The present invention provides a process for preparing sulfur-containing branched organosilane polymers comprising: reacting sulfur with a vinyl silane compound in a solvent and in the presence of a catalytic amount of an accelerator at an elevated temperature of at least 40° C. The process, and the organosilane polymers obtained by using the process, are very suitable for application in battery technologies.

The present invention provides a process for preparing sulfur-containing branched organosilane polymers comprising: reacting sulfur with a vinyl silane compound in a solvent and in the presence of a catalytic amount of an accelerator at an elevated temperature of at least 40° C. The process, and the organosilane polymers obtained by using the process, are very suitable for application in battery technologies.

A rubber-steel cord composite according to an embodiment is formed by vulcanizing and bonding a rubber composition containing 1 to 10 parts by mass of sulfur, 0.1 to 5 parts by mass of N,N-dibenzylbenzothiazole-2-sulfenamide, and 0.1 to 5 parts by mass of either one or both of hexamethylene bis-thiosulfate disodium salt dihydrate and 1,6-bis(N,N-dibenzylthiocarbamoyldithio)hexane, with respect to 100 parts by mass of diene rubber containing natural rubber, and a steel cord. A pneumatic tire according to an embodiment includes the rubber-steel cord composite.

A rubber-steel cord composite according to an embodiment is formed by vulcanizing and bonding a rubber composition containing 1 to 10 parts by mass of sulfur, 0.1 to 5 parts by mass of N,N-dibenzylbenzothiazole-2-sulfenamide, and 0.1 to 5 parts by mass of either one or both of hexamethylene bis-thiosulfate disodium salt dihydrate and 1,6-bis(N,N-dibenzylthiocarbamoyldithio)hexane, with respect to 100 parts by mass of diene rubber containing natural rubber, and a steel cord. A pneumatic tire according to an embodiment includes the rubber-steel cord composite.

Provided is a rubber composition having a high vulcanization rate and excellent in storage stability. The rubber composition contains a rubber component that contains at least one type of a dienic rubber, a filler, a vulcanizing agent, a compound represented by a formula (1), a compound represented by a formula (2), and a vulcanization accelerator except the compound represented by the formula (1), wherein the total amount of the vulcanization accelerator and the compound represented by the formula (1) is 1.3 to 2.0 parts by mass relative to 100 parts by mass of the rubber component. ##STR00001##

Provided is a rubber composition having a high vulcanization rate and excellent in storage stability. The rubber composition contains a rubber component that contains at least one type of a dienic rubber, a filler, a vulcanizing agent, a compound represented by a formula (1), a compound represented by a formula (2), and a vulcanization accelerator except the compound represented by the formula (1), wherein the total amount of the vulcanization accelerator and the compound represented by the formula (1) is 1.3 to 2.0 parts by mass relative to 100 parts by mass of the rubber component. ##STR00001##

Provided is a rubber composition having a high vulcanization rate and excellent in storage stability. The rubber composition contains a rubber component that contains at least one type of a dienic rubber, a filler, a vulcanizing agent, a compound represented by a formula (1), a compound represented by a formula (2), and a vulcanization accelerator except the compound represented by the formula (1), wherein the total amount of the vulcanization accelerator and the compound represented by the formula (1) is 1.3 to 2.0 parts by mass relative to 100 parts by mass of the rubber component. ##STR00001##

A curable polymer latex composition obtainable by: (a) subjecting a monomer mixture comprising i. at least one conjugated diene; ii. at least one ethylenically unsaturated nitrile; iii. optionally at least one ethylenically unsaturated acid; iv. optionally at least one further ethylenically unsaturated compound different from any of the compounds (i)-(iii); to free-radical emulsion polymerization in an aqueous reaction medium to form a raw polymer latex; and (b) allowing the obtained raw latex to mature in the presence of at least one thiocarbonyl-functional compound, wherein the at least one thiocarbonyl-functional compound is present in an amount of at least 0.05 wt.-%, based on the total amount of monomers subjected to free-radical emulsion polymerization in step (a), and (c) optionally compounding the matured polymer latex with one or more cross-linking agent. Methods for making such curable polymer latex composition or rubber articles made therefrom, respectively.

A curable polymer latex composition obtainable by: (a) subjecting a monomer mixture comprising i. at least one conjugated diene; ii. at least one ethylenically unsaturated nitrile; iii. optionally at least one ethylenically unsaturated acid; iv. optionally at least one further ethylenically unsaturated compound different from any of the compounds (i)-(iii); to free-radical emulsion polymerization in an aqueous reaction medium to form a raw polymer latex; and (b) allowing the obtained raw latex to mature in the presence of at least one thiocarbonyl-functional compound, wherein the at least one thiocarbonyl-functional compound is present in an amount of at least 0.05 wt.-%, based on the total amount of monomers subjected to free-radical emulsion polymerization in step (a), and (c) optionally compounding the matured polymer latex with one or more cross-linking agent. Methods for making such curable polymer latex composition or rubber articles made therefrom, respectively.

A curable polymer latex composition obtainable by: (a) subjecting a monomer mixture comprising i. at least one conjugated diene; ii. at least one ethylenically unsaturated nitrile; iii. optionally at least one ethylenically unsaturated acid; iv. optionally at least one further ethylenically unsaturated compound different from any of the compounds (i)-(iii); to free-radical emulsion polymerization in an aqueous reaction medium to form a raw polymer latex; and (b) allowing the obtained raw latex to mature in the presence of at least one thiocarbonyl-functional compound, wherein the at least one thiocarbonyl-functional compound is present in an amount of at least 0.05 wt.-%, based on the total amount of monomers subjected to free-radical emulsion polymerization in step (a), and (c) optionally compounding the matured polymer latex with one or more cross-linking agent. Methods for making such curable polymer latex composition or rubber articles made therefrom, respectively.