A method for providing particles of polyvinyl chloride, wherein the particles offer improved chlorinating efficiency, the method comprising (i) providing polyvinyl chloride particles; and (ii) introducing a chlorination accelerant to the polyvinyl chloride particles to thereby provide polyvinyl chloride particles having an accelerant associated therewith.

The present invention provides a chlorinated polyvinyl chloride resin that enables the production of a molded article that maintains high adhesion strength even when used in a form subjected to high pressure and is less susceptible to defects such as cracks due to insufficient strength, as well as a resin composition for molding and a molded article each including the chlorinated polyvinyl chloride resin. Provided is a chlorinated polyvinyl chloride resin, containing two components including a A.sub.30 component and a B.sub.30 component, the A.sub.30 component and the B.sub.30 component being determined by measuring the resin by a solid echo method using pulse NMR at 30° C. to give a free induction decay curve of .sup.1H spin-spin relaxation, and subjecting the free induction decay curve to waveform separation into two curves derived from the A.sub.30 component and the B.sub.30 component in order of shorter relaxation time using the least square method, and having a ratio of T5.sub.B to T.sub.B [T5.sub.B/T.sub.B] of 76% or more and less than 96%, where T.sub.B is a relaxation time of the B.sub.30 component and T5.sub.B is a relaxation time of the B.sub.30 component after heating at 200° C. for five minutes.

The present invention provides a chlorinated polyvinyl chloride resin that enables the production of a molded article that maintains high adhesion strength even when used in a form subjected to high pressure and is less susceptible to defects such as cracks due to insufficient strength, as well as a resin composition for molding and a molded article each including the chlorinated polyvinyl chloride resin. Provided is a chlorinated polyvinyl chloride resin, containing two components including a A.sub.30 component and a B.sub.30 component, the A.sub.30 component and the B.sub.30 component being determined by measuring the resin by a solid echo method using pulse NMR at 30° C. to give a free induction decay curve of .sup.1H spin-spin relaxation, and subjecting the free induction decay curve to waveform separation into two curves derived from the A.sub.30 component and the B.sub.30 component in order of shorter relaxation time using the least square method, and having a ratio of T5.sub.B to T.sub.B [T5.sub.B/T.sub.B] of 76% or more and less than 96%, where T.sub.B is a relaxation time of the B.sub.30 component and T5.sub.B is a relaxation time of the B.sub.30 component after heating at 200° C. for five minutes.

The disclosed technology relates to a plastic compound suitable for preparing articles, such as pipe fittings and valves, with good physical properties, such as impact strength, and resistance to environmental stress cracking (ESC). In particular, the technology relates to a vinyl chloride resin, which includes chlorinated polyvinyl chloride (“CPVC”) homopolymer. Furthermore, the invention relates to vinyl chloride homopolymer compounds containing the vinyl chloride homopolymer resin, and articles made from such compounds, which compounds meet 23447 cell classifications under ASTM D1784.

The disclosed technology relates to a plastic compound suitable for preparing articles, such as pipe fittings and valves, with good physical properties, such as impact strength, and resistance to environmental stress cracking (ESC). In particular, the technology relates to a vinyl chloride resin, which includes chlorinated polyvinyl chloride (“CPVC”) homopolymer. Furthermore, the invention relates to vinyl chloride homopolymer compounds containing the vinyl chloride homopolymer resin, and articles made from such compounds, which compounds meet 23447 cell classifications under ASTM D1784.

The disclosed technology relates to a plastic compound suitable for preparing articles, such as pipe fittings and valves, with good physical properties, such as impact strength, and resistance to environmental stress cracking (ESC). In particular, the technology relates to a vinyl chloride resin, which includes chlorinated polyvinyl chloride (“CPVC”) homopolymer. Furthermore, the invention relates to vinyl chloride homopolymer compounds containing the vinyl chloride homopolymer resin, and articles made from such compounds, which compounds meet 23447 cell classifications under ASTM D1784.

An alcohol-based composition may contain an acryl-modified polyolefin resin and exhibit a good adhesion even at a high solid content, suppress an increase in viscosity, and have good stability such as dispersibility and sustainable stability. A dispersion composition may contain at least a modified polyolefin resin dispersed in a dispersing medium containing an alcohol solvent and an aliphatic hydrocarbon solvent. The modified polyolefin resin may be modified with a (meth)acrylic acid component containing at least a (meth)acrylic ester of formula (I) and a (meth)acrylic ester of formula (II). The total content of the structure derived from the (meth)acrylic acid component in the dispersion composition is 3% to 94% by weight, relative to 100% by weight as a total amount of the modified polyolefin resin and (meth)acrylic acid component polymer, and a solid fraction in the dispersion composition is 30% to 80% by weight.

An alcohol-based composition may contain an acryl-modified polyolefin resin and exhibit a good adhesion even at a high solid content, suppress an increase in viscosity, and have good stability such as dispersibility and sustainable stability. A dispersion composition may contain at least a modified polyolefin resin dispersed in a dispersing medium containing an alcohol solvent and an aliphatic hydrocarbon solvent. The modified polyolefin resin may be modified with a (meth)acrylic acid component containing at least a (meth)acrylic ester of formula (I) and a (meth)acrylic ester of formula (II). The total content of the structure derived from the (meth)acrylic acid component in the dispersion composition is 3% to 94% by weight, relative to 100% by weight as a total amount of the modified polyolefin resin and (meth)acrylic acid component polymer, and a solid fraction in the dispersion composition is 30% to 80% by weight.

A process for producing a halogenated isoolefin copolymer involves contacting an unsaturated isoolefin copolymer cement, the cement containing an unsaturated isoolefin copolymer dissolved in an organic solvent, under halogenation conditions with a halogenating agent and an aqueous solution of an organic peracid oxidant to form a two-phase reaction medium having an organic phase and an aqueous phase, the organic peracid oxidant capable of converting hydrogen halide to free halogen. The process leads to higher halogen utilization even when the cement contains significant amounts of water and without the use of an emulsifier.

A process for producing a halogenated isoolefin copolymer involves contacting an unsaturated isoolefin copolymer cement, the cement containing an unsaturated isoolefin copolymer dissolved in an organic solvent, under halogenation conditions with a halogenating agent and an aqueous solution of an organic peracid oxidant to form a two-phase reaction medium having an organic phase and an aqueous phase, the organic peracid oxidant capable of converting hydrogen halide to free halogen. The process leads to higher halogen utilization even when the cement contains significant amounts of water and without the use of an emulsifier.