Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart one or more structural enhancements to articles printed from the build materials. In one aspect, a polymerizable liquid comprises at least one additive including a plurality of cyclopolymerizable functionalities separated by an aliphatic linker or alkylene oxide linker.

An anti-corrosive material contains an ultraviolet curable resin including a polymerizable compound including at least one of a photopolymerizable (meth)acrylate monomer or a photopolymerizable (meth)acrylate oligomer. The anti-corrosive material has a viscosity of 18,900 mPa.Math.s or less. The anti-corrosive material has an elongation rate of 60% or greater as a result of heating at 120° C. for 4,000 hours after curing.

An anti-corrosive material contains a ultraviolet curable resin including a polymerizable compound including at least one of a photopolymerizable (meth)acrylate monomer or a photopolymerizable (meth)acrylate oligomer. The polymerizable compound includes a combination of certain substances. The photopolymerizable (meth)acrylate oligomer contains a low molecular-weight (meth)acrylate oligomer. The polymerizable compound contains a certain cross linking density increasing agent. 35 to 100 parts by mass of the cross linking density increasing agent are contained for 100 parts by mass of the ultraviolet curable resin. The anti-corrosive material has a viscosity of 18,900 mPa.Math.s or less, the viscosity being measured at 25° C. according to JIS Z8803.

An anti-corrosive material includes an ultraviolet curable resin including a polymerizable compound and a photopolymerization initiator. The polymerizable compound includes at least one of a photopolymerizable (meth)acrylate monomer or a photopolymerizable (meth)acrylate oligomer, and the photopolymerization initiator includes at least one of an aminoalkylphenon-based photopolymerization initiator or an acylphosphine oxide-based photopolymerization initiator. When being irradiated with excitation light with a wavelength falling within a range from 365 nm to 415 nm, the ultraviolet curable resin emits visible light having a wavelength longer than that of the excitation light. Further, the anti-corrosive material has a viscosity of 18,900 mPa.Math.s or less.

The application relates to a two-component composition comprising: a component A comprising: at least one polyurethane P having at least two terminal (meth)acrylate functions; at least one reducing agent; and at least one (meth)acrylate monomer M1 selected from among the following compounds and mixtures thereof:

##STR00001## a component B comprising: at least one oxidizing agent; and optionally at least one methacrylate monomer.

Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided.

A coating agent includes: a film forming component including a component A consisting of a urethane (meth)acrylate having an isocyanuric ring skeleton, a component B consisting of a tri(meth)acrylate having an isocyanuric ring skeleton and having no urethane bond, a component C consisting of a polymerizable urethane which has a polycarbonate skeleton derived from a polycarbonate diol having an alicyclic structure, 3 or more polymerizable unsaturated groups per molecule, a weight average molecular weight of 10,000 to 40,000, and a content ratio of the alicyclic structure of 10 mass% to 25 mass%, and a component D consisting of colloidal silica having a (meth)acryloyl group; and a component E consisting of a photoradical polymerization initiator. The content of the component E is 0.1 to 10 parts by mass based on 100 parts by mass of the total film forming component.

A coating agent includes: a film forming component including a component A consisting of a urethane (meth)acrylate having an isocyanuric ring skeleton, a component B consisting of a tri(meth)acrylate having an isocyanuric ring skeleton and having no urethane bond, a component C consisting of a polymerizable urethane which has a polycarbonate skeleton derived from a polycarbonate diol having an alicyclic structure, 3 or more polymerizable unsaturated groups per molecule, a weight average molecular weight of 10,000 to 40,000, and a content ratio of the alicyclic structure of 10 mass% to 25 mass%, and a component D consisting of colloidal silica having a (meth)acryloyl group; and a component E consisting of a photoradical polymerization initiator. The content of the component E is 0.1 to 10 parts by mass based on 100 parts by mass of the total film forming component.

The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes at least one urethane component, at least one monofunctional reactive diluent, an initiator, and optionally an inhibitor. The present disclosure also provides an article including the reaction product of the photopolymerizable composition. Further, the present disclosure provides a method of making an article. The method includes (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes at least one urethane component, at least one monofunctional reactive diluent, an initiator, and optionally an inhibitor. The present disclosure also provides an article including the reaction product of the photopolymerizable composition. Further, the present disclosure provides a method of making an article. The method includes (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.