Provided is a water-soluble film for molding a packaging capsule which is capable of enclosing chemical agents especially a detergent, has a robust property that prevents leakage of the detergent through suitable thickness and strength and an easy-processing property that keeps robustness not to make a drawn portion break in mold-processing such as deep drawing, further has a soluble resistance that does not make the chemical agent elute within 30 seconds in water at 20° C. and a complete-solubility property within a short period of time in dish-washing and clothes-washing, also has sufficient solubility and complete-solubility properties for film portions around the perimeter edge pasted with a water-soluble film for a top, and exhibits a strong-sealing property to have a temporal stability.

A water-soluble film comprises one or more kinds of anion-group-modified polyvinyl alcohols including repeating units from a fatty acid vinyl ester comonomer and anion-group-containing repeating units, in which a degree of saponification thereof is set from 91 mol% or more to 99 mol% or less and a degree of modification by anion groups is set from 1.0 mol% or more to 6.0 mol% or less so that an amount of anion-group modification is set from 1.0 mol% or more to 3.5 mo%l or less to a total amount of the anion-group-modified polyvinyl alcohols, and are formed by including less than 45 parts by mass of a plasticizer per 100 parts by mass of a total amount of the anion-group-modified polyvinyl alcohols, and have a tensile modulus of 100 MPa or less.

Provided is a water-soluble film for molding a packaging capsule which is capable of enclosing chemical agents especially a detergent, has a robust property that prevents leakage of the detergent through suitable thickness and strength and an easy-processing property that keeps robustness not to make a drawn portion break in mold-processing such as deep drawing, further has a soluble resistance that does not make the chemical agent elute within 30 seconds in water at 20° C. and a complete-solubility property within a short period of time in dish-washing and clothes-washing, also has sufficient solubility and complete-solubility properties for film portions around the perimeter edge pasted with a water-soluble film for a top, and exhibits a strong-sealing property to have a temporal stability.

A water-soluble film comprises one or more kinds of anion-group-modified polyvinyl alcohols including repeating units from a fatty acid vinyl ester comonomer and anion-group-containing repeating units, in which a degree of saponification thereof is set from 91 mol% or more to 99 mol% or less and a degree of modification by anion groups is set from 1.0 mol% or more to 6.0 mol% or less so that an amount of anion-group modification is set from 1.0 mol% or more to 3.5 mo%l or less to a total amount of the anion-group-modified polyvinyl alcohols, and are formed by including less than 45 parts by mass of a plasticizer per 100 parts by mass of a total amount of the anion-group-modified polyvinyl alcohols, and have a tensile modulus of 100 MPa or less.

Provided is a water-soluble film for molding a packaging capsule which is capable of enclosing chemical agents especially a detergent, has a robust property that prevents leakage of the detergent through suitable thickness and strength and an easy-processing property that keeps robustness not to make a drawn portion break in mold-processing such as deep drawing, further has a soluble resistance that does not make the chemical agent elute within 30 seconds in water at 20° C. and a complete-solubility property within a short period of time in dish-washing and clothes-washing, also has sufficient solubility and complete-solubility properties for film portions around the perimeter edge pasted with a water-soluble film for a top, and exhibits a strong-sealing property to have a temporal stability.

A water-soluble film comprises one or more kinds of anion-group-modified polyvinyl alcohols including repeating units from a fatty acid vinyl ester comonomer and anion-group-containing repeating units, in which a degree of saponification thereof is set from 91 mol% or more to 99 mol% or less and a degree of modification by anion groups is set from 1.0 mol% or more to 6.0 mol% or less so that an amount of anion-group modification is set from 1.0 mol% or more to 3.5 mo%l or less to a total amount of the anion-group-modified polyvinyl alcohols, and are formed by including less than 45 parts by mass of a plasticizer per 100 parts by mass of a total amount of the anion-group-modified polyvinyl alcohols, and have a tensile modulus of 100 MPa or less.

