To provide a 2-cyanoacrylate-based adhesive composition not only exhibiting an excellent adhesion rate to a metal and a thermoplastic elastomer low in polarity, but also being excellent in storage stability. A 2-cyanoacrylate-based adhesive composition containing a 2-cyanoacrylic acid ester, and a compound having a sulfur atom-containing heteroallene structure.

To provide a 2-cyanoacrylate-based adhesive composition not only exhibiting an excellent adhesion rate to a metal and a thermoplastic elastomer low in polarity, but also being excellent in storage stability. A 2-cyanoacrylate-based adhesive composition containing a 2-cyanoacrylic acid ester, and a compound having a sulfur atom-containing heteroallene structure.

Curable cyanoacrylate compositions are reported that comprise cyanoacrylate and a thermoplastic polyurethane (TPU) components. Such compositions are toughened cyanoacrylate compositions exhibiting long term viscosity stability when stored for prolonged periods at room temperature (25 C.). TPU components are reported having structural units in which at least one of the structural units has the formula OR.sup.1OArOR.sup.2O, wherein Ar is a C.sub.6-C.sub.20 aromatic group with at least one aromatic ring; R.sup.1 is a C.sub.2-C.sub.10 alkyl group; and R.sup.2 is a C.sub.2-C.sub.10 alkyl group. The thermoplastic polyurethane (TPU) component may be present in the curable cyanoacrylate composition from about 1 wt % to about 40 wt %, for example from about 2 wt % to about 30 wt %, such from about 3 wt % to about 20 wt %, suitably from about 5 wt % to about 10 wt %, based on the total weight of the composition.

A cyanoacrylate composition with thermoplastic polyurethane, formulated as a non-flowable soft solid or semi solid mass, for example in stick form, is reported.

The present application provides compositions and methods for allowing surfaces such as HDPE, LDPE, polyethylene, polypropylene, Teflon (polytetrafluoroethylene), SBS, SEBS, SIS elastomers, and silicone rubber, which are notoriously difficult to apply adhesives, glues, or coatings to, to be treated with a Primer System comprising a cyanoacrylate monomer and non-polar solvent component and an initiator component, wherein the polymerization product of the components is a microstructured polycyanoacrylate layer. The microstructured polycyanoacrylate layer-increases the ability of a glue, adhesive, or coating to adhere to that surface and subsequently allows other materials to be used as coatings on the surface or to be applied using a glue or adhesive.

The present application provides compositions and methods for allowing surfaces such as HDPE, LDPE, polyethylene, polypropylene, Teflon (polytetrafluoroethylene), SBS, SEBS, SIS elastomers, and silicone rubber, which are notoriously difficult to apply adhesives, glues, or coatings to, to be treated with a Primer System comprising a cyanoacrylate monomer and non-polar solvent component and an initiator component, wherein the polymerization product of the components is a microstructured polycyanoacrylate layer. The microstructured polycyanoacrylate layer-increases the ability of a glue, adhesive, or coating to adhere to that surface and subsequently allows other materials to be used as coatings on the surface or to be applied using a glue or adhesive.

Provided is an adhesive composition which exhibits excellent water resistance and warm-water resistance without impairing instantaneous adhesiveness. The 2-cyanoacrylate adhesive composition contains a 2-cyanoacrylic acid ester, and a specific phthalic anhydride derivative, in which the content of the phthalic anhydride derivative is from 0.01 to 5% by mass, relative to the total amount of the adhesive composition. Preferably, the adhesive composition further contains an elastomer.

Fast light curing adhesive compositions, which include cyanoacrylate or methylidene malonate monomers or mixtures thereof, and either a photoinitiator system with a combination of specific ferrocene compounds and specific acylgermane compounds or a photoinitiator system with a specific ferrocene compound substituted with acylgermane groups. The use of that light curable adhesive composition, and a package.

Cyanoacrylate compositions, methods for forming same, and applications thereof are disclosed. The compositions demonstrate improved thermal ageing performance, including improved tensile strength performance after heat ageing in high humidity.

Cyanoacrylate compositions, methods for forming same, and applications thereof are disclosed. The compositions demonstrate improved thermal ageing performance, including improved tensile strength performance after heat ageing in high humidity.