Patent classifications
C10M2207/144
ALKYLPHENOL DETERGENTS
The disclosed technology provides a lubricating composition comprising an oil of lubricating viscosity and a detergent comprising a polyolefin-substituted hydroxy-aromatic carboxylic acid or salt thereof, wherein the polyolefin is derived from a branched alkene having at least 4 carbon atoms and wherein the polyolefin has a number average molecular weight of 150 to 800. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.
REDUCED FRICTION LUBRICANTS COMPRISING MAGNESIUM DETERGENTS AND/OR OVERBASED MAGNESIUM DETERGENTS AND MOLYBDENUM BASED FRICTION MODIFIERS
The addition of mixed thio acid amide molybdenum dithiocarbamates to lubricant compositions comprising magnesium detergents and/or overbased magnesium detergents, e.g., overbased magnesium sulfonate, provides lubricant compositions that suppress Low Speed Pre-Ignition and possess excellent low friction characteristics. Furthermore, the addition of molybdenum based friction reducing additives, e.g., mixed thio acid amide molybdenum dithiocarbamates, in combination with one or more fatty acid 2-hydroxyalkylamides, to lubricant compositions comprising magnesium detergents or overbased magnesium detergents provides lubricant compositions that suppress Low Speed Pre-ignition and possess excellent low friction characteristics.
REDUCED FRICTION LUBRICANTS COMPRISING MAGNESIUM DETERGENTS AND/OR OVERBASED MAGNESIUM DETERGENTS AND MOLYBDENUM BASED FRICTION MODIFIERS
The addition of mixed thio acid amide molybdenum dithiocarbamates to lubricant compositions comprising magnesium detergents and/or overbased magnesium detergents, e.g., overbased magnesium sulfonate, provides lubricant compositions that suppress Low Speed Pre-Ignition and possess excellent low friction characteristics. Furthermore, the addition of molybdenum based friction reducing additives, e.g., mixed thio acid amide molybdenum dithiocarbamates, in combination with one or more fatty acid 2-hydroxyalkylamides, to lubricant compositions comprising magnesium detergents or overbased magnesium detergents provides lubricant compositions that suppress Low Speed Pre-ignition and possess excellent low friction characteristics.
Lubricating oil compositions
A crankcase lubricating oil composition for the crankcase of a spark-ignited or compression-ignited internal combustion engine, comprising a magnesium-containing detergent, in an amount sufficient to provide from 200-4000 ppm magnesium to the lubricating oil composition, in combination with an oil-soluble or oil-dispersible molybdenum compound in an amount sufficient to provide from 600-1500 ppm molybdenum atoms to the lubricating oil composition, and with an oil-soluble or oil-dispersible boron-containing compound in an amount sufficient to provide from 200-600 ppm boron atoms to the lubricating oil composition to improve the friction and fuel economy performance.
Lubricating oil compositions
A crankcase lubricating oil composition for the crankcase of a spark-ignited or compression-ignited internal combustion engine, comprising a magnesium-containing detergent, in an amount sufficient to provide from 200-4000 ppm magnesium to the lubricating oil composition, in combination with an oil-soluble or oil-dispersible molybdenum compound in an amount sufficient to provide from 600-1500 ppm molybdenum atoms to the lubricating oil composition, and with an oil-soluble or oil-dispersible boron-containing compound in an amount sufficient to provide from 200-600 ppm boron atoms to the lubricating oil composition to improve the friction and fuel economy performance.
LUBRICATING OIL COMPOSITION
A lubricating oil composition including: a lubricating base oil; (A) a poly(meth)acrylate having a weight average molecular weight of no more than 50,000, in an amount of 2 to 10 mass %; (B) a phosphite ester of the general formula (1) in an amount of 0.01 to 0.06 mass % in terms of P; (C) a thiadiazole compound in an amount of 0.01 to 0.2 mass %; and (D) a Ca salicylate detergent in an amount of 0.005 to 0.03 mass % in terms of Ca, wherein the lubricating oil composition has a kinematic viscosity at 40 C. of 4.0 to 20.0 mm.sup.2/s, and a kinematic viscosity at 100 C. of 1.8 to 5.2 mm.sup.2/s; and has a ratio [S]/[P] of 2.2 to 4.0, wherein the [S] represents a sulfur content, and the [P] represents a phosphorus content:
##STR00001##
wherein R.sup.1 and R.sup.2 are each independently a group having 5 to 20 carbons represented by the general formula (2); and
##STR00002##
wherein R.sup.3 is a C2-17 linear chain hydrocarbon group, and R.sup.4 is a C2-17 linear chain hydrocarbon group.
