The invention provides for polymer structures and their preparation and resulting novel functionalities including open-shell character and high intrinsic conductivity with wide-range tenability. Electrical conductivity can be further modulated by introducing or blending with materials, fillers, dopants, and/or additives. The materials or resultant composites of the invention can be processed by various techniques into different forms to realize multiple applications.

Embodiments may relate to a microelectronic package comprising: a die and a package substrate coupled to the die with a first interconnect on a first face. The package substrate comprises: a second interconnect and a third interconnect on a second face opposite to the first face; a conductive signal path between the first interconnect and the second interconnect; a conductive ground path between the second interconnect and the third interconnect; and an electrostatic discharge (ESD) protection material coupled to the conductive ground path. The ESD protection material comprises a first electrically-conductive carbon allotrope having a first functional group, a second electrically-conductive carbon allotrope having a second functional group, and an electrically-conductive polymer chemically bonded to the first functional group and the second functional group permitting an electrical signal to pass between the first and second electrically-conductive carbon allotropes.

The present invention relates to polymers comprising a repeating unit of the formula—[Ar.sup.3].sub.c—[Ar.sup.2].sub.b—[Ar.sup.1].sub.a—Y(R.sup.1).sub.n1 (R.sup.2).sub.n2—[Ar.sup.1′].sub.a—[Ar.sup.2′].sub.b′—[Ar.sup.3′].sub.c′— (I), wherein γ is a bivalent heterocyclic group, or ring system, which may optionally be substituted, Ar.sup.1, Ar.sup.1′Ar.sup.2, Ar.sup.2′, Ar.sup.3 and Ar.sup.3′ are independently of each other a C.sub.6-C.sub.24 arylen group, which can optionally be substituted, or a C.sub.2-C.sub.30 heteroarylen group, which can optionally be, Formula (1), substituted; at least one of R1 and R2 is a group of formula (II); and their use as organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes. ##STR00001##

The present invention relates to a polymer, an organic solar cell comprising the polymer, and a perovskite solar cell comprising the polymer. The polymer according to the present invention has excellent absorption ability for visible light and an energy level suitable for the use as an electron donor compound in a photo-active layer of the organic solar cell, thereby increasing the light conversion efficiency of the organic solar cell. In addition, the polymer according to the present invention has high hole mobility, and is used as a compound for a hole transport layer, and thus can improve efficiency and service life of the perovskite solar cell without an additive.

In an embodiment, a composition is provided that includes an indenofluorene moiety; an alkyl radical, an aryl radical, or a heteroaryl radical chemically bound to the indenofluorene moiety; and an electron donor moiety bound to the indenofluorene moiety. In another embodiment, a device is provided that includes compositions described herein. In another embodiment, a method of forming a donor-acceptor small molecule or a donor-acceptor copolymer is provided that includes forming an indenofluorene moiety; forming an electron donor moiety; and reacting the indenofluorene moiety with the electron donor moiety in a cross-coupling reaction.

The present specification relates to a composition for an organic material layer of an organic solar cell including an electron donor including a polymer including a first unit represented by Chemical Formula 1, a second unit represented by Chemical Formula 2, and a third unit represented by Chemical Formula 3 or 4; and a non-fullerene-based electron acceptor, and an organic solar cell including the composition.

The present invention discloses a conjugated polymer, which is a random copolymer, and with Formula I: ##STR00001##
Additionally, the present invention also discloses an organic photovoltaic device comprising the conjugated polymer.

A method of reacting bis(R.sub.1) 5,5′″-dibromo-3″,4′-difluoro-[2,2′:5′,2″:5″,2′″-quaterthiophene]-3,3′″-dicarboxylate and bis(R.sub.2) 5,5′″-dibromo-3″,4′-difluoro-[2,2′:5′,2″:5″,2′″-quaterthiophene]-3,3′″-dicarboxylate to form the polymer: ##STR00001## In this polymer R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently selected from the group consisting of: a halogen, a substituted alkyl, an unsubstituted alkyl, a substituted aryl, an unsubstituted aryl, a substituted heteroaryl and an unsubstituted heteroaryl.

Embodiments may relate to a material to provide electrostatic discharge (ESD) protection in an electrical device. The material may include first and second electrically-conductive carbon allotropes. The material may further include an electrically-conductive polymer that is chemically bonded to the first and second electrically-conductive carbon allotropes such that an electrical signal may pass between the first and second electrically-conductive carbon allotropes. Other embodiments may be described or claimed.

Electrochromic polymers include conjugated chromophores in spaced relation with one another, and conjugation-break spacers (CBSs). At least one CBS separates adjacent chromophores. The chromophores may be colored in the neutral state, and multicolored to transmissive in different oxidization states.