C10G2300/1007

Purification of hydrocarbons
11248177 · 2022-02-15 ·

We disclose a process for purification of hydrocarbons, suitable for a wide range of contexts such as refining bunker fuels to yield low-sulphur fuels, cleaning of waste engine oil (etc) to yield a usable hydrocarbon product, recovery of hydrocarbons from used tyres, recovery of hydrocarbons from thermoplastics etc, as well as the treatment of crude oils, shale oils, and the tailings remaining after fractionation and like processes. The method comprises the steps of heating the hydrocarbon thereby to release a gas phase, contacting the gas with an aqueous persulphate electrolyte within a reaction chamber, and condensing the gas to a liquid or a liquid/gas mixture and removing its aqueous component. It also comprises subjecting the reaction product to an electrical field generated by at least two opposing electrode plates between which the reaction product flows; this electrolytic step regenerates the persulphate electrolyte which can be recirculated within the process. The process is ideally applied in an environment at lower than atmospheric pressure, such as less than 1500 Pa. A wide range of hydrocarbons can be treated in this way. Used hydrocarbons such as engine oils and sulphur-contaminated fuels are prime examples, but there are a wide range of others such as hydrocarbons derived from the pyrolysis of a material having a hydrocarbon content. One such example is a mix of used rubber (such as end-of-life tyres) and used oils (such as engine oils, waste marine oils), which can be pyrolysed together to yield a hydrocarbon liquid which can be treated as above, and a residue that provides a useful solid fuel.

PROCESS FOR INTEGRATED PRODUCTION OF RENEWABLE FUELS AND CHEMICALS
20220041939 · 2022-02-10 · ·

The present disclosure provides a versatile process for producing valuable renewable hydrocarbons from triglyceride containing feedstock. The triglyceride containing feedstock is first split to provide a mixture containing fatty acids, glycerol and water, from which a phase separation provides an oily phase, and an aqueous phase. The oily phase containing fatty acids is subjected to fractionation, whereby specific fractions may be refined to products with controlled hydroprocessing. Products may contain paraffinic renewable aviation fuel components, paraffinic renewable base oil, renewable paraffinic diesel fuel components, renewable paraffinic technical fluid, or any combination thereof.

ALKALI-ENHANCED HYDROTHERMAL PURIFICATION OF PLASTIC PYROLYSIS OILS

A method is disclosed for preparing fuel components from waste pyrolysis oil. Exemplary embodiments include providing a waste pyrolysis oil having plastic pyrolysis oil and/or tyre pyrolysis oil, and impurities; purifying the waste pyrolysis oil by hydrothermal treatment with water or alkaline water; separating the hydrothermally treated waste pyrolysis oil from an aqueous phase; preparing a hydroprocessing feed from the hydrothermally treated waste pyrolysis oil; hydroprocessing the hydroprocessing feed catalytically with hydrogen to cause hydrogenation; and recovering a hydrocarbon fraction boiling in a liquid fuel range.

METHOD AND DEVICE FOR CLEANING CONTAMINATED USED OIL
20210402321 · 2021-12-30 · ·

The invention relates to a method and a device for cleaning contaminated used oil, in which starting material is heated to the gas phase and the resultant vapor is rectified, with purified oil being removed as condensate from a drain in a rectification column. This enables efficient operation even in the smallest of systems, such that a compact system configuration and thus in particular mobile use by a container structure is made possible. The invention also reduces the cost required for servicing. The used oil is subjected to an evaporation process by at least indirectly placing the starting material in contact with a melting bath, the melting temperature of which is above the evaporation temperature but below the ignition temperature of the used oil, and by rectifying the vapor in the rectification column.

PREPARATION OF AN AVIATION FUEL COMPOSITION
20220177789 · 2022-06-09 · ·

A method is disclosed for preparing an aviation fuel composition by subjecting a feedstock of biological and/or recycled origin to cracking in a cracking unit and to fractionation in a fractionation unit to obtain a kerosene fraction. The obtained kerosene fraction is subjected to hydrotreatment in a hydrotreatment unit to form a first jet fuel component. The formed first jet fuel component is mixed with a further jet fuel component to form a fuel composition having a wear scar diameter of 0.78 mm or less, as measured with BOCLE lubricity test method according to ASTM D5001. The feedstock contains one or more of tall oil pitch (TOP), a mixture of sludge palm oil, palm fatty acid distillate and animal fat (FATS), and used lubricant oil (ULO).

