A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.

Provided is grease capable of suppressing a decrease in a function as a lubricant even when used in a device installed in a refrigerant circuit in which a refrigerant containing a chlorine atom and an olefin bond in a molecule flows, and a refrigeration cycle apparatus using the grease as a lubricant. Grease that is used in a device installed in a refrigerant circuit in which a refrigerant containing a chlorine atom and an olefin bond in a molecule flows contains fluorine as a component. In a chiller apparatus, the grease is used as a lubricant for at least one of a first radial touchdown bearing and a second radial touchdown bearing of a compressor, a drive portion of an inlet guide vane of the compressor, and a drive portion of an expansion valve.

Disclosed is an environmentally friendly near-azeotropic mixed refrigerant, consisting essentially of HFO-1234 yf, HFE-143a and a third component, with the mass percentage of each component being: 70%-98% of HFO-1234yf, 1%-15% of HFE-143a and 1%-15% of the third component. The refrigerant of the present invention is environmentally friendly, excellent in thermodynamic properties, can directly realize drop-in substitution in an original system using HFC-134a without changing any parts, and can be used as a long term alternative to HFC-134a.

A heat cycle system is a heat cycle system (1) using a working medium containing hydrofluoroolefin (HFO) that has a double bond in a molecule structure, the heat cycle system (1) having a compressor (10), a high-pressure side heat exchanger (12), a low-pressure side heat exchanger (14), an expansion mechanism (13), and an acid detection means (40) which is disposed in a discharge pipe (21) connecting the compressor (10) and the high-pressure side heat exchanger (12) and which detects acid generated by decomposition of the working medium in a heat cycle.

An object is to provide a mixed refrigerant having three types of performance, i.e., a refrigerating capacity that is equivalent to that of R410A, a sufficiently low GWP, and a lower flammability (Class 2L) according to the ASHRAE standard. Provided is a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf), wherein when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AC, CF, FD, and DA that connect the following 4 points: point A (71.1, 0.0, 28.9), point C (36.5, 18.2, 45.3), point F (47.6, 18.3, 34.1), and point D (72.0, 0.0, 28.0), or on these line segments; the line segment AC is represented by coordinates (0.0181y.sup.2−2.2288y+71.096, y, −0.0181y.sup.2+1.2288y+28.904); the line segment FD is represented by coordinates (0.02y.sup.2−1.7y+72, y, −0.02y.sup.2+0.7y+28); and the line segments CF and DA are straight lines.

The invention provides a composition comprising 1,1-difluoroethene (R-1132a), difluoromethane (R-32), 2,3,3,3-tetrafluoropropene (R-1234yf), optionally carbon dioxide (CO.sub.2, R-744), and, optionally, 1,1,2-trifluoroethene (R-1123).

A refrigerant composition comprising carbon dioxide (CO.sub.2; R-744) and from 1 to 32 weight % difluoromethane (R-32) based on the total weight of the composition is described. Also described is the use of the refrigerant composition for providing heating and cooling and a refrigeration, air-conditioning or heat pump system comprising the refrigerant composition.

An object is to provide a mixed refrigerant having three types of performance, i.e., a refrigerating capacity that is equivalent to that of R410A, a sufficiently low GWP, and a lower flammability (Class 2L) according to the ASHRAE standard. Provided is a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf), wherein when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AC, CF, FD, and DA that connect the following 4 points: point A (71.1, 0.0, 28.9), point C (36.5, 18.2, 45.3), point F (47.6, 18.3, 34.1), and point D (72.0, 0.0, 28.0), or on these line segments; the line segment AC is represented by coordinates (0.0181y.sup.2−2.2288y+71.096, y, −0.0181y.sup.2+1.2288y+28.904); the line segment FD is represented by coordinates (0.02y.sup.2−1.7y+72, y, −0.02y.sup.2+0.7y+28); and the line segments CF and DA are straight lines.

A lubricating oil composition excellent in the wear resistance and a refrigerator oil composition excellent in the oxidation stability using the lubricating oil composition are provided by a lubricating oil composition containing a base oil (A) and a phosphine derivative (B) having one or more oxygen atom in a molecule.

A refrigeration cycle apparatus (1) is capable of performing a refrigeration cycle using a small-GWP refrigerant. The refrigeration cycle apparatus (1) includes a refrigerant circuit (10) and a refrigerant enclosed in the refrigerant circuit (10). The refrigerant circuit includes a compressor (21), a condenser (23), a decompressing section (24), and an evaporator (31). The refrigerant contains at least 1,2-difluoroethylene.