A water-based polyurethane resin and a method for manufacturing the same are provided. The method for manufacturing the water-based polyurethane includes: a preparation step of a prepolymer, a dilution step of the prepolymer, a water dispersion and chain extension step, and an acrylic synthesis step. The method further includes mixing polyol and polyisocyanate to obtain a prepolymer, and diluting the prepolymer by adding acrylic monomer in the prepolymer. In the water-based polyurethane resin, at least one of the polyhydric alcohol, polyisocyanate, and the acrylic monomer includes a compound with a cyclic structure.

A sheet molding compound according to a first aspect of the present invention comprises: a thickened product of a resin composition comprising a vinyl ester resin, a thickener, a polymerization initiator, a polymerization inhibitor and isobornyl methacrylate; and a reinforcing fiber.

The present invention provides a resin composition for optical shaping that, with its low viscosity, enables easy stereolithographical fabrication of an object, and that can produce an object having desirable toughness and desirable water resistance, particularly for dental mouthpieces and denture base materials. The present invention relates to a resin composition for optical shaping comprising a urethanized (meth)acrylic compound (A) and a photopolymerization initiator (B), the urethanized (meth)acrylic compound (A) being a (meth)acrylate containing at least one polyol moiety and a urethane bond per molecule, said at least one polyol moiety being selected from the group consisting of a polyester, a polycarbonate, a polyurethane, and a polyether each having a structure derived from a C4 to C18 aliphatic chain diol unit (a) having a branched structure.

The present invention provides an ionizing radiation curable paint composition which is capable of forming a cured film that has excellent elongation (for example, 30% or more) under heating and has excellent solvent resistance and chemical resistance and which can contain an alcohol as a diluent solvent. The ionizing radiation curable paint composition contains a urethane (meth)acrylate oligomer (A1) having 6 or more (meth)acryloyl groups and having a weight average molecular weight of 3,000 to 50,000, wherein the urethane (meth)acrylate oligomer (A1) is a silicone-modified oligomer having a constituent unit (a) derived from a multifunctional (meth)acrylate monomer having a hydroxy group and 3 or more (meth)acryloyl groups, a constituent unit (b) derived from an alcohol having 2 or more hydroxy groups and having a molecular weight of 100 or lower, a constituent unit (c) derived from isophorone diisocyanate, and a constituent unit (d) derived from a carbinol-modified polysiloxane.

A reactive resin composition is described, with a resin component, which contains a radical-polymerizable compound, and an initiator system, which contains an α-halocarboxylic acid and a catalyst system, which comprises a nitrogen-containing ligand and Cu(0) or an inorganic Cu(I) compound, as is the use of the same for construction purposes.

Urethane/urea-containing bis(alkenyl) ethers can be incorporated into the backbone of polythioether prepolymers and can be used as curing agents in thiol-terminated polythioether prepolymer compositions. Cured sealants prepared using compositions containing urethane/urea-containing bis(alkenyl) ether-containing polythioether prepolymers and/or urethane/urea-containing bis(alkenyl) ether curing agents exhibit improved physical properties suitable for use in aerospace sealant applications.

A compound is described having following formula: (I) Also described is a mixture of compounds comprising the reaction product of i) a urethane compound comprising a perfluorooxyalkyl moiety and at least two (meth)acryl groups; and ii) a silane compound comprising hydrolysable groups and a group selected from amine or mercapto group; wherein i) and ii) are reacted at an equivalent ratio of excess compound i) such that (meth)acryl groups remain unreacted. Methods and articles are also described.

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Compounds useful for formulating inks, 3D printing resins, molding resins, coatings, sealants and adhesives which exhibit reduced shrinkage stress and high hardness and stiffness when cured are described which include a single free radical-polymerizable functional group, one or more urethane and/or ureido linkages and one or more cyclic structural elements per molecule.

The present invention generally relates to the field of radiation curable compositions comprising (meth)acrylated acrylic polymers comprising pendant hydroxyl groups, methods for making these radiation curable compositions and their uses.

Embodiments of the disclosure generally provide compositions and methods related to oligomeric and polymeric urethane materials that contain hydrolyzable polythioaminal groups for use in biomedical applications.