A method for producing a lubricant in producing an overbased calcium sulfonate, which is converted from the vaterite form into the calcite form and, finally, a calcium sulfonate grease is produced by heating the mixture. A lubricant may comprise at least one ester composition, calcium carbonate and at least one overbased alkylbenzene sulfonate. The basicity of the mixture is limited during the preparation of the overbased calcium sulfonate to a TBN of at most 550 mg KOH/g and during the conversion of the calcium sulfonate to a TBN of at most 450 mg KOH/g. Both the calcium sulfonate and the grease containing said calcium sulfonate may be produced exclusively on an ester basis, so that the end product does not contain any mineral oil and is therefore easily and completely biodegradable.

The present invention provides a refrigerating machine oil comprising a lubricating base oil and at least one selected from the group consisting of an amine salt of phosphonic acid and an amine salt of phosphonic acid monoester, and a method for producing the same.

The invention relates to a food-compatible high-temperature lubricant, more particularly a high-temperature oil and a high-temperature grease, comprising the following components: a) at least one oil selected from a trimellitic ester or a mixture of different trimellitic esters, alkylaromatics, preferably an aliphatically substituted naphthalene, or estolides; b) a hydrogenated or fully hydrogenated polyisobutylene or a mixture of hydrogenated or fully hydrogenated polyisobutylene; and c) additives individually or in combination.

In the case of the high-temperature grease, a thickener is added.

Provided herein are compositions containing at least one estolide compound and at least one ene and/or Diels Alder compound. In certain embodiments, the addition of at least one ene and/or Diels Alder compound to an estolide-containing composition may improve the cold temperature, viscometric, and/or anti-wear properties of the composition.

The present invention provides a working fluid composition for a refrigerating machine, comprising: a refrigerating machine oil comprising, as a base oil, a mixed ester of (A) a complex ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane and pentaerythritol, a C6-C12 polybasic acid, and a C4-C18 monohydric alcohol or a C4-C18 monocarboxylic fatty acid, and (B) a polyol ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane, pentaerythritol and dipentaerythritol, and a C4-C18 monocarboxylic fatty acid, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; and a hydrocarbon refrigerant having 3 or 4 carbon atoms, wherein a refrigerant dissolved viscosity, at a temperature of 80° C. and an absolute pressure of 1.5 MPa, is 1.0 mm.sup.2/s or more.

The present invention provides a refrigerating machine oil containing a lubricating base oil, a dialkyl hydrogen phosphite having two alkyl groups having 1 to 12 carbon atoms in the molecule, and an epoxy compound.

The present invention provides a working fluid composition for a refrigerating machine, comprising: a refrigerating machine oil comprising, as a base oil, a mixed ester of (A) a complex ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane and pentaerythritol, a C6-C12 polybasic acid, and a C4-C18 monohydric alcohol or a C4-C18 monocarboxylic fatty acid, and (B) a polyol ester obtainable by synthesis of from at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane, pentaerythritol and dipentaerythritol, and a C4-C18 monocarboxylic fatty acid, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; and tetrafluoropropene as a refrigerant, wherein a refrigerant dissolved viscosity, at a temperature of 80° C. and an absolute pressure of 1.6 MPa, is 1.5 mm.sup.2/s or more.

The invention relates to a food-grade high-temperature lubricant, more particularly a high-temperature oil and a high-temperature grease, comprising the following components: a) at least one oil selected from a trimellitic ester or a mixture of different trimellitic esters, alkylaromatics, preferably an aliphatically substituted naphthalene, or estolides; b) a hydrogenated or fully hydrogenated polyisobutylene or a mixture of hydrogenated or fully hydrogenated polyisobutylene; and c) additives individually or in combination.

In the case of the high-temperature grease, a thickener is added.

The present disclosure relates to methods and compositions for making bio-based, biodegradable, and non-bioaccumulating lubricating base oils generated by esterifying alkoxylated polyols (average alkoxylation ≥3) with long-chain (≥C14) saturated and unsaturated fatty acids (FA) or fatty acids modified using industry recognized techniques.

Provided herein are compositions comprising at least one estolide compound of formula:

##STR00001##

in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R.sub.1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.3 and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are uses of the compositions described herein.