A polymerizable composition for an optical material includes an episulfide compound (A); an organic coloring matter (B); an UV absorber (C); and a polymerization catalyst (D), wherein the organic coloring matter (B) has a main absorption peak (P) between 565 nm and 605 nm in a visible light absorption spectrum, an absorption coefficient (ml/g.Math.cm) of a peak apex (Pmax) exhibiting a maximum absorption coefficient of (P) is equal to or greater than 0.5105, a peak width in an absorbance of of an absorbance of (Pmax) of (P) is equal to or less than 50 nm, a peak width in an absorbance of of the absorbance of (Pmax) of (P) is equal to or less than 30 nm, and a peak width in an absorbance of of the absorbance of (Pmax) of (P) is in a range of equal to or less than 20 nm.

A method for setting polymerization condition includes a physical property acquiring step of, when heating a composition including a polymerization-reactive compound and a polymerization catalyst and/or a polymerization initiator and retaining heat at a predetermined temperature, acquiring a physical property value a derived from a functional group before heating of the polymerization-reactive compound and a physical property value b derived from a remaining functional group after maintaining a temperature for a predetermined time; a remaining functional group ratio calculating step of calculating a remaining functional group ratio from the physical property value a and the physical property value b; a reaction rate coefficient calculating step of calculating a reaction rate coefficient from the remaining functional group ratio on the basis of a reaction rate equation; and a polymerization temperature calculating step of calculating a polymerization temperature on the basis of the reaction rate coefficient and conditions below.

A method for setting polymerization condition includes a physical property acquiring step of, when heating a composition including a polymerization-reactive compound and a polymerization catalyst and/or a polymerization initiator and retaining heat at a predetermined temperature, acquiring a physical property value a derived from a functional group before heating of the polymerization-reactive compound and a physical property value b derived from a remaining functional group after maintaining a temperature for a predetermined time; a remaining functional group ratio calculating step of calculating a remaining functional group ratio from the physical property value a and the physical property value b; a reaction rate coefficient calculating step of calculating a reaction rate coefficient from the remaining functional group ratio on the basis of a reaction rate equation; and a polymerization temperature calculating step of calculating a polymerization temperature on the basis of the reaction rate coefficient and conditions below.

Provided is a composition for optical materials that gives optical materials which can have at least one improved property selected from among satisfactory mold releasability after polymerization and curing, unsusceptibility to separation from the mold during polymerization and curing, transparency, and low-level striae. The present invention further provides a compound represented by formula (1). The composition for optical materials comprises the compound represented by formula (1) and a compound represented by formula (2). (In formula (1), X.sub.1 and X.sub.2 represent O or S, provided that both X.sub.1 and X.sub.2 are O or that X.sub.1 is O and X.sub.2 is S.) ##STR00001##

Provided is a composition for optical materials that gives optical materials which can have at least one improved property selected from among satisfactory mold releasability after polymerization and curing, unsusceptibility to separation from the mold during polymerization and curing, transparency, and low-level striae. The present invention further provides a compound represented by formula (1). The composition for optical materials comprises the compound represented by formula (1) and a compound represented by formula (2). (In formula (1), X.sub.1 and X.sub.2 represent O or S, provided that both X.sub.1 and X.sub.2 are O or that X.sub.1 is O and X.sub.2 is S.) ##STR00001##

The present invention makes it possible to provide an optical material composition containing an episulfide compound (A), a polythiol compound (B), and a photochromic compound (C). The episulfide compound (A) is preferably a compound represented by formula (1), and the polythiol compound (B) is preferably a compound represented by formula (6). ##STR00001##
(In formula (1), m represents an integer of 0 to 4, and n represents an integer of 0 to 2.) ##STR00002##
(In formula (6), n represents an integer of 4 to 20, and R.sub.1 and R.sub.2 may be the same or different and represent H, SH, C.sub.1-10 alkyl groups, or C.sub.1-10 alkylthiol groups.)

The present invention makes it possible to provide an optical material composition containing an episulfide compound (A), a polythiol compound (B), and a photochromic compound (C). The episulfide compound (A) is preferably a compound represented by formula (1), and the polythiol compound (B) is preferably a compound represented by formula (6). ##STR00001##
(In formula (1), m represents an integer of 0 to 4, and n represents an integer of 0 to 2.) ##STR00002##
(In formula (6), n represents an integer of 4 to 20, and R.sub.1 and R.sub.2 may be the same or different and represent H, SH, C.sub.1-10 alkyl groups, or C.sub.1-10 alkylthiol groups.)

The present invention features linear and three-dimensional supramolecular materials self-assembled from block co-polymers comprising oligo(ethylene sulfide) (OES). The block copolymers assemble into fibrils, micelles, or matrices. The fibrillar materials are sensitive to oxidation, which leads to decreased OES block hydrophobicity and crystallinity, and increased water solubility of the polymer constituents. Molecular loading options, coupled with oxidative sensitivity, allow implantable or injectable fibrillar suspensions or cross-linked three-dimensional matrices to demonstrate significant biomedical potential, especially in the context of extracellular and intracellular molecular delivery and applications related to infection and disease.

The present invention features linear and three-dimensional supramolecular materials self-assembled from block co-polymers comprising oligo(ethylene sulfide) (OES). The block copolymers assemble into fibrils, micelles, or matrices. The fibrillar materials are sensitive to oxidation, which leads to decreased OES block hydrophobicity and crystallinity, and increased water solubility of the polymer constituents. Molecular loading options, coupled with oxidative sensitivity, allow implantable or injectable fibrillar suspensions or cross-linked three-dimensional matrices to demonstrate significant biomedical potential, especially in the context of extracellular and intracellular molecular delivery and applications related to infection and disease.

Provided an optical material composition which makes it possible to design an optical material exhibiting a broad range of properties. This optical material composition contains a compound (A) represented by formula (1) and a polythiol (a), and does not contain 1,2,3,5,6-pentathiepane (b).

##STR00001##