A hybrid inkjet ink comprising a water miscible organic solvent, a UV radiation-curable material and appropriate photoinitiator, and an epoxide-containing material and printed decorations produced by applying the inkjet ink images to an aluminum substrate.

A method of inkjet printing a gradient dielectric element in a deposition and photo-polymerization process. The method comprises: providing a plurality of complex-dielectric-inks that are inkjet printable including a nanocomposite-ink with an organic-matrix and a nanoparticle filler dispersed within. The plurality of complex-dielectric-inks have a first complex-dielectric-ink having a first photoinitiator and a second complex-dielectric-ink with a second photoinitiator. The first and second complex-dielectric-ink have different wavelength selective photo-polymerization absorption bands such that spectrally discrete exposure results in different degrees of polymerization of the first and second complex-dielectric-ink. The method further comprises providing an optical source to polymerize the complex-dielectric-inks, depositing droplets of the plurality of complex-dielectric-ink and curing the plurality of complex-dielectric-inks, wherein deposition of the plurality of layers result in a volumetric nanoparticle concentration gradient.

The present invention is directed to an ultraviolet curing ink jet ink composition which contains at least a polymerizable compound and a photopolymerization initiator, and is free from an aqueous solvent. The polymerizable compound comprises at least a urethane oligomer, and the photopolymerization initiator comprises an acylphosphineoxide and α-hydroxyketone. The polymerizable compound further comprises an allyl compound and/or an N-vinyl compound.

The present invention is directed to an ultraviolet curing ink jet ink composition which contains at least a polymerizable compound and a photopolymerization initiator, and is free from an aqueous solvent. The polymerizable compound comprises at least a urethane oligomer, and the photopolymerization initiator comprises an acylphosphineoxide and α-hydroxyketone. The polymerizable compound further comprises an allyl compound and/or an N-vinyl compound.

Curable ink compositions include a curable aromatic monomer composition, and surface treated metal oxide nanoparticles. The surface treated metal oxide nanoparticles are surface treated with a mixture of at least two silane-functional surface treatment agents, at least one aromatic-containing silane-functional surface treatment agent and at least one silane-functional surface treatment agent comprising a co-polymerizable group. The curable ink composition is inkjet printable, having a viscosity of 30 centipoise or less at a temperature of from room temperature to 60° C., and is free from solvents. The curable ink composition, when printed and cured, has a refractive index of 1.55 or greater, and is optically clear.

Curable ink compositions include a curable aromatic monomer composition, and surface treated metal oxide nanoparticles. The surface treated metal oxide nanoparticles are surface treated with a mixture of at least two silane-functional surface treatment agents, at least one aromatic-containing silane-functional surface treatment agent and at least one silane-functional surface treatment agent comprising a co-polymerizable group. The curable ink composition is inkjet printable, having a viscosity of 30 centipoise or less at a temperature of from room temperature to 60° C., and is free from solvents. The curable ink composition, when printed and cured, has a refractive index of 1.55 or greater, and is optically clear.

A fluid set can include an ink composition having an acidic pH and a crosslinker composition having a basic pH from pH 8 to pH 10. The ink composition can include from 60 wt % to 90 wt % water, from 5 wt % to 30 wt % organic co-solvent, from 1 wt % to 6 wt % pigment, a sulfonated dispersant, and an acrylic polymer binder. The crosslinker composition can include from 70 wt % to 95 wt % water, from 1 wt % to 25 wt % organic co-solvent, and from 0.5 wt % to 5 wt % polycarbodiimide.

Various of the disclosed embodiments concern removable ultraviolet (UV) curable dye sublimation ink to be used in various printing systems and printing methods. In some embodiments, the ink includes a dye component, a UV curable component, and a soluble or solvent-sensitive component. In order to print an image on a substrate, the ink is heated to a temperature sufficient to cause sublimation of at least the dye component. During the sublimation process, the dye is able to permeate the substrate and form a printed image. After the transfer process has been completed, a solvent can be jetted onto the substrate that causes the soluble component to dissolve. The washing process ensures that any residual ink remaining on the surface of the substrate is substantially removed.

Various of the disclosed embodiments concern removable ultraviolet (UV) curable dye sublimation ink to be used in various printing systems and printing methods. In some embodiments, the ink includes a dye component, a UV curable component, and a soluble or solvent-sensitive component. In order to print an image on a substrate, the ink is heated to a temperature sufficient to cause sublimation of at least the dye component. During the sublimation process, the dye is able to permeate the substrate and form a printed image. After the transfer process has been completed, a solvent can be jetted onto the substrate that causes the soluble component to dissolve. The washing process ensures that any residual ink remaining on the surface of the substrate is substantially removed.

An active energy ray curable composition is provided. The active energy ray curable composition includes polymerizable compounds including a first monofunctional monomer having a polar group, a second monofunctional monomer having no polar group, and a polyfunctional monomer. The homopolymer of each of the first monofunctional monomer and the second monofunctional monomer has a glass transition temperature of 50° C. or more. The first monofunctional monomer and the second monofunctional monomer account for 50% by mass or more of the polymerizable compounds in total, and the polyfunctional monomer accounts for 30% by mass or less of the polymerizable compounds.