An inorganic nanomaterial for continuous formaldehyde removal includes the following components in part by mass: 20-30 parts of water, 0.1-0.3 parts of cellulose, 0.1-0.2 parts of a defoamer, 0.3-0.6 parts of a dispersant, 0.3-0.6 parts of a wetting agent, 20-25 parts of titanium dioxide, 5-10 parts of kaolin, 10-15 parts of heavy calcium, 30-40 parts of modified inorganic hybrid resin, 0.1-1 part of a film-forming additive, and 0.1-1 part of propylene glycol. After inorganic hybrid modification, an ammonia group is introduced, which can continuously and effectively decompose formaldehyde in the environment. A coating film not only has good anti-mildew, anti-algae, fire prevention, and heat insulation functions, but also has a continuous formaldehyde removal function. The formaldehyde removal efficiency is greater than 95%. The durability of formaldehyde purification effect is 90%.

Systems, devices, and methods are provided for producing a 3d-printable composite material for large scale printing. A method can include receiving a first component comprising a (meth)acrylic monomer or a (meth)acrylic oligomer, or a combination thereof. The method can include receiving a second component comprising a photoinitiator and a third component comprising a polymerization enhancer. The method can include mixing the first component, second component, and third component with a mixing reactor to form a mixture. The method can include filtering the mixture with a filtration unit and removing a solid residue from the mixture. The method can include curing the filtered mixture with a radiation unit into a gel component and a liquid component. The method can include separating the gel component with a phase separation unit and then milling the gel component. And the method can include mixing the gel component, the photoinitiator, the mineral filler and optionally the recycled previously printed composite material to form the composite material.

According to one embodiment, a high-definition and decolorable image is formed. A method for producing a colorable material according to an embodiment includes supplying a first solution containing a color developable agent and a first solvent to a color developing agent in the form of a powder which is insoluble in the first solvent so that a first mixture of the first solution and the color developing agent maintains the powder state, and removing the first solvent from the first mixture, thereby obtaining a powder of colorable particles containing the color developable agent and the color developing agent.

According to one embodiment, a high-definition and decolorable image is formed. A method for producing a colorable material according to an embodiment includes supplying a first solution containing a color developable agent and a first solvent to a color developing agent in the form of a powder which is insoluble in the first solvent so that a first mixture of the first solution and the color developing agent maintains the powder state, and removing the first solvent from the first mixture, thereby obtaining a powder of colorable particles containing the color developable agent and the color developing agent.

A self-healing polymer network containing a physical crosslinking agent, a composition therefor, and an optical element comprising the same is provided. The self-healing polymer network comprises a polymer derived from monomers including self-healing monomers each having a first polymerizable functional group and at least one of urethane, urea, or amide group chemically linked to the first polymerizable functional group, wherein the polymer has a backbone formed by polymerizing the first polymerizable functional groups of the self-healing monomers and a plurality of side groups each having at least one of urethane, urea, or amide group chemically linked to the backbone. In addition, the self-healing polymer network comprises a physical crosslinking agent which is an alcohol mixture having at least two of monool, diol, triol, and tetraol or the higher polyol and crosslinking the polymer by physically crosslinking the urethane, urea, or amide group of the side groups.

A self-healing polymer network containing a physical crosslinking agent, a composition therefor, and an optical element comprising the same is provided. The self-healing polymer network comprises a polymer derived from monomers including self-healing monomers each having a first polymerizable functional group and at least one of urethane, urea, or amide group chemically linked to the first polymerizable functional group, wherein the polymer has a backbone formed by polymerizing the first polymerizable functional groups of the self-healing monomers and a plurality of side groups each having at least one of urethane, urea, or amide group chemically linked to the backbone. In addition, the self-healing polymer network comprises a physical crosslinking agent which is an alcohol mixture having at least two of monool, diol, triol, and tetraol or the higher polyol and crosslinking the polymer by physically crosslinking the urethane, urea, or amide group of the side groups.

The invention relates to a method for stabilizing halogen-free thermoplastic recyclates or pre-damaged plastics against oxidative, thermal, and/or actinic degradation. In the method according to the invention, at least one alditol or cyclitol is introduced into a halogen-free thermoplastic recyclate as a component, and optionally in addition thereto, at least one primary antioxidant and/or at least one secondary antioxidant is introduced into a halogen-free thermoplastic recyclate. By virtue of the method according to the invention, plastic recyclates can be stabilized against oxidative, thermal, and/or actinic degradation with a high degree of effectiveness and in a very environmentally friendly and inexpensive manner. The invention additionally relates to corresponding recyclate-based plastic compositions, to molding compound and molded parts produced therefrom, to stabilizer compositions, and to the use thereof for stabilizing halogen-free thermoplastic recyclates against oxidative, thermal, and/or actinic degradation.