Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

The present disclosure refers to a process of obtaining a biocrude from biomass, where said process comprises the solvothermal liquefaction of the biomass in the presence of a mixture of solvents, until obtaining a gaseous phase, a solid phase, an aqueous liquid phase and an organic liquid phase comprising the biocrude. Wherein the mixture of solvents comprises between 0.5% w/w to 99.5% w/w of water and at least one solvent; and wherein the solvent is selected from alcohols, ketones, aldehydes, or precursors thereof under the processing conditions. The process described herein allows the use of biomass for the production of renewable fuels, as well as obtaining a biocrude with a yield greater than or equal to 30%, with a calorific value between 20 and 35 MJ/Kg and with a sulfur percentage lower than 1% w/w.

The process removes hydrogen sulfide from hydrotreated gas by TSA. Hydrogen sulfide adsorbs on the adsorbent while allowing hydrogen in the hydrotreated gas to pass the adsorbent to provide a desulfided hydrogen gas stream and a sulfided adsorbent. A regenerant gas stream can be contacted with the sulfided adsorbent at a swing temperature to desorb hydrogen sulfide from the adsorbent into the regenerant gas stream. The regenerant gas stream can then be recycled to a hydrotreating reactor for processing biorenewable feed to provide hydrogen sulfide to the reactor. The desulfided gas stream can be purified to remove impurities such as carbon oxides and recycled to the hydrotreating reactor and/or used as the regenerant gas stream.

A process for hydroprocessing a hydrocarbon feed of the present disclosure includes contacting the hydrocarbon feed with hydrogen in the presence of at least one hydroprocessing catalyst in a two-phase hydroprocessing unit, where the at least one hydroprocessing catalyst is a solid catalyst and contacting produces a hydroprocessed effluent having a reduced concentration of one or more of metals, nitrogen, sulfur, aromatic compounds, or combinations of these. The process further includes combining the hydroprocessed effluent with make-up hydrogen downstream of the two-phase hydroprocessing unit to produce a hydrogen saturated hydroprocessed effluent, separating the hydrogen saturated hydroprocessed effluent in a separation system to produce a hydrogen-saturated high-pressure bottom stream, a hydroprocessed product stream, and a gaseous effluent, and passing at least a portion of the hydrogen-saturated high-pressure bottom stream back to the two-phase hydroprocessing unit.

A method is provided for reprocessing a petroleum-based waste oil feedstock into diesel fuel. The method includes forming a treated feedstock by (a) filtering the feedstock, thereby removing solids and metals from the feedstock, and (b) dehydrating the feedstock; vaporizing the treated feedstock to produce an oil vapor; passing the oil vapor through at least one catalyst bed and subsequently through a cooler, thereby converting the oil vapor to a hydrocarbon liquid product with a diesel product boiling point range; and removing contaminants from the hydrocarbon liquid product, wherein the contaminants are selected from the group consisting of particulates and color precursors.

A method of removing metals and amines from crude oil comprising adding an effective metal removing amount of one or more hydroxycarboxylic acids selected from lactic acid and malic acid and salts thereof to said crude oil; adding wash water to said crude oil; mixing said crude oil, acid and wash water to form an emulsion; and resolving said emulsion into an aqueous phase and crude oil having a reduced metals content.

Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.

A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.

Provided is a mercury adsorbent that can efficiently adsorb and remove mercury and/or a mercury compound contained in a liquid hydrocarbon and can suppress corrosive action even when used for a long time. The mercury adsorbent comprises an activated carbon including a mineral acid supported thereon, the activated carbon having a specific surface area of 1000 m.sup.2/g or larger and a volume of micropores of 80 cm.sup.3/g or larger, each of the micropores having a pore radius of 8 Å or smaller, and the mercury adsorbent has a moisture content of from 0.1 to 3 wt %.

A process for producing olefins from the hydrocarbon feed includes introducing the hydrocarbon feed into a Solvent Deasphalting Unit (SDA) to remove asphaltene from the hydrocarbon feed producing a deasphalted oil stream, wherein the SDA comprises a solvent that reacts with the hydrocarbon feed, and the deasphalted oil stream comprises from 0.01 weight percent (wt. %) to 18 wt. % asphaltenes; introducing the deasphalted oil stream into a steam catalytic cracking system; steam catalytically cracking the deasphalted oil stream in the steam catalytic cracking system in the presence of steam and a nano zeolite cracking catalyst to produce a steam catalytic cracking effluent; and separating the olefins from the steam catalytic cracking effluent.