An object of the present invention is to provide an aqueous dispersion composition containing polyester resin having high storage stability, film-forming properties, tackiness, adhesiveness, and water resistance. An aqueous dispersion composition containing polyester resin, comprises, a polyester resin (A), a coalescing aid (B), and an aqueous medium (C), wherein the coalescing aid (B) has a Hansen solubility parameter with a dispersion term (d) of 15.4 MPa.sup.0.5 or more and less than 18.0 MPa.sup.0.5, a polarization term (p) of 4.1 MPa.sup.0.5 or more and less than 9.1 MPa.sup.0.5, and a hydrogen bond term (h) of 7.0 MPa.sup.0.5 or more and less than 12.3 MPa.sup.0.5.

The presently claimed invention relates to polyalkyleneimine-based polymers that are useful as dispersants and a process for the preparation thereof. The presently claimed invention is also directed to dispersants that are useful in solvent-based dispersion systems as well as in water-based dispersion systems.

A coating composition comprises an emulsion copolymer of a monomer mixture comprising at least one vinyl ester, ethylene, and a stabilizing system. The stabilizing system comprises at least one polyvinyl alcohol. The monomer mixture comprises from 60 to 82 wt % of the at least one vinyl ester and from 18 to 40 wt % of the ethylene based on the total weight of monomers in the mixture. The stabilizing system comprises from 1 to 5 wt % of at least one medium molecular weight polyvinyl alcohol and at least one low molecular weight polyvinyl alcohol. The emulsion copolymer has a solids content from 50% to 60% and a viscosity ranges from 500 to 6,000 mPa.Math.s. and a formaldehyde content of less than 10 ppm as determined by HPLC.

Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of pigment are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone.

A method for optimizing a Hegman rating of a diluted emulsion including adjusting the shear work in the dilution mixer, wherein the adjusting the shear work may comprise raising or lowering the shear work; adjusting the temperature of the concentrated and/or diluted emulsion; if not earlier added, adding a basic aqueous solution and/or dispersing agent; adding one or more other additives; and/or adjusting the amount of any additive, basic solution or surfactant solution is provided. Also provided are diluted emulsions produced thereby and coatings made from the diluted emulsions.

An apparatus, kit, and methods for forming a bead between bead-forming blocks having internal bead-forming channels are provided. The bead-forming channels of adjacent bead-forming blocks are slidably engaged to manipulate a measured amount of modeling compound between the bead-forming blocks and within an internal space between the opposing channels. In one embodiment, the bead-forming blocks maintain orientation with respect to an axis of travel based on a block guide. Further, the measured amount of modeling compound is determined using an integrated measuring feature coupled to at least one of the pair of bead-forming blocks. The internal volume of an integrated measuring feature corresponds to a threshold amount of modeling compound for manipulating between the pair of blocks and forming a bead while contacting at least a portion of the mated bead-forming channels. In further aspects, a molded bead may be coated with a multicomponent bead-coating mixture. Multi-component bead-coating mixtures and methods of using thereof are provided.

An apparatus, kit, and method for forming a bead between bead-forming blocks having internal bead-forming channels are provided. The bead-forming channels of adjacent bead-forming blocks are slidably engaged to manipulate a measured amount of modeling compound between the bead-forming blocks and within an internal space between the opposing channels. In one embodiment, the bead-forming blocks maintain orientation with respect to an axis of travel based on a block guide. Further, the measured amount of modeling compound is determined using an integrated measuring feature coupled to at least one of the pair of bead-forming blocks. The internal volume of an integrated measuring feature corresponds to a threshold amount of modeling compound for manipulating between the pair of blocks and forming a bead while contacting at least a portion of the mated bead-forming channels. In further aspects, a molded bead may be coated with a multicomponent bead-coating mixture. Multi-component bead-coating mixtures and methods of using thereof are provided.

A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses. Upon deposition of the film, the degradable polymeric nanotube (NT) dispersant can be cleaved and the cleavage residues removed from the film to yield a film where contact between NTs is unencumbered by dispersants, resulting in highly conductive NT films.

A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses. Upon deposition of the film, the degradable polymeric nanotube (NT) dispersant can be cleaved and the cleavage residues removed from the film to yield a film where contact between NTs is unencumbered by dispersants, resulting in highly conductive NT films.

A wet coating composition useful for coating a cellulosic fiber-based substrate is provided. The composition includes two aqueous emulsions. The first emulsion includes an oxidized paraffin/polyethylene wax and the second emulsion includes an ethylene/acrylic acid copolymer wax, ethylene/acrylic amide copolymer wax, ethylene/acrylic acid/acrylic amide copolymer wax or a mixture thereof. The oxidized paraffin/polyethylene wax has a surface energy less than or equal to 2 m N/m being substantially dispersive energy. The wet coating composition when dried forms a coating having a surface energy ranging from 20 to 60 m N/m being the sum of dispersive and polar energies. A process for treating a cellulosic fiber-based substrate with the wet coating composition, a substrate coated and articles including the coated substrate are also described. The process involves a heating step to allow migration of the coating towards a core of the cellulosic fiber-based substrate.