TREATING AND STEAM CRACKING A COMBINATION OF PLASTIC-DERIVED OIL AND USED LUBRICATING OILS TO PRODUCE HIGH-VALUE CHEMICALS
20220177785 · 2022-06-09 ·

Systems and methods for producing one or more olefins using waste plastics and used lubricating oil are disclosed. Mixed waste plastic is processed in a pyrolysis unit to produce plastic derived oil. The plastic derived oil is subsequently blended with used lubricating oil to form a mixture. The mixture is then separated into (1) a light-end stream comprising C1 to C8 hydrocarbons and (2) a heavy hydrocarbon feed stream. The heavy hydrocarbon feed stream is then processed to produce a steam cracking feedstock stream. The light end-stream and/or the steam cracking feedstock stream are then flowed into a cracking unit to produce one or more olefins.

PROCESSES FOR CONVERTING PETROLEUM BASED WASTE OILS INTO LIGHT AND MEDIUM DISTILLATE
20220154085 · 2022-05-19 ·

The present technology relates to processes for converting PBWO into light and medium distillate such as usable diesel fuel, the processes generally comprising the steps of: boiling the PBWO to dehydrate the PBWO, heating the PBWO to produce PBWO hydrocarbon vapor, contacting the PBWO hydrocarbon vapor with a catalyst, and cooling the resultant vapor to liquid form through heat exchangers to produce light and medium distillate.

System and Process for Heavy Fuel Oil Pyrolysis
20220145191 · 2022-05-12 ·

Provided is a system for continuous processing of heavy fuel oil from recycling waste oil and the processing residues of crude oil into useful products including means for feeding waste oil; at least one hot-gas filter, at least one condenser, at least one rotating kiln including an outer stationary jacket which forms a heating channel, and an inner rotating reactor, and means for removing solid coke from the rotating reactor. The at least one hot gas filter is configured to separate a naphtha/gasoil fraction after the processing of the heavy fuel oil from a soft coke fraction. The rotating reactor is configured to recover a solid coke fraction comprising high contaminant content. The invention further relates to a process for continuous processing of heavy fuel oil from recycling waste oil and the processing residues of crude oil into useful products, preferably with the system of the invention. Moreover, the invention relates to use of the products and waste products produced with the process and system of the invention.

HIGH NANOPORE VOLUME CATALYST AND PROCESS USING SSZ-91
20220143587 · 2022-05-12 ·

An improved hydroisomerization catalyst and process for making a base oil product wherein the catalyst comprises a base extrudate that includes SSZ-91 molecular sieve and a high nanopore volume alumina. The catalyst and process generally involves the use of a SSZ-91/high nanopore volume alumina based catalyst to produce dewaxed base oil products by contacting the catalyst with a hydrocarbon feedstock. The catalyst base extrudate advantageously comprises an alumina having a pore volume in the 11-20 nm pore diameter range of 0.05 to 1.0 cc/g, with the base extrudate formed from SSZ-91 and the alumina having a total pore volume in the 2-50 nm pore diameter range of 0.12 to 1.80 cc/g. The catalyst and process provide improved base oil yield with reduced gas and fuels production.

Process and plant for producing hydrocarbons with reduced CO.SUB.2.-footprint and improved hydrogen integration

Process and plant for producing hydrocarbon products from a feedstock originating from a renewable source, where a hydrogen-rich stream and on off-gas stream comprising hydrocarbons is formed. A portion of the hydrogen-rich stream is used as a recycle gas stream in a hydroprocessing stage for the production of said hydrocarbon products, and another portion may be used for hydrogen production, while the off-gas stream is treated to remove its H.sub.2S content and used as a recycle gas stream in the hydrogen producing unit, from which the hydrogen produced i.e. make-up hydrogen, is used in the hydroprocessing stage. The invention enables minimizing natural gas consumption in the hydrogen producing unit as well as steam reformer size.