Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

A carbonaceous fuel gasification system for all-steam gasification with carbon capture includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, volatiles, hydrogen, and volatiles at outlets. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying fluid, and steam. The gasification chamber produces syngas, ash, and steam at one or more outlets. A combustion chamber receives a mixture of hydrogen and oxidant and burns the mixture of hydrogen and oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and nitrogen. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. The system of the present teaching produces nitrogen free high hydrogen syngas for applications such as IGCC with CCS, CTL, and Polygeneration plants.

Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

This invention relates to a method and apparatus for gasifying or liquifying coal. In particular, the method comprises reacting a coal with a molten aluminum or aluminum alloy bath. The apparatus includes a reaction vessel for carrying out the reaction, as well as other equipment necessary for capturing and removing the reaction products. Further, the process can be used to cogenerate electricity using the excess heat generated by the process.

A land based or marine vessel based system for generating power from syngas utilizes a feedstock of waste material acquired from waste dumps, municipalities, and/or ports of call of the marine vessel. The marine vessel or land based system can be retrofitted to be fueled by the waste material. The syngas is used to provide propulsive and/or electrical power for the marine vessel or the land based system. The waste material is not just a feedstock for the syngas but is provided with payment from the ports of call to take the waste material away. The marine vessel also collects garbage floating on the waterway along the voyage between the various ports of call for use as feedstock in the production of syngas. The modular syngas generation system further generates H.sub.2 from the syngas. The H.sub.2 generated thereby is used to fuel an H.sub.2 fuel cell for the generation of electrical power.

This invention relates to a power recovery process in waste steam/CO.sub.2 reformers in which a waste stream can be made to release energy without having to burn the waste or the syngas. This invention in some embodiments does not make use of fuel cells as a component but makes use of exothermic chemical reactors using syngas to produce heat, such as Fischer-Tropsch synthesis. It also relates to control or elimination of the emissions of greenhouse gases in the power recovery process of this invention with the goal of producing energy in the future carbonless world economy.

A system for producing high purity carbon monoxide and hydrogen as well as activated carbon includes a pyrolysis reactor, a gasifier, a combustion turbine, a boiler, a steam turbine, a combined cycle unit and an electrolysis unit. Liquid fuel from the pyrolysis reactor is provided to the combustion turbine. Liquid and gaseous fuels are provided to the boiler. Compressed oxygen from the electrolysis unit is provided to the combustion turbine. Electric power from the combustion turbine and steam turbine are provided to the electrolysis unit. The gasifier includes a preheat region, a gasification region, and a cooling region. CO.sub.2 and O.sub.2 are injected into the gasifier at multiple injection levels to create an isothermal gasification region to produce CO. The CO.sub.2 and O.sub.2 are preheated in a heat exchanger using the CO exiting from the gasifier prior to injection.

An integrated refinery process for the disposal of metal-containing spent coked catalyst from hydrotreating and/or hydrocracking unit operations includes introducing the spent coked catalyst into a membrane wall gasification reactor in the form of flowable particles along with predetermined amounts of oxygen and steam based upon an analysis of the hydrocarbon content of the coke, and optionally, a liquid hydrocarbon; gasifying the feed to produce synthesis gas and a slag material; recovering and subjecting the slag material to further processes in preparation for a leaching step to solubilize and form one or more active phase metal compounds that are recovered from the leaching solution, either separately by sequential processing, or together. The recovered active metal compounds can be used, e.g., in preparing fresh catalyst for use in the refinery's hydroprocessing units.

A process for the manufacture of one or more useful products comprises: gasifying a carbonaceous feedstock comprising waste materials and/or biomass in a gasification zone to generate a raw synthesis gas; supplying at least a portion of the raw synthesis gas to a clean-up zone to remove contaminants and provide a clean synthesis gas; supplying the clean synthesis gas to a first further reaction train to generate at least one first useful product and a tailgas; and diverting selectively on demand a portion of at least one of the carbonaceous feedstock, the clean synthesis gas, the tailgas and the light gas fraction to heat or power generation within the process, in response to external factors to control the carbon intensity of the overall process and enable GHG emission savings.