Automatic transmission oil composition
An automatic transmission oil composition includes 80 to 85 wt % of a base oil, 1 to 5 wt % of metallocene polyalphaolefin, 1 to 5 wt % of a detergent-dispersant, 0.01 to 0.03 wt % of a trinuclear molybdenum-based dialkyldithiocarbamate friction modifier, 3 to 10 wt % of a viscosity modifier, and 3 to 5 wt % of an anti-wear additive. The automatic transmission oil composition is prepared by mixing base oil with metallocene polyalphaolefin and a trinuclear molybdenum-based dialkyldithiocarbamate friction modifier at specific mixing ratios, whereby the dynamic friction coefficient can be maintained at an equivalent level and the metal friction coefficient can be reduced, thus improving the power transfer efficiency between transmission metals and fuel economy (an improvement of 1.5% or more), increasing durability, and minimizing energy loss.
LUBRICATING OIL COMPOSITION
The present invention relates to a lubricating oil composition containing a base oil (A), a molybdenum dithiocarbamate (B), an ester-based ashless friction modifier (C), and a metal salicylate (D), wherein the content of a molybdenum atom derived from the molybdenum dithiocarbamate (B) is 650 ppm by mass or more on the basis of the whole amount of the lubricating oil composition; a content ratio [C/B.sub.Mo] of the ester-based ashless friction modifier (C) to a molybdenum atom derived from the molybdenum dithiocarbamate (B) is 5.0 to 10 in terms of a mass ratio; the content of a salicylate soap group derived from the metal salicylate (D) is 0.50% by mass or more on the basis of the whole amount of the lubricating oil composition; and a kinematic viscosity at 100 C. is 4.0 mm.sup.2/s or more and less than 9.3 mm.sup.2/s, and a high-temperature high-shear viscosity at 150 C. is 1.7 mPa.Math.s or more and less than 2.9 mPa.Math.s. In accordance with the present invention, a viscosity-reduced lubricating oil composition in which nonetheless a molybdenum dithiocarbamate and an ashless friction modifier are jointly used, not only friction can be reduced early after commencement of lubrication, but also such a state can be maintained, is provided.
LUBRICATING OIL COMPOSITION
The present invention relates to a lubricating oil composition containing a base oil (A), a molybdenum dithiocarbamate (B), an ester-based ashless friction modifier (C), and a metal salicylate (D), wherein the content of a molybdenum atom derived from the molybdenum dithiocarbamate (B) is 650 ppm by mass or more on the basis of the whole amount of the lubricating oil composition; a content ratio [C/B.sub.Mo] of the ester-based ashless friction modifier (C) to a molybdenum atom derived from the molybdenum dithiocarbamate (B) is 5.0 to 10 in terms of a mass ratio; the content of a salicylate soap group derived from the metal salicylate (D) is 0.50% by mass or more on the basis of the whole amount of the lubricating oil composition; and a kinematic viscosity at 100 C. is 4.0 mm.sup.2/s or more and less than 9.3 mm.sup.2/s, and a high-temperature high-shear viscosity at 150 C. is 1.7 mPa.Math.s or more and less than 2.9 mPa.Math.s. In accordance with the present invention, a viscosity-reduced lubricating oil composition in which nonetheless a molybdenum dithiocarbamate and an ashless friction modifier are jointly used, not only friction can be reduced early after commencement of lubrication, but also such a state can be maintained, is provided.
Additive concentrates
The use of polyalkylenyl succinic anhydrides to stabilize an additive concentrate which includes a salicylate detergent and a nitrogen-free ashless organic friction modifier.