present invention, a method for producing a halogenated organic pigment which does not use high toxic raw materials, does not generate a large amount of unfavorable by-products such as hydrogen halide gas and succinimide, and is excellent in terms of safety and productivity can be provided.

The invention relates to cross-linkable oligoimides, processes of making such cross-linkable oligoimides and products comprising such cross-linkable oligoimides. Such cross-linkable oligoimides provide articles made by an AM process with the desired process ability that permits filament formation, post cure increased strength, the desired in use temperature stability and the desired thermo-oxidative stability.

The invention relates to cross-linkable oligoimides, processes of making such cross-linkable oligoimides and products comprising such cross-linkable oligoimides. Such cross-linkable oligoimides provide articles made by an AM process with the desired process ability that permits filament formation, post cure increased strength, the desired in use temperature stability and the desired thermo-oxidative stability.