The embodiments relate to a polyester film, which comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds and a melting point of 170° C. or higher as measured by differential scanning calorimetry, which not only solve the environmental problems by improving the recyclability of the polyester container, but also are capable of enhancing the yield and productivity, and a process for regenerating a polyester container using the same.

A method of making polyesters and polyurethanes from biomass-derived polyols. The polyol is biomass-derived and has the structure: ##STR00001##
wherein dashed bonds are single or double bonds and R is selected from the group consisting of —OH and ═O. Polyurethanes are made by reacting the polyol with a diisocyanate. Polyesters are made by reacting the polyol with a dicarboxylic acid.

A method of making polyesters and polyurethanes from biomass-derived polyols. The polyol is biomass-derived and has the structure: ##STR00001##
wherein dashed bonds are single or double bonds and R is selected from the group consisting of —OH and ═O. Polyurethanes are made by reacting the polyol with a diisocyanate. Polyesters are made by reacting the polyol with a dicarboxylic acid.

The polyester film according to the embodiment prepared while the crystallinity of a copolymerized polyester film is controlled can be improved in thermal properties and chemical properties. Specifically, the polyester film has not only an excellent shrinkage rate with respect to temperature, but also excellent adhesive strength by a solvent even when applied to gravure printing, UV curing printing, and VSOP printing, making it suitable for a heat shrinkage process and a seaming process. In addition, the polyester film can be applied to a recycling process since it has an appropriate change in crystals during washing with an aqueous solution of NaOH, and the generation of fusion is suppressed even upon prolonged high-temperature drying.

A method for preparing a polycarbonate ester includes feeding a monomer mixture containing (i) at least one compound selected from the group consisting of compounds of the following Formulae 1 and 3; (ii) a compound of the following Formula 2; and (iii) a 1,4:3,6-dianhydrohexitol to a polycondensation reactor and allowing the monomers and the 1,4:3,6-dianhydrohexitol to react to prepare the polycarbontate ester. The prepared polycarbonate ester has improved mechanical properties including tensile strength and impact strength: ##STR00001##

An amorphous polyester or copolyester composition comprises the reaction product of a crystalline or semicrystalline polyester or copolyester, optionally derived from a recycled waste stream, at least one diol or aromatic diacid or an ester of a diacid or a hydroxycarboxylic acid or a lactone or a dianhydride, and a catalyst, wherein the amorphous composition has a weight average molecular weight of at least 10,000 g/mol (polystyrene equivalent molecular weight) as measured by gel permeation chromatography.

Chemically modified polyesters, foamable compositions thereof that form low density foams, and methods of making the foamable compositions and foams are disclosed. The compositions comprise an amorphous copolyester, or amorphous co-polyesterpolycarbonate or amorphous co-polyesterpolyether or combination thereof. Additionally, uses for the low density foams are disclosed.

Chemically modified polyesters, foamable compositions thereof that form low density foams, and methods of making the foamable compositions and foams are disclosed. The compositions comprise an amorphous copolyester, or amorphous co-polyesterpolycarbonate or amorphous co-polyesterpolyether or combination thereof. Additionally, uses for the low density foams are disclosed.

The present invention relates to a polyester product having a relatively high atypical density of greater than 1 g/cm.sup.3 at 25° C., the polyester product comprises the reaction product of one or more C2 to C12 polybasic acid and one or more polyol. The invention also relates to methods of making the polyester product, compositions containing or comprising the polyester product and the use of such compositions. More especially, the polyester containing compositions may advantageously be utilised in aqueous environment applications, or other applications, where environmental containment is an important consideration.

The present invention relates to a polyester product having a relatively high atypical density of greater than 1 g/cm.sup.3 at 25° C., the polyester product comprises the reaction product of one or more C2 to C12 polybasic acid and one or more polyol. The invention also relates to methods of making the polyester product, compositions containing or comprising the polyester product and the use of such compositions. More especially, the polyester containing compositions may advantageously be utilised in aqueous environment applications, or other applications, where environmental containment is an important consideration.