The present disclosure relates to a preparation method of a polyarylene sulfide, and this method may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method at a high yield by using a dihalogenated aromatic compound in a predetermined equivalent ratio with respect to a sulfur compound and performing both dehydration and polymerization under optimum conditions.

The present invention relates to a method of preparing a polyphenylene sulfide and a high-viscosity polyphenylene sulfide prepared using the method. In this method, the ratio of an organic phase to an aqueous phase is controlled by controlling dehydration conditions, so that high viscosity may be realized without adversely affecting a reaction or physical properties during preparation of the polyphenylene sulfide.

A method for forming a polyarylene sulfide is described. The method can include a multi-step cooling and precipitation process in which the cooling rate of the solution that carries the polymer is decreased during a portion of the overall cooling. This slower cooling period can encompass at least a portion of the period during which the polymer precipitates from the solution. The precipitation process can form polyarylene sulfide particles with good particle integrity and a narrow particle size distribution, which can reduce fines and improve downstream processing and final product characteristics.

A method for forming a polyarylene sulfide is described. The method can include a multi-step cooling and precipitation process in which the cooling rate of the solution that carries the polymer is decreased during a portion of the overall cooling. This slower cooling period can encompass at least a portion of the period during which the polymer precipitates from the solution. The precipitation process can form polyarylene sulfide particles with good particle integrity and a narrow particle size distribution, which can reduce fines and improve downstream processing and final product characteristics.

The present invention provides a continuous polymerization apparatus capable of simply and efficiently separating a polymer and solid matter from a reaction mixture while having an apparatus configuration conducive to washing and maintenance, and a continuous production method for a polymer. A continuous polymerization apparatus (100) includes a plurality of reaction vessels (1a to 1c), wherein the plurality of reaction vessels are configured such that reaction mixtures (9a to 9c) successively move through each reaction vessel; in the plurality of reaction vessels, gas phase parts formed above the reaction mixture communicate with one another; and the continuous polymerization apparatus includes a washing part (5), the washing part configured to separate a solid included in the reaction mixture by sedimentation and to perform countercurrent washing.

Provided are a continuous production method and a continuous production apparatus utilizing the solution polycondensation for aromatic cyclic oligomers, which achieve a good space-time yield and are inexpensive and simple. The continuous production method includes: (a) supplying a polymerization solvent and a reaction raw material to a continuous production apparatus; (b) performing a polymerization reaction in the reaction vessels to form a reaction mixture; (c) removing water in gas phase parts of the reaction vessels from the reaction vessels; and (d) successively moving the reaction mixture to each of the reaction vessels; the steps (a), (b), (c), and (d) being performed in parallel; wherein an amount of the polymerization solvent in the reaction vessel positioned furthest downstream in a movement direction of the reaction mixture is not less than 1 L and not greater than 50 L per 1 mol of arylene units in the reaction raw material.

Provided is a continuous production apparatus and a continuous production method capable of preventing the countercurrent of evaporation components generated at the time of polymerization so that continuous solution polymerization reactions can progress reliably. A continuous production apparatus (100) includes a housing chamber (2) configured to house a plurality of reaction vessels (1a to 1d); wherein a reaction mixture is formed by subjecting monomers to a polymerization reaction in a solvent in at least one of the reaction vessels; the reaction vessels communicate with one another via a gas phase part (4); the reaction vessels are sequentially connected; the reaction mixture successively moves to each of the reaction vessels; and the housing chamber includes a baffle (9) configured to narrow the cross-sectional area of the gas phase part at the boundary between at least one pair of adjacent reaction vessels or in the vicinity of the boundary.

Provided is a continuous production apparatus and a continuous production method capable of preventing the countercurrent of evaporation components generated at the time of polymerization so that continuous solution polymerization reactions can progress reliably. A continuous production apparatus (100) includes a housing chamber (2) configured to house a plurality of reaction vessels (1a to 1d); wherein a reaction mixture is formed by subjecting monomers to a polymerization reaction in a solvent in at least one of the reaction vessels; the reaction vessels communicate with one another via a gas phase part (4); the reaction vessels are sequentially connected; the reaction mixture successively moves to each of the reaction vessels; and the housing chamber includes a baffle (9) configured to narrow the cross-sectional area of the gas phase part at the boundary between at least one pair of adjacent reaction vessels or in the vicinity of the boundary.

A method for preparing a compound and a method for preparing a polymer employing the same are provided. The method for preparing a compound includes reacting a compound having a structure represented by Formula (I) with a compound having a structure represented by Formula (III) in the presence of a compound having a structure represented by Formula (II) to obtain a compound having a structure represented by Formula (IV) ##STR00001##
wherein Ar.sup.1 is substituted or unsubstituted aryl group; X is O, S, or NH; R.sup.1 is independently hydrogen or C.sub.1-6 alkyl group; R.sup.2 is hydroxyl group, C.sub.1-6 alkyl group, phenyl group, or tolyl group; and R.sup.3 is independently C.sub.1-6 alkyl group, C.sub.5-8 cycloalkyl group, or C.sub.2-6 alkoxyalkyl group.

A method for preparing a compound and a method for preparing a polymer employing the same are provided. The method for preparing a compound includes reacting a compound having a structure represented by Formula (I) with a compound having a structure represented by Formula (III) in the presence of a compound having a structure represented by Formula (II) to obtain a compound having a structure represented by Formula (IV) ##STR00001##
wherein Ar.sup.1 is substituted or unsubstituted aryl group; X is O, S, or NH; R.sup.1 is independently hydrogen or C.sub.1-6 alkyl group; R.sup.2 is hydroxyl group, C.sub.1-6 alkyl group, phenyl group, or tolyl group; and R.sup.3 is independently C.sub.1-6 alkyl group, C.sub.5-8 cycloalkyl group, or C.sub.2-6 alkoxyalkyl group.