Two-part cyanoacrylate/cationically curable adhesive systems, are provided.

Two-part cyanoacrylate/cationically curable adhesive systems, are provided.

The present invention concerns a two-part curable composition comprising: ⋅ a first part (component A) comprising at least 51% by weight based on the total weight of the first part, of one or more cyanoacrylate monomer(s), provided that at least one of the cyanoacrylate monomer(s) is a cyanoacrylate monomer comprising a group —X—O—R.sup.b wherein X is a linear or branched alkylene radical optionally interrupted with one or several oxygen atom(s), and R.sup.b is an alkyl group; ⋅ a second part (component B) comprising: at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof, provided that at least one of the Michael acceptor(s) M comprises at least one group of formula -0(CHR.sup.a—CH.sub.2O).sub.n— where n ranges from 1 to 10 (Michael acceptor M1), and R.sup.a represents CH.sub.3 or H; and a nucleophilic initiator.

The present invention concerns a two-part curable composition comprising: ⋅ a first part (component A) comprising at least 51% by weight based on the total weight of the first part, of one or more cyanoacrylate monomer(s), provided that at least one of the cyanoacrylate monomer(s) is a cyanoacrylate monomer comprising a group —X—O—R.sup.b wherein X is a linear or branched alkylene radical optionally interrupted with one or several oxygen atom(s), and R.sup.b is an alkyl group; ⋅ a second part (component B) comprising: at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof, provided that at least one of the Michael acceptor(s) M comprises at least one group of formula -0(CHR.sup.a—CH.sub.2O).sub.n— where n ranges from 1 to 10 (Michael acceptor M1), and R.sup.a represents CH.sub.3 or H; and a nucleophilic initiator.

The present invention concerns a two-part curable composition comprising: •a first part (component A) comprising: —at least 51% by weight based on the total weight of the first part, of one or more cyanoacrylate monomer(s); —a transition metal complex; and—an antioxidant; •a second part (component B) comprising: —a per-compound; —at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof; provided that the composition comprises (in the first part and/or in the second part) at least one compound C comprising a radical -EWG.sub.1-CH.sub.2-EWG.sub.2- wherein EWG.sub.2 and EWG.sub.1 are independently of each other an electron withdrawing group.

The present invention concerns a two-part curable composition comprising: •a first part (component A) comprising: —at least 51% by weight based on the total weight of the first part, of one or more cyanoacrylate monomer(s); —a transition metal complex; and—an antioxidant; •a second part (component B) comprising: —a per-compound; —at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof; provided that the composition comprises (in the first part and/or in the second part) at least one compound C comprising a radical -EWG.sub.1-CH.sub.2-EWG.sub.2- wherein EWG.sub.2 and EWG.sub.1 are independently of each other an electron withdrawing group.

The present invention refers to a curable two-part adhesive composition comprising a first part comprising one or more cyanoacrylate monomer(s), one or more (metha)acrylate monomer(s), a per-compound and, optionally, additives to control viscosity and rheology; and a second part comprising: a non-reactive diluent and a transition metal catalyst, and optionally an electron rich initiator for cyanoacrylates. It also relates to a syringe or a cartridge comprising said two-part curable composition, to the use of such composition for bonding substrates, to the use of such composition filling depressions, cracks or holes in a substrate or between substrates to a method for bonding substrates using said composition, and to a repair method for filling depressions, cracks or holes in a substrate or between substrates using said composition.

The present invention refers to a curable two-part adhesive composition comprising a first part comprising one or more cyanoacrylate monomer(s), one or more (metha)acrylate monomer(s), a per-compound and, optionally, additives to control viscosity and rheology; and a second part comprising: a non-reactive diluent and a transition metal catalyst, and optionally an electron rich initiator for cyanoacrylates. It also relates to a syringe or a cartridge comprising said two-part curable composition, to the use of such composition for bonding substrates, to the use of such composition filling depressions, cracks or holes in a substrate or between substrates to a method for bonding substrates using said composition, and to a repair method for filling depressions, cracks or holes in a substrate or between substrates using said composition.

This invention relates to cyanoacrylate-containing compositions that include, in addition to the cyanoacrylate component, a polybutylmethacrylate-polymethylmethacrylate copolymer. The inventive cyanoacrylate compositions load up to nearly a threefold increase of polybutylmethacrylate-polymethylmethacrylate copolymer over conventional polymethylmethacrylate and cured products of the inventive cyanoacrylate compositions demonstrate improved flexibility in terms of modulus (at comparable loading levels as well as increased loading levels compared to conventional polymethylmethacrylate) without compromising stability, fixture time or tensile shear strength.

This invention relates to cyanoacrylate-containing compositions that include, in addition to the cyanoacrylate component, a polybutylmethacrylate-polymethylmethacrylate copolymer. The inventive cyanoacrylate compositions load up to nearly a threefold increase of polybutylmethacrylate-polymethylmethacrylate copolymer over conventional polymethylmethacrylate and cured products of the inventive cyanoacrylate compositions demonstrate improved flexibility in terms of modulus (at comparable loading levels as well as increased loading levels compared to conventional polymethylmethacrylate) without compromising stability, fixture time or tensile shear strength.