The present application relates to an electrochromic composite, an electrochromic device comprising the same, and a method for manufacturing an electrochromic device.

Embodiments of the invention are directed to yellow/orange-to-transmissive conjugated polymers, a method to prepare the yellow/orange conjugated polymers, and an electrochromic and/or electroluminescent device comprising the neutral state yellow/orange conjugated polymers as one of a plurality of primary subtractive colored conjugated polymers. The yellow/orange conjugated polymers show enhanced redox stability and can have a (D.sub.2Ar.sub.z).sub.n structure with a dioxyheterocycle repeating unit or a (DAr.sub.z).sub.n structure with a dioxythiophene monomer that has at least one substituted carbon to an oxygen of the monomer; and where the one to three Ar groups have at least one carbon to the carbon attached to a D unit substituted that has at least 5 atoms in the substituent. The yellow/orange conjugated polymers show enhanced redox stability. The yellow/orange conjugated polymers are prepared by cross-condensation reactions.

Disclosed is a method to color tune an electrochromic device by the use of a standard dye. By following the subtractive color mixing theory and selecting the appropriate standard dye to compliment or accentuate the electrochromic material, tuning of the optical and colorimetric properties of the resulting electrochromic device can be achieved. The method can also be used to prepare electrochromic devices that will switch between two neutral colors.

Copolymers including dioxythiophene repeating units and no acceptor units allow the formation of electrochromic polymers (ECPs) with vivid neutral state colors and very colorless oxidized states that can be switched rapidly. The dioxythiophene repeating units can included in sequences where all of one type of dioxythiophene is included exclusively as isolated dyads or triads within the copolymer, or the copolymer can be an alternating copolymer with propylenedioxythiophene units. Other non-acceptor units can be included in the copolymers. The copolymers are rendered organic solvent soluble by alkyl substituents on repeating units. The inclusion of sterically encumbered acyclic dioxythiophene (AcDOT) units promotes red color while unsubstituted ethylenedioxythiophene (EDOT) units promote blue colors, and their respective content can be manipulated to achieve a desired neutral state color. Soluble copolymers comprising at least 50% EDOT repeating units can be used in supercapacitor applications.

Yellow electrochromic polymers (ECPs) are prepared that display a yellow neutral state and a highly transmissive oxidized state. The ECPs are copolymers where a dyad of dioxyhetereocyclic repeating unis alternate with a monad of an aromatic repeating unit. An alternate yellow ECP has an oxidation potential of 450 mV or less and is an alternating copolymer of an acyclic dioxythiophene (AcDOT) or a propylene dioxythiophene (ProDOT) with an aromatic repeating unit that has an electron donating substituent. The yellow ECPs can be processed from solution for electrochromic devices.

Disclosed is a rare-earth complex polymer including trivalent rare-earth ions and a phosphine oxide bidentate ligand represented by the formula (1). One phosphine oxide bidentate ligand is coordinated to the two rare-earth ions, and crosslinks the same.

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The present invention relates to novel compositions comprising an organic semiconductor (OSC) and one or more organic solvents. The composition is solid at a temperature of 25? C. and fluid at a higher temperature and the boiling point of the solvent is at most 400? C. Furthermore, the present invention describes the use of these compositions as inks for the preparation of organic electronic (OE) devices, especially organic photovoltaic (OPV) cells and OLED devices, to methods for preparing OE devices using the novel compositions, and to OE devices, OLED devices and OPV cells prepared from such methods and compositions.

An object of the invention is to provide an organic semiconductor element having high mobility and excellent temporal stability under high humidity, and a manufacturing method thereof. Another object is to provide a novel compound suitable for an organic semiconductor. Still another object is to provide an organic semiconductor film having high mobility and excellent temporal stability under high humidity and a composition for forming an organic semiconductor film that can suitably form the organic semiconductor film. The organic semiconductor element according to the invention includes an organic semiconductor layer containing an organic semiconductor having a repeating unit represented by Formula 1. ##STR00001##

Resins comprising nanoparticles formed from -conjugated cross-linked polymers are disclosed, together with their methods of manufacture and their applications in light emitting devices.

The disclosure relates generally to black-to-transmissive electrochromic polymers having superior properties such as absorbance of across the entire visible spectrum and an obvious color change from black to transmissive with an applied voltage. The disclosure also relates to methods for synthesizing or using the same. Further, the disclosure also relates to black-to-transmissive electrochromic polymer thin films comprising the black-to-transmissive electrochromic polymers, as well as electrochromic devices comprising the black-to-transmissive electrochromic polymers or thin films.