C08F20/26

Plastic lens, spectacle lens, and spectacles
11187828 · 2021-11-30 · ·

Provided is a plastic lens obtained by curing a curable composition including a curable compound, wherein the curable composition includes 50 parts by mass or more of a (meth)acrylic curable compound relative to 100 parts by mass of the total amount of the curable compound, and in the plastic lens, the absorbance ratio of the maximum absorbance Abs1 at a wave number of 1680 to 1620 cm.sup.−1 relative to the maximum absorbance Abs2 at a wave number of 1800 to 1690 cm.sup.−1 in an infrared spectrum obtained by measurement with a Fourier transform infrared spectrophotometer is 7.0% or less, as calculated by using the following Formula 1:
Absorbance ratio (%)=(Abs1/Abs2)×100.

Active energy ray-curable composition

An active energy ray-curable composition is disclosed including: an anionically polymerizable compound represented by (1): ##STR00001##
wherein EWG represents an electron-withdrawing group, X represents a single bond or an oxygen atom (—O—), R represents an n-valent organic group, and n represents an integer of 1 to 6; when n is an integer of 2 to 6, the respective EWG and the respective X may be the same or different; and when n is 1, EWG and R may be bonded; and a compound (photobase generator) represented by (2): ##STR00002##
wherein ring A represents an aromatic ring that may be substituted or a heteroaromatic ring that may be substituted; R.sup.1 and R.sup.2 are the same or different and each represents a hydrogen atom or an alkyl group; R.sup.1 and R.sup.2 may be bonded to each other to form a ring together with an adjacent nitrogen atom; and the ring may be substituted.

Active energy ray-curable composition

An active energy ray-curable composition is disclosed including: an anionically polymerizable compound represented by (1): ##STR00001##
wherein EWG represents an electron-withdrawing group, X represents a single bond or an oxygen atom (—O—), R represents an n-valent organic group, and n represents an integer of 1 to 6; when n is an integer of 2 to 6, the respective EWG and the respective X may be the same or different; and when n is 1, EWG and R may be bonded; and a compound (photobase generator) represented by (2): ##STR00002##
wherein ring A represents an aromatic ring that may be substituted or a heteroaromatic ring that may be substituted; R.sup.1 and R.sup.2 are the same or different and each represents a hydrogen atom or an alkyl group; R.sup.1 and R.sup.2 may be bonded to each other to form a ring together with an adjacent nitrogen atom; and the ring may be substituted.

Polymer production method and radical polymerization initiating group-containing compound

The present invention provides: a novel production technique that enables production of a polymer whose molecular weight and molecular weight distribution are controlled and production of a polymer having a complicated structure in a desirably controlled manner using commercially available materials without using a radical polymerization initiator or a special material for use in living radical polymerization and without the need for strict polymerization conditions; and a radical polymerization initiating group-containing compound for use in the technique. The present invention relates to: a method for producing a polymer, the method including a polymerization step of mixing and warming (1) a radically polymerizable monomer, (2) an organic compound wherein at least one group that functions as a group for initiating polymerization of the monomer and that has a structure represented by formula 1 or formula 2 (X in the formula represents Cl or Br) is introduced in a molecule of the organic compound, and (3) an iodine-containing compound, thereby initiating, from the group having the structure, radical polymerization accompanied by a termination reaction; and the organic compound of (2) for use in the method. ##STR00001##

Polymer production method and radical polymerization initiating group-containing compound

The present invention provides: a novel production technique that enables production of a polymer whose molecular weight and molecular weight distribution are controlled and production of a polymer having a complicated structure in a desirably controlled manner using commercially available materials without using a radical polymerization initiator or a special material for use in living radical polymerization and without the need for strict polymerization conditions; and a radical polymerization initiating group-containing compound for use in the technique. The present invention relates to: a method for producing a polymer, the method including a polymerization step of mixing and warming (1) a radically polymerizable monomer, (2) an organic compound wherein at least one group that functions as a group for initiating polymerization of the monomer and that has a structure represented by formula 1 or formula 2 (X in the formula represents Cl or Br) is introduced in a molecule of the organic compound, and (3) an iodine-containing compound, thereby initiating, from the group having the structure, radical polymerization accompanied by a termination reaction; and the organic compound of (2) for use in the method. ##STR00001##

