Disclosed herein are integrated preparation and detection devices for studying biomass-burning aerosols, where the devices include a micro-fluidized bed reactor (MFBR), a transmission line, and an on-line detection unit that are connected in sequence. The MFBR may include a pyrolysis reactor and a pyrolysis furnace; the pyrolysis reactor may include a thermocouple, an introduction tube, and quartz sands; the on-line detection unit may be an on-line photoionization mass spectrometer; and the photoionization mass spectrometer may include a laser desorption system, a laser ionizer and a light energy ionizer. Devices of the present disclosure are beneficial to retain the original state of aerosol particles, and the fixed MFBR can realize rapid pyrolysis of a biomass due to its high and stable heat conduction efficiency, which is beneficial to studying the formation mechanism of aerosol particles.

The invention relates to a device (100) for converting carbonaceous dry raw materials (MPCS) into a synthesis gas, comprising a MPCS pyrolysis chamber (110); a port (106) for introducing the MPCS into said pyrolysis chamber (110); and a port (108) for extraction of synthesis gas from said pyrolysis chamber (110). The device (100) further includes a central chamber (120) immersed in said pyrolysis chamber (110) and comprising a port (128) allowing only a gaseous communication between said central chamber (120) and said pyrolysis chamber (110); and an oxygen injection port (132) in said central chamber (120) for oxidizing at least one portion of the pyrolysis gases passing from the pyrolysis chamber (110) to the central chamber (120).

The CO shift unit 500 as part of the plant 1 for conversing solid waste into a product gas stream comprising hydrogen allows an energy efficient use of the low temperature heat energy in the low temperature heat recovery unit 524 to heat process water streams used in the plant 1.

The CO shift unit 500 as part of the plant 1 for conversing solid waste into a product gas stream comprising hydrogen allows an energy efficient use of the low temperature heat energy in the low temperature heat recovery unit 524 to heat process water streams used in the plant 1.

Process for gasifying an organic material, comprising the following steps: subjecting an organic material to a drying phase to reduce its humidity content and obtain dry organic material and steam, and extracting said steam; subjecting the dry organic material to pyrolysis and generating a pyrolysis gas and a carbonaceous solid residue from the dry organic material, the pyrolysis gas containing a tar fraction; separating the pyrolysis gas from the carbonaceous solid residue, wherein separating the pyrolysis gas comprises extracting the pyrolysis gas and conveying it separately from the carbonaceous solid residue generated by the pyrolysis; subjecting the pyrolysis gas to a thermochemical treatment; and, after the thermochemical treatment, causing the treated pyrolysis gas to penetrate through a reducing bed (31) composed of the carbonaceous solid residue generated by the pyrolysis, and producing a synthesis gas. Subjecting the pyrolysis gas to a thermochemical treatment comprises: subjecting the pyrolysis gas to a first combustion with a gasifying agent under sub-stoichiometric conditions by using ejecting nozzles (25) arranged below and upstream of the reducing bed (31), and obtaining the cracking of the tar fraction contained in the pyrolysis gas; and subjecting the pyrolysis gas to a second combustion introducing an additional gasifying agent in a chamber (20) arranged above and downstream of the ejecting nozzles (25) and upstream of an interface (23) separating the chamber (20) from the reducing bed (31), and completing the combustion of the tar fraction until the pyrolysis gas is fully converted to CO.sub.2, H.sub.2O(g) and heat.

Process for gasifying an organic material, comprising the following steps: subjecting an organic material to a drying phase to reduce its humidity content and obtain dry organic material and steam, and extracting said steam; subjecting the dry organic material to pyrolysis and generating a pyrolysis gas and a carbonaceous solid residue from the dry organic material, the pyrolysis gas containing a tar fraction; separating the pyrolysis gas from the carbonaceous solid residue, wherein separating the pyrolysis gas comprises extracting the pyrolysis gas and conveying it separately from the carbonaceous solid residue generated by the pyrolysis; subjecting the pyrolysis gas to a thermochemical treatment; and, after the thermochemical treatment, causing the treated pyrolysis gas to penetrate through a reducing bed (31) composed of the carbonaceous solid residue generated by the pyrolysis, and producing a synthesis gas. Subjecting the pyrolysis gas to a thermochemical treatment comprises: subjecting the pyrolysis gas to a first combustion with a gasifying agent under sub-stoichiometric conditions by using ejecting nozzles (25) arranged below and upstream of the reducing bed (31), and obtaining the cracking of the tar fraction contained in the pyrolysis gas; and subjecting the pyrolysis gas to a second combustion introducing an additional gasifying agent in a chamber (20) arranged above and downstream of the ejecting nozzles (25) and upstream of an interface (23) separating the chamber (20) from the reducing bed (31), and completing the combustion of the tar fraction until the pyrolysis gas is fully converted to CO.sub.2, H.sub.2O(g) and heat.

