A vulcanizate is provided that includes a crosslinked network of elastomeric polymer having hydrogen bonds and covalent bonds. A method for preparing a functionalized elastomeric polymer and a method for preparing the vulcanizate are also provided.

Provided is a rubber composition that realizes excellent low heat generating properties while maintaining good steering stability when applied to a tire. The rubber composition of the present disclosure contains a rubber component containing a copolymer having a conjugated diene unit and an aromatic vinyl unit, and a filler, where the copolymer is a modified copolymer having a content of the aromatic vinyl unit of less than 10 mass % and modified with a modifier containing a compound represented by the formula (1).

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Provided is a rubber composition that realizes excellent low heat generating properties while maintaining good steering stability when applied to a tire. The rubber composition of the present disclosure contains a rubber component containing a copolymer having a conjugated diene unit and an aromatic vinyl unit, and a filler, where the copolymer is a modified copolymer having a content of the aromatic vinyl unit of less than 10 mass % and modified with a modifier containing a compound represented by the formula (1).

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A rubber composition of the present invention contains 100 parts by mass of a rubber component (A) containing 45 to 75% by mass of natural rubber and 25 to 55% by mass of a conjugated diene-based polymer, in which a bonded styrene amount of the conjugated diene compound moieties is 25% or less, 1 to 40 parts by mass of a non-modified conjugated diene-based polymer (B) which has a weight average molecular weight of 5,000 or more but less than 40,000 in terms of polystyrene as measured by GPC and in which a bonded styrene amount of the conjugated diene compound moieties is less than 10% and a bonded vinyl amount of the conjugated diene compound moieties is 20% or more, and a filler (C), in which at least one of the conjugated diene-based polymers contained in the rubber component (A) is a modified conjugated diene-based polymer. With the rubber composition, a tire having further enhanced on-ice performance and having both excellent on-ice performance and excellent abrasion resistance is obtained.

A rubber composition of the present invention contains 100 parts by mass of a rubber component (A) containing 45 to 75% by mass of natural rubber and 25 to 55% by mass of a conjugated diene-based polymer, in which a bonded styrene amount of the conjugated diene compound moieties is 25% or less, 1 to 40 parts by mass of a non-modified conjugated diene-based polymer (B) which has a weight average molecular weight of 5,000 or more but less than 40,000 in terms of polystyrene as measured by GPC and in which a bonded styrene amount of the conjugated diene compound moieties is less than 10% and a bonded vinyl amount of the conjugated diene compound moieties is 20% or more, and a filler (C), in which at least one of the conjugated diene-based polymers contained in the rubber component (A) is a modified conjugated diene-based polymer. With the rubber composition, a tire having further enhanced on-ice performance and having both excellent on-ice performance and excellent abrasion resistance is obtained.

The present invention relates to the use of N,N′,N″-substituted hexahydro-1,3,5-triazine in the anionic polymerization of conjugated diene monomer and vinylaromatic monomer. Use of this polar additive produces copolymers having both high vinylaromatic and low vinyl contents, while the blockiness of the vinylaromatic unit can be tailored.

The present invention relates to the use of N,N′,N″-substituted hexahydro-1,3,5-triazine in the anionic polymerization of conjugated diene monomer and vinylaromatic monomer. Use of this polar additive produces copolymers having both high vinylaromatic and low vinyl contents, while the blockiness of the vinylaromatic unit can be tailored.

A terpolymer of ethylene, of a first 1,3-diene having from 4 to 6 carbon atoms and of a second 1,3-diene of formula CH.sub.2═CR-CH═CH.sub.2 is provided. The terpolymer contains more than 50 mol % of ethylene units and at least 1 mol % of units of the second 1,3-diene, the symbol R representing a hydrocarbon chain having from 3 to 20 carbon atoms. Such a polymer gives an improved compromise between its ethylene content, its stiffness and its degree of crystallinity for use in tires.

A terpolymer of ethylene, of a first 1,3-diene having from 4 to 6 carbon atoms and of a second 1,3-diene of formula CH.sub.2═CR-CH═CH.sub.2 is provided. The terpolymer contains more than 50 mol % of ethylene units and at least 1 mol % of units of the second 1,3-diene, the symbol R representing a hydrocarbon chain having from 3 to 20 carbon atoms. Such a polymer gives an improved compromise between its ethylene content, its stiffness and its degree of crystallinity for use in tires.

A terpolymer of ethylene, of a first 1,3-diene having from 4 to 6 carbon atoms and of a second 1,3-diene of formula CH.sub.2═CR-CH═CH.sub.2 is provided. The terpolymer contains more than 50 mol % of ethylene units and at least 1 mol % of units of the second 1,3-diene, the symbol R representing a hydrocarbon chain having from 3 to 20 carbon atoms. Such a polymer gives an improved compromise between its ethylene content, its stiffness and its degree of crystallinity for use in tires.