An aspect of the present disclosure relates to a process for solvent deasphalting dearomatization, said process including: effecting deasphaltenation of a heavy oil feed by contacting the feed with a paraffinic rich solvent, optionally, in presence of a FCC catalyst to obtain a deasphalted oil rich stream, said paraffinic rich solvent being untreated naphtha; contacting the DAO rich stream with a second solvent to obtain a raffinate stream rich in non-asphaltene and non-aromatic contents and a solvent rich stream; contacting the raffinate stream with water in a first decanter to obtain a first stream rich in aromatic-lean fraction and a second stream rich in the second solvent and water; subjecting the first stream to distillation to recover the paraffinic rich solvent and to obtain deasphalted oil; contacting the solvent rich stream with water in a second decanter to obtain an aromatic rich fraction and a third stream rich in the second solvent and water; and subjecting the second stream and the third stream to distillation to recover the second solvent and water.

An aspect of the present disclosure relates to a process for solvent deasphalting dearomatization, said process including: effecting deasphaltenation of a heavy oil feed by contacting the feed with a paraffinic rich solvent, optionally, in presence of a FCC catalyst to obtain a deasphalted oil rich stream, said paraffinic rich solvent being untreated naphtha; contacting the DAO rich stream with a second solvent to obtain a raffinate stream rich in non-asphaltene and non-aromatic contents and a solvent rich stream; contacting the raffinate stream with water in a first decanter to obtain a first stream rich in aromatic-lean fraction and a second stream rich in the second solvent and water; subjecting the first stream to distillation to recover the paraffinic rich solvent and to obtain deasphalted oil; contacting the solvent rich stream with water in a second decanter to obtain an aromatic rich fraction and a third stream rich in the second solvent and water; and subjecting the second stream and the third stream to distillation to recover the second solvent and water.

Corrosion inhibitor compositions and methods for inhibiting corrosion on a metal surface exposed to a hydrocarbon fluid are provided. The corrosion inhibitor composition can comprise 2-aminoterephthalic acid, dimethyl sulfoxide and heavy aromatic naphtha (HAN). In another embodiment, the composition can comprise 4-methylamino benzoic acid or 4-methylsulfonyl benzoic acid, N-methyl pyrrolidone, and HAN. In the method, a corrosion inhibitor composition comprising 2-aminoterephthalic acid, 4-methylamino benzoic acid, or 4-methylsulfonyl benzoic acid can be added to a hydrocarbon fluid exposed to the metal surface. The corrosion can be caused by naphthenic acid.

A process for removing heavy polycyclic aromatic contaminants from a hydrocarbon stream using a quinolinium ionic liquid is described. The process includes contacting the hydrocarbon stream comprising the contaminant with a hydrocarbon-immiscible quinolinium ionic liquid to produce a mixture comprising the hydrocarbon and a hydrocarbon-immiscible quinolinium ionic liquid comprising at least a portion of the removed contaminant; and separating the mixture to produce a hydrocarbon effluent having a reduced level of the contaminant and a hydrocarbon-immiscible quinolinium ionic liquid effluent comprising the hydrocarbon-immiscible quinolinium ionic liquid comprising at least the portion of the removed contaminant.

Embodiments of a composition of the present invention for scavenging sulfides from hydrocarbon fluids and water generally include diaminol/diaminacetal provided in a chemical system, wherein the diaminol/diaminacetal is prepared by reacting one molar equivalent of glyoxal and two molar equivalents of a primary amine functionality. In various embodiments, the chemical system includes at least one component selected from surfactants, hydrotropes, alcohols, amines, amino acids, and ethers. Embodiments of a method for scavenging sulfides from hydrocarbon fluids and water is also provided.

The invention provides a method of desulfurizing an oil composition, the method comprising: flowing an oil composition comprising sulfur through a conduit comprising a constricted region, wherein oil-phase bubbles form in the constricted region and collapse in a turbulent zone downstream of the constricted region; contacting the oil composition with an immiscible deep eutectic solvent in the turbulent zone, thereby extracting at least a portion of the sulfur from the oil composition into association with the deep eutectic solvent; and separating the deep eutectic solvent and the extracted sulfur from the desulfurized oil composition.

The invention provides a method of desulfurizing an oil composition, the method comprising: flowing an oil composition comprising sulfur through a conduit comprising a constricted region, wherein oil-phase bubbles form in the constricted region and collapse in a turbulent zone downstream of the constricted region; contacting the oil composition with an immiscible deep eutectic solvent in the turbulent zone, thereby extracting at least a portion of the sulfur from the oil composition into association with the deep eutectic solvent; and separating the deep eutectic solvent and the extracted sulfur from the desulfurized oil composition.

The invention relates to hydrocarbon pyrolysis, e.g., the steam cracking of feeds comprising hydrocarbon and nitrogen-containing compositions. The invention also relates to equipment, systems, and apparatus useful for such pyrolysis, to the products and by-products of such pyrolysis, and to the further processing of such products and co-products, e.g., by polymerization.

The invention relates to hydrocarbon pyrolysis, e.g., the steam cracking of feeds comprising hydrocarbon and nitrogen-containing compositions. The invention also relates to equipment, systems, and apparatus useful for such pyrolysis, to the products and by-products of such pyrolysis, and to the further processing of such products and co-products, e.g., by polymerization.

A process for removing heavy polycyclic aromatic contaminants from a hydrocarbon stream using a quinolinium ionic liquid is described. The process includes contacting the hydrocarbon stream comprising the contaminant with a hydrocarbon-immiscible quinolinium ionic liquid to produce a mixture comprising the hydrocarbon and a hydrocarbon-immiscible quinolinium ionic liquid comprising at least a portion of the removed contaminant; and separating the mixture to produce a hydrocarbon effluent having a reduced level of the contaminant and a hydrocarbon-immiscible quinolinium ionic liquid effluent comprising the hydrocarbon-immiscible quinolinium ionic liquid comprising at least the portion of the removed contaminant.