Provided is a hydrophilic treatment coating composition which imparts a soil guard property and is superior in durability of soil guard performance. Provided is a hydrophilic treatment coating composition for an inorganic substrate surface-treated with a silane coupling agent (S), comprising a hydrophilic compound (A) and a hydrophilic compound (B), wherein the hydrophilic compound (A) is a compound having at least one of a sulfonic acid group and an alkali metal salt of a sulfonic acid group, and the hydrophilic compound (B) is a compound having a quaternary ammonium cationic group.

Disclosed herein is an anti-biofouling copolymer including a first structural unit represented by formula (I) and a second structural unit represented by formula (II),

##STR00001##

wherein each of the substituents is given the definition as set forth in the Specification and Claims. Also disclosed herein is a method for preparing an anti-biofouling copolymer which includes subjecting a first compound represented by formula (a) to polymerization reaction with a second compound represented by formula (b),

##STR00002##

wherein each of the substituents is given the definition as set forth in the Specification and Claims.

A fluoropolyether group-containing silane compound represented by the following formula (I) wherein the symbols are as defined herein:

##STR00001##

Methods of protecting a propeller include applying an inner polymer layer onto a propeller. The inner polymer layer is impregnated with a biologically active chemical substance that inhibits biofouling-induced chemical, biological, and bio-proliferative damage and that does not chemically or galvanically interact with a material of the propeller. An outer polymer layer is applied onto the inner polymer layer, the outer polymer layer being impregnated with a biologically active chemical substance that inhibits biofouling-induced chemical, biological, and bio-proliferative damage and that repels biofouling organisms to prevent invasion of the inner polymer layer.

The invention relates to a hull of a vessel having characteristic surface properties, allowing an increase in surface runoff while benefiting from an inherent anti-fouling property and an original aesthetic appearance. Furthermore, the invention allows the incorporation of said outer composite envelope into the structure of the hull, thereby preventing delamination problems and inherently providing a vessel hull with the above-mentioned properties.

Coated articles include a substrate and a periodic mesoporous organosilica layer adhered to a surface of the substrate. The coated articles may further include a secondary silane layer covalently attached the periodic mesoporous organosilica layer. Depending on the compositions of the layers, the combination of the periodic mesoporous organosilica layer and the secondary silane layer renders the surface of the substrate superhydrophobic or omniphobic. Methods for coating a surface of a substrate include contacting the surface with a mixture of a hydrolyzed organosilane and a poloxamer and curing the mixture on the surface to form a PMO-coated substrate. The methods may further include contacting the PMO-coated article with a secondary silane coating solution of one or more silanes, then curing the secondary silane coating solution to form a dual-coated article comprising a secondary alkylsilane layer covalently attached to the periodic mesoporous organosilica layer on the surface of the substrate.

The present invention provides compound of formulae (A1), (A2), (B1), (B2), (C1) and (C2) which can form a layer having water-repellency, oil-repellency and antifouling property as well as high friction durability:

##STR00001##

wherein each symbols are as defined in the specification.

An aqueous or water-borne precursor liquid for forming an odor-absorbing and anti-fouling heterophasic thermoset polymeric coating is provided. The precursor includes a fluorine-containing polyol precursor having a functionality >about 2 that forms a branched fluorine-containing polymer component defining a first phase in the anti-fouling heterophasic thermoset polymeric coating. The precursor also includes a first precursor that forms a first component including a cyclodextrin present as second phase. The first phase can be a continuous phase and the second phase can be a first discrete phase, or the second phase can be the continuous phase and the first phase can be the first discrete phase. A crosslinking agent, water, and optional acid or base are also present. An emulsifier may also be included. Methods of making an odor-absorbing and anti-fouling heterophasic thermoset polymeric coatings with such precursors are also provided.

Methods of forming a boat hull include applying an outer polymer layer onto a hull mold, the outer polymer layer being impregnated with a biologically active chemical substance that inhibits biofouling-induced chemical, biological, and bio-proliferative damage. An inner polymer layer is applied onto the outer polymer layer, the inner polymer layer being impregnated with a biologically active chemical substance that inhibits biofouling-induced chemical, biological, and bio-proliferative damage. One or more layers of fiberglass matting are applied on the inner polymer layer, the fiberglass matting being saturated with a polymer selected from one of a group of polymers comprising a vinyl ester polymer, a phthalic unsaturated polyester polymer, and an epoxy polymer.

A composition including a compound containing a carbon-carbon double bond obtained by reacting (A) a polyisocyanate which is a trimer of diisocyanate, with (B) a compound having an active hydrogen, wherein component (B) includes (B1) a perfluoropolyether having an active hydrogen, and (B2) a monomer having an active hydrogen and at least two groups having a carbon-carbon double bond.