The present invention relates to elastomeric compositions for tyres and relative compounds, components and tyres comprising them, said compositions comprising an elastomeric polymer, a phenolic product, optionally already partially cross-linked, optionally an aldehyde and/or at least a methylene donor product and an oxidised carbon allotrope as a cross-linking catalyst. Advantageously, this catalyst is able to complete the cross-linking reactions of the phenolic resins in the conventional times and conditions of vulcanisation, or even more rapidly, providing mechanically stable compounds.

A tire whose tread consists totally or partly of a rubber composition which comprises at least 80 phr of a copolymer of ethylene and of a 1,3-diene which contains at least 70 mol % of ethylene units, between 25 phr and 55 phr of a carbon black, less than 1 phr of sulfur and a vulcanization accelerator is provided. The carbon black representing more than 60% by mass of the reinforcing filler of the rubber composition, the mass ratio between the sulfur content and the amount of vulcanization accelerator in the rubber composition being less than 1. The vulcanization accelerator is a primary accelerator or a mixture of a primary accelerator and of a secondary accelerator. Such a composition has good cohesion properties.

A tire whose tread consists totally or partly of a rubber composition which comprises at least 80 phr of a copolymer of ethylene and of a 1,3-diene which contains at least 70 mol % of ethylene units, between 25 phr and 55 phr of a carbon black, less than 1 phr of sulfur and a vulcanization accelerator is provided. The carbon black representing more than 60% by mass of the reinforcing filler of the rubber composition, the mass ratio between the sulfur content and the amount of vulcanization accelerator in the rubber composition being less than 1. The vulcanization accelerator is a primary accelerator or a mixture of a primary accelerator and of a secondary accelerator. Such a composition has good cohesion properties.

An NBR composition for rubber laminated metal having 1 to 3 parts by weight of sulfur and 1 to 15 parts by weight of a disulfide compound such as 4,4′-dithiodimorpholine or dithiodicaprolactam represented by the general formula RN—S—S—NR (wherein RN is a cyclic linking group formed together with the N atom bonded to the S atom), based on 100 parts by weight of NBR. The rubber composition that can improve the protrusion properties of a rubber layer when used for, for example, a gasket or a brake shim material that is a laminated composite metal laminated with another metal plate.

An NBR composition for rubber laminated metal having 1 to 3 parts by weight of sulfur and 1 to 15 parts by weight of a disulfide compound such as 4,4′-dithiodimorpholine or dithiodicaprolactam represented by the general formula RN—S—S—NR (wherein RN is a cyclic linking group formed together with the N atom bonded to the S atom), based on 100 parts by weight of NBR. The rubber composition that can improve the protrusion properties of a rubber layer when used for, for example, a gasket or a brake shim material that is a laminated composite metal laminated with another metal plate.

An NBR composition for rubber laminated metal having 1 to 3 parts by weight of sulfur and 1 to 15 parts by weight of a disulfide compound such as 4,4′-dithiodimorpholine or dithiodicaprolactam represented by the general formula RN—S—S—NR (wherein RN is a cyclic linking group formed together with the N atom bonded to the S atom), based on 100 parts by weight of NBR. The rubber composition that can improve the protrusion properties of a rubber layer when used for, for example, a gasket or a brake shim material that is a laminated composite metal laminated with another metal plate.

An object of the present disclosure is to provide a rubber composition containing an organic sulfur compound from which a molded product having a high hardness can be obtained. The present disclosure provides a rubber composition containing (a) a base rubber, (b) a co-crosslinking agent, (c) a crosslinking initiator, (d) a benzothiazole derivative, and (e) an organic sulfur compound, wherein (d) the benzothiazole derivative is a compound represented by the formula (1) and/or a compound represented by the formula (2).

##STR00001## [R.sup.1 represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an aryl group having 4 to 14 carbon atoms, or a metal atom, R.sup.2 to R.sup.5 are identical to or different from each other, and represent an electron-withdrawing group or a hydrogen atom, and at least one of R.sup.3 to R.sup.5 is an electron-withdrawing group.]

Provided is a thermoplastic elastomer composition capable of producing a molded article having a good appearance such as surface smoothness and excellent bondability to another member, the thermoplastic elastomer composition comprising: an ethylene-based polymer (A); and a propylene-based polymer (B), wherein a melt viscosity of the thermoplastic elastomer composition measured at a temperature of 220° C. and a shear rate of 12 sec.sup.−1 is 2,500 Pa.Math.sec or less; the thermoplastic elastomer composition has a sea-island structure; and an island portion has a volume average particle diameter of 2.1 μm or more and a particle diameter dispersion D of 7.0 or less.

Provided is a thermoplastic elastomer composition capable of producing a molded article having a good appearance such as surface smoothness and excellent bondability to another member, the thermoplastic elastomer composition comprising: an ethylene-based polymer (A); and a propylene-based polymer (B), wherein a melt viscosity of the thermoplastic elastomer composition measured at a temperature of 220° C. and a shear rate of 12 sec.sup.−1 is 2,500 Pa.Math.sec or less; the thermoplastic elastomer composition has a sea-island structure; and an island portion has a volume average particle diameter of 2.1 μm or more and a particle diameter dispersion D of 7.0 or less.

A sulfur-crosslinked rubber mixture, in particular for vehicle tires, and a vehicle tire. The sulfur-crosslinked rubber mixture contains at least the following constituents: at least one diene rubber and 0.5 to 10.0 phr of at least one anti-reversion agent and 2.0 phr or more of at least one para-phenylenediamine and 2.0 phr or more of at least one dihydroquinoline
and wherein the network node spacing of the crosslinked rubber mixture is 4.5 to 10 nm.