Polymerizable liquid crystal composition, optically anisotropic film, optical film, polarizing plate, and image display device

An object of the present invention is to provide a polymerizable liquid crystal composition used for formation of an optically anisotropic film having excellent moisture-heat resistance and an excellent surface condition, an optically anisotropic film, an optical film, a polarizing plate, and an image display device. The polymerizable liquid crystal composition of an embodiment of the present invention is a polymerizable liquid crystal composition containing a polymerizable liquid crystal compound and a compound represented by Formula (1): L.sup.1-SP.sup.1-(E.sup.3-A.sup.1).sub.m-E.sup.1-G.sup.1-C(═O)—O—C(═O)-G.sup.2-E.sup.2-(A.sup.2-E.sup.4).sub.n-SP.sup.2-L.sup.2, in which a content of the compound represented by Formula (1) is 0.01 to 5 parts by mass with respect to 100 parts by mass of the polymerizable liquid crystal compound.

Polymerizable liquid crystal composition, optically anisotropic film, optical film, polarizing plate, and image display device

An object of the present invention is to provide a polymerizable liquid crystal composition used for formation of an optically anisotropic film having excellent moisture-heat resistance and an excellent surface condition, an optically anisotropic film, an optical film, a polarizing plate, and an image display device. The polymerizable liquid crystal composition of an embodiment of the present invention is a polymerizable liquid crystal composition containing a polymerizable liquid crystal compound and a compound represented by Formula (1): L.sup.1-SP.sup.1-(E.sup.3-A.sup.1).sub.m-E.sup.1-G.sup.1-C(═O)—O—C(═O)-G.sup.2-E.sup.2-(A.sup.2-E.sup.4).sub.n-SP.sup.2-L.sup.2, in which a content of the compound represented by Formula (1) is 0.01 to 5 parts by mass with respect to 100 parts by mass of the polymerizable liquid crystal compound.

RANDOM BIPOLYMERS OF CONTROLLED MOLECULAR MASS BASED ON HYDROXYACRYLATES AND THEIR USE AS DESTABILIZERS OF WATER/OIL EMULSIONS IN CRUDE OILS

The present disclosure provide bipolymers, based on alkyl acrylate and hydroxyalkyl acrylate, with high randomness and controlled molecular mass, that are useful as demulsifying and dehydrating agents for crude oil. The synthesis of these bipolymers is carried out in a single stage by emulsion polymerization, a process that, in addition to having moderate reaction conditions, allows the control of the homogeneity of the chain size, the molecular mass, and the demulsifying efficiency. These random bipolymers are soluble in organic phase; therefore, these cannot be carried away by the removed water, and are eliminated in the atmospheric distillation stage. An additional advantage is the superior demulsifying and clarifying efficiency of these random bipolymers compared with the polyether formulations widely used at industrial level. In addition, these random bipolymers provide single molecule that performs three functions: breaker, coalescer and clarifier, in contrast to formulations based on at least three different polyethers.

RANDOM BIPOLYMERS OF CONTROLLED MOLECULAR MASS BASED ON HYDROXYACRYLATES AND THEIR USE AS DESTABILIZERS OF WATER/OIL EMULSIONS IN CRUDE OILS

The present disclosure provide bipolymers, based on alkyl acrylate and hydroxyalkyl acrylate, with high randomness and controlled molecular mass, that are useful as demulsifying and dehydrating agents for crude oil. The synthesis of these bipolymers is carried out in a single stage by emulsion polymerization, a process that, in addition to having moderate reaction conditions, allows the control of the homogeneity of the chain size, the molecular mass, and the demulsifying efficiency. These random bipolymers are soluble in organic phase; therefore, these cannot be carried away by the removed water, and are eliminated in the atmospheric distillation stage. An additional advantage is the superior demulsifying and clarifying efficiency of these random bipolymers compared with the polyether formulations widely used at industrial level. In addition, these random bipolymers provide single molecule that performs three functions: breaker, coalescer and clarifier, in contrast to formulations based on at least three different polyethers.

Functionalized resin having a polar linker

Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.