A system for use in carbon negative emission methods, a nitrogen oxide ultra-low emission system, an air supply device and a flow control module. The system for use in carbon negative emission methods enables biomass to produce inorganic carbon and pyrolysis gas/gasification gas to realize negative emission of carbon. The nitrogen oxide ultra-low emission system enables fuel to be in mixed combustion with the pyrolysis gas/gasification gas to remove nitrogen oxides, which realizes ultra-low emission of the nitrogen oxides. The air supply device is in communication with a biomass pyrolysis coupling partial gasification and is in communication with the system for use in carbon negative emission methods and the nitrogen oxide ultra-low emission system. The pyrolysis gas/gasification gas enters the nitrogen oxide ultra-low emission system. The flow control module controls a flow ratio of a pyrolysis agent/gasification agent entering the system for use in carbon negative emission methods and flow of the pyrolysis gas/gasification gas and air entering the nitrogen oxide ultra-low emission system.

The present invention relates to a process for co-gasification of two or more carbonaceous feedstock, said process comprising combusting a first carbonaceous feedstock having high calorific value with low ash and high hydrogen content, to produce a heated effluent; carrying the heated effluent to second reactor where the heated effluent reacts with a second carbonaceous feedstock, having low calorific value with high ash and low hydrogen content, to produce synthesis gas.The present invention also relates to an apparatus for co-gasification of two or more carbonaceous feedstock, comprising a first reactor (3), having a first feedstock inlet port (1), a oxygen or air inlet port (2), a steam inlet port (9), a ash removal port (7), and a solid recycle port (6); a first cyclone separator (5) connected to the first reactor (3) through a first cyclone separator inlet port (4); a second reactor (16), having a second feedstock inlet port (10), and a ash removal port (15), the second reactor is connected to the first cyclone separator (5) through a gaseous inlet port (8); and a second cyclone separator (12), having a fine particles removal port (13), and an effluent port (14), wherein the second cyclone separator is connected to the second reactor through a second cyclone separator inlet port (11).

The present invention relates to a process for co-gasification of two or more carbonaceous feedstock, said process comprising combusting a first carbonaceous feedstock having high calorific value with low ash and high hydrogen content, to produce a heated effluent; carrying the heated effluent to second reactor where the heated effluent reacts with a second carbonaceous feedstock, having low calorific value with high ash and low hydrogen content, to produce synthesis gas.The present invention also relates to an apparatus for co-gasification of two or more carbonaceous feedstock, comprising a first reactor (3), having a first feedstock inlet port (1), a oxygen or air inlet port (2), a steam inlet port (9), a ash removal port (7), and a solid recycle port (6); a first cyclone separator (5) connected to the first reactor (3) through a first cyclone separator inlet port (4); a second reactor (16), having a second feedstock inlet port (10), and a ash removal port (15), the second reactor is connected to the first cyclone separator (5) through a gaseous inlet port (8); and a second cyclone separator (12), having a fine particles removal port (13), and an effluent port (14), wherein the second cyclone separator is connected to the second reactor through a second cyclone separator inlet port (11).

Carbon negative emission methods, a nitrogen oxide ultra-low emission system, an air supply device and a flow control module. The system for use in carbon negative emission methods enables biomass to produce inorganic carbon and pyrolysis gas/gasification gas to realize negative emission of carbon. The nitrogen oxide ultra-low emission system enables fuel to be in mixed combustion with the pyrolysis gas/gasification gas to remove nitrogen oxides, which realizes ultra-low emission of the nitrogen oxides. The air supply device is in communication with a biomass pyrolysis coupling partial gasification and is in communication with the system for use in carbon negative emission methods and the nitrogen oxide ultra-low emission system. The pyrolysis gas/gasification gas enters the nitrogen oxide ultra-low emission system. The flow control module controls a flow ratio of a pyrolysis agent/gasification agent entering the system for use in carbon negative emission methods and flow of the pyrolysis gas/gasification gas and air entering the nitrogen oxide ultra-low emission system.