A water-resistant film layer, a preparation method therefor, and a product. The water-resistant film layer is formed on a surface of a substrate by one or more compounds shown in general formula (I) by means of a plasma chemical vapor deposition method, i.e., R.sub.1R.sub.2═R.sub.3R.sub.4(I), wherein R.sub.1 and R.sub.2 are each independently selected from one of a group consisting of hydrogen, alkyl, halogen, haloalkyl, and aryl, at least one of R.sub.1, R.sub.2, and R.sub.3 is halogen, and R.sub.4 is a hydrophobic functional group, typically having a fluorine-containing alky structure.

##STR00001##

A water-resistant film layer, a preparation method therefor, and a product. The water-resistant film layer is formed on a surface of a substrate by one or more compounds shown in general formula (I) by means of a plasma chemical vapor deposition method, i.e., R.sub.1R.sub.2═R.sub.3R.sub.4(I), wherein R.sub.1 and R.sub.2 are each independently selected from one of a group consisting of hydrogen, alkyl, halogen, haloalkyl, and aryl, at least one of R.sub.1, R.sub.2, and R.sub.3 is halogen, and R.sub.4 is a hydrophobic functional group, typically having a fluorine-containing alky structure.

##STR00001##

A liquid repellent structure includes a surface to which liquid repellency is to be imparted, and a liquid repellent layer formed on the surface. In the structure: the liquid repellent layer contains a binder resin containing a fluorine-containing resin, and a filler dispersed in the binder resin; the filler contains a first filler having a BET specific surface area M of 100 m.sup.2/g to 400 m.sup.2/g; and the ratio M/F of the BET specific surface area M of the first filler to a mass F (mass %) of the fluorine-containing resin relative to the total mass of the liquid repellent layer is 4.1 to 20.0.

A liquid repellent structure includes a surface to which liquid repellency is to be imparted, and a liquid repellent layer formed on the surface. In the structure: the liquid repellent layer contains a binder resin containing a fluorine-containing resin, and a filler dispersed in the binder resin; the filler contains a first filler having a BET specific surface area M of 100 m.sup.2/g to 400 m.sup.2/g; and the ratio M/F of the BET specific surface area M of the first filler to a mass F (mass %) of the fluorine-containing resin relative to the total mass of the liquid repellent layer is 4.1 to 20.0.

A liquid repellent structure including: a surface to which liquid repellency is to be imparted; and a liquid repellent layer formed on the surface, wherein the liquid repellent layer contains a binder resin containing a fluorine-containing resin, and a filler dispersed in the binder resin, the filler contains a first filler having a BET specific surface area M of 100 m.sup.2/g to 400 m.sup.2/g, and a ratio M/F of the BET specific surface area M of the first filler to a mass F (mass %) of the fluorine-containing resin relative to a total mass of the liquid repellent layer is 1.5 to 4.0.

The present invention relates to a highly fluorinated nanostructured polymer foam as well as to its use as a super-repellent coating of substrates. Furthermore, the present invention relates to a composition and to a method for producing the highly fluorinated nanostructured polymer foam.

The present invention relates to a highly fluorinated nanostructured polymer foam as well as to its use as a super-repellent coating of substrates. Furthermore, the present invention relates to a composition and to a method for producing the highly fluorinated nanostructured polymer foam.

A fluoroacrylic compound of formula (1) which, when added to an actinic-ray-curable composition, can impart excellent liquid repellency, antifouling properties, and wear resistance.

Y—Rf.sup.1—Z.sup.1-Q.sup.1-[Z.sup.2—X].sub.a  (1)

[Rf.sup.1 is a divalent perfluoropolyether group. Z.sup.1 is a divalent hydrocarbon group optionally containing O, N, or Si. Q.sup.1 is an (a+1)-valent linking group including a+1 or more Si atoms. Z.sup.2 is a divalent alkylene ether group. X is H or a monovalent organic group having an (α-substituted) acryl group, and at least one of the X moieties is a monovalent organic group having an (α-substituted) acryl group. Symbol a is 1-10. Y is F or —Z.sup.1-Q.sup.1-[Z.sup.2—X].sub.a. All of the Z.sup.1 moiety and the a Z.sup.2 moieties within the [ ] have been bonded to the Si atoms contained in the Q.sup.1 and the molecule has no urethane bond therein.]

A fluoroacrylic compound of formula (1) which, when added to an actinic-ray-curable composition, can impart excellent liquid repellency, antifouling properties, and wear resistance.

Y—Rf.sup.1—Z.sup.1-Q.sup.1-[Z.sup.2—X].sub.a  (1)

[Rf.sup.1 is a divalent perfluoropolyether group. Z.sup.1 is a divalent hydrocarbon group optionally containing O, N, or Si. Q.sup.1 is an (a+1)-valent linking group including a+1 or more Si atoms. Z.sup.2 is a divalent alkylene ether group. X is H or a monovalent organic group having an (α-substituted) acryl group, and at least one of the X moieties is a monovalent organic group having an (α-substituted) acryl group. Symbol a is 1-10. Y is F or —Z.sup.1-Q.sup.1-[Z.sup.2—X].sub.a. All of the Z.sup.1 moiety and the a Z.sup.2 moieties within the [ ] have been bonded to the Si atoms contained in the Q.sup.1 and the molecule has no urethane bond therein.]

An object is to provide a resin composition having excellent performance as a binder such as adhesiveness and, at the same time, retaining solution properties favorably even after a solution is stored for a long period of time. A modified polyolefin resin composition includes a modified polyolefin resin (C), in which the modified polyolefin resin (C) is a resin made by modifying a polymer (A) that is a polymer (a) of a polyolefin resin or a chlorinated polyolefin resin and an α,β-unsaturated carboxylic acid derivative having a structure derived from at least one carboxy group or a chlorinated product (b) thereof with a modification component including an alcohol (B); and a residual ratio of the structure derived from at least one carboxy group in the modified polyolefin resin (C) is 50% or more and 80% or less.