C08J2325/08

HYDROGENATED BLOCK COPOLYMER COMPOSITION, METHOD FOR PRODUCING SAME, AND FILM
20220289890 · 2022-09-15 · ·

Provided is a hydrogenated block copolymer composition comprising a hydrogenated block copolymer A represented by General Formula (A) and a hydrogenated block copolymer B represented by General Formula (B), wherein the weight ratio (A/B) of the hydrogenated block copolymer A to the hydrogenated block copolymer B is 10/90 to 80/20, and the hydrogenation ratio of olefins in the polymer components constituting the hydrogenated block copolymer composition is 10 to 100%:


Ar1.sup.a-HD.sup.a-Ar2.sup.a  (A)


Ar1.sup.b-HD.sup.b-A2.sup.b  (B)

wherein in General Formulae (A) and (B) above, Ar1.sup.a, Ar1.sup.b, Ar2.sup.a, and Ar2.sup.b are each an aromatic vinyl polymer block, HD.sup.a and HD.sup.b are each a hydrogenated polymer block of a conjugated diene polymer, and the ratio (Mw(Ar2.sup.a)/Mw(Ar1.sup.a)) of the weight average molecular weight of Ar2.sup.a (Mw(Ar2.sup.a)) to the weight average molecular weight of Ar1.sup.a (Mw(Ar1.sup.a)) is 2.6 to 66.

Glass mat reinforcement

A glass mat is provided. The glass mat includes an assembly of glass fibers; and a binder composition including a polymer resin and a crosslinker. The polymer resin has a pH of at least about 5.0. The polymer resin includes a styrenic copolymer, an acrylic copolymer, or combination thereof having at least one functional group of a carboxylic acid, a salt of a carboxylic acid, an anhydride, a salt of an anhydride, or combination thereof. The crosslinker includes a polyol, a polyepoxy, a polycarbodiimide, a polyaziridine, a bivalent metal carbonate, or combination thereof. Further provided is a method of making the glass mat.

Coated particles and production method therefor

A coated particle according to the present invention is a coated particle containing a conductive metal-coated particle having a metal film formed on a surface of a core material, the conductive metal-coated particle coated with an insulation layer containing a polymer, wherein the insulation layer has a phosphonium group. The insulation layer preferably contains an insulating fine particle and the fine particle has a phosphonium group on a surface thereof, or the insulation layer is preferably a film having a phosphonium group. In addition, the metal is preferably at least one selected from nickel, gold, nickel alloys, and gold alloys. The polymer constituting the insulation layer is preferably at least one polymerized product selected from styrenes, esters, and nitriles.

Thermosetting resin composition and prepreg and metal foil-covered laminate made using same

A thermosetting resin composition and a prepreg and a metal foil-covered laminate made using same, the thermosetting resin composition comprising component (A): a solvent-soluble polyfunctional vinyl aromatic copolymer, the copolymer being a poly-functional vinyl aromatic copolymer having a stoctoal unit derived from monomers comprising divinyl aromatic compound (a) and ethyl vinyl aromatic compound (b); and component (B): a vinyl-containing organic silicone resin. The prepreg and metal foil-covered laminate made from the thermosetting resin composition have good toughness, and maintain a high glass transition temperature, a low water absorption, dielectric properties and humidity resistance, being suitable for the field of high-frequency and high-speed printed circuit boards and the processing of multilayer printed circuit boards.

Block copolymer containing photo-sensitive moiety

A block copolymer and a use thereof are disclosed herein. The block copolymer of the present application may have excellent self-assembly properties or phase separation characteristics and simultaneously have characteristics capable of changing the self-assembly structure formed once, or provide a block copolymer capable of forming a pattern of phase separation structures in a polymer membrane.

Expandable vinyl aromatic polymers

The present invention is related to expandable vinyl aromatic polymers comprising comminuted coke, said comminuted coke having an average stack height (Lc) of carbon crystallites at least 4 nm, a volume median particle diameter (D50) comprised between 1 and less than 5 μm and being characterized by a span (D90−D10)/D50 below 2.5 Molded parts produced from the expandable vinyl aromatic polymers prove low thermal conductivities for a low foam density.

FOAMS AND METHOD OF FORMING FOAMS OF IONOMERS OF COPOLYMERS OF VINYLIDENE AROMATIC MONOMER AND UNSATURATED COMPOUNDS WITH ACID GROUPS
20220010087 · 2022-01-13 ·

A foaming composition useful to make an extruded foam is comprised of comprising a plurality of chains of a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated acids, the copolymer having about 0.01 to about 15.0 percent by weight of the one or more unsaturated acids wherein the acid groups are pendant from the copolymer a metal salt, metal oxide or combination thereof, the metal having a valence of at least 2; and one or more blowing agents. The foaming composition may be made into a foam by heating the foaming composition to a temperature sufficient to melt and ionically crosslink said copolymer which is then extruded through a die forming a foam. The foam is comprised of an ionically crosslinked aforementioned copolymer, wherein the copolymer is crosslinked through ionic bonds between the unsaturated acids and the metal of the metal salt or metal oxide.

Method for preparing modified thermoplastics having germ-repellent properties and a product thereof, and a composition for preparing the modified thermoplastics

This disclosure discloses a preparing method of transforming commercial base thermoplastics into germ-repellent resins or functional masterbatch through plasma and (melt)mixing assisted grafting process. The resins or masterbatch concentrate composition enable a number of product reforming processes, including but not limited to thermoforming, profile extrusion, injection molding, blow molding, blow filming, film casting, and spinning into articles of different shapes and geometries or overmolding on plastic substrates that can resist surface adsorption of microbes after solidification.

THERMALLY STABLE HYDROCARBON-BASED ANION EXCHANGE MEMBRANE AND IONOMERS

An anion exchange membrane is composed of a copolymer of 1,1-diphenylethylene and one or more styrene monomers, such as 4-tert-butylstyrene. The copolymer includes a backbone substituted with a plurality of ionic groups coupled to phenyl groups on the backbone via hydrocarbyl tethers between about 1 and about 7 carbons in length. High-temperature conditions enabled by these copolymers enhance conductivity performance, making them particularly suitable for use in anion exchange membranes in fuel cells, electrolyzers employing hydrogen, ion separations, etc. The properties of the membranes can be tuned via the degree of functionalization of the phenyl groups and selection of the functional groups, such as quaternary ammonium groups. Several processes can be used to incorporate the desired ionic functional groups into the polymers, such as chloromethylation, radical bromination, Friedel-Crafts acylation and alkylation, sulfonation followed by amination, or combinations thereof.