Provided is a grain-oriented electrical steel sheet which has been subjected to heat-resistant magnetic domain refining treatment and can effectively suppress carburizing and nitriding during stress relief annealing. The grain-oriented electrical steel sheet has a plurality of grooves on one side that extend linearly across the rolling direction and are lined up at intervals in the rolling direction, and has at least a forsterite film on a surface of the steel sheet, where an average thickness of the forsterite film formed on the floor of the grooves is 0.45 μm or more, and a standard deviation a of the thickness is 0.34 μm or less.

A high permeability grain oriented electrical steel having a chemistry comprising, all in weight percent, 2.5% to 4.5% silicon, 0.02% to 0.08% carbon, 0.01 to 0.05% aluminum, 0.005% to 0.050% sulfur or selenium, 0.02 to 0.20% manganese, 0.05 to 0.20% tin, 0.05 to 1% copper, 0.5% to 2.0% chromium, up to 0.10% phosphorus and up to 0.20% antimony with the balance being essentially iron and residual elements. The steel contains chromium and phosphorus in such amounts that a Cr:(P+0.25Sb) ratio is below 80:1 or, below 50:1, or below 30:1 which provides highly stable magnetic properties in the finished steel sheet. A hot processed band comprised of such steel is annealed and rapidly cooled after such annealing at a rate of at least 50° C. per second from 875-950° C. to a temperature below 400° C. prior to cold rolling to final thickness. Such steel forming a hot processed band having a thickness of from 1.5 to 4.0 mm and having a volume resistivity of at least 50 μΩ-cm, an austenite volume fraction (γ1150° C.) of at least 20%, and an isomorphic layer thickness of at least 2% of the total thickness on at least one surface of the hot processed band.

Grain-oriented electrical steel sheet excellent in magnetic properties and adhesion of a primary coating to a base steel sheet and with few defects where the base metal is exposed in point defects and a method for manufacturing grain-oriented electrical steel sheet are provided. This is characterized by being provided with a base steel sheet and a primary coating. The primary coating satisfies (1) Number density D3 of Al concentrated regions: 0.015 to 0.150/μm.sup.2 (2) (Area S5 of regions comprised of anchoring oxide layer regions and Al concentrated regions)/(area S3 of Al concentrated regions)≥0.30, (3) Distance H5 of mean value of heights in thickness direction of regions of comprised of anchoring oxide layer regions and Al concentrated regions minus HO: 0.4 to 4.0 μm, (4) (Perimeter L5 of regions comprised of anchoring oxide layer regions and Al concentrated regions)/(observed area S0): 0.020 to 0.500 μm/μ.sup.2, and (5) (Area S1 of anchoring oxide layer regions)/(observed area S0)≥0.15.

A grain-oriented electrical steel sheet has a steel sheet and an insulating coating which is formed on a surface of the steel sheet. In the insulating coating, a metal phosphate and a colloidal silica are contained, the colloidal silica is contained in an amount of 20 to 150 parts by mass with respect to 100 parts by mass of the metal phosphate, one or more kinds of fine particles selected from the group consisting of silicon carbide, silicon nitride, aluminum nitride, boron nitride, sialon, and cordierite are further contained in an amount of 0.5 to 7 parts by mass with respect to 100 parts by mass of the metal phosphate, an average particle size of the fine particles is 0.3 to 7.0 μm, crystallized ratio of the metal phosphate is 2% to 40%, and chromium is not contained.

According to an exemplary embodiment of the present invention, a method for manufacturing a grain-oriented electrical steel sheet includes: a step of hot-rolling a slab to manufacture a hot-rolled steel sheet; a step of performing hot-rolled sheet annealing on the hot-rolled steel sheet; a step of performing primary cold-rolling on the hot-rolled sheet annealed hot-rolled steel sheet; a step of performing primary decarburization annealing on the primarily cold-rolled steel sheet; a step of performing secondary cold-rolling on the decarburization-annealed steel sheet; a step of performing secondary decarburization annealing on the secondarily cold-rolled steel sheet; and a step of performing continuous annealing on the secondarily decarburization-annealed steel sheet.

A grain-oriented electrical steel sheet having a metallographic structure after secondary-recrystallized annealing including matrix grains of Goss-oriented secondary recrystallized grains, wherein an existence frequency of Goss-oriented crystal grains having a major diameter of 5 mm or less in the matrix grains is 1.5 grains/cm.sup.2 or more and 8 grains/cm.sup.2 or less, and the magnetic flux density B8 is 1.88 T or more, and wherein deviation angles from a rolling direction of [001] direction of the Goss-oriented crystal grains having the major diameter of 5 mm or less are 7″ or less and 5° or less, in terms of a simple or arithmetic average of α angle and β angle, respectively, wherein the α angle represents an angle formed by a longitudinal direction and a projection of the [001] on a specimen surface, and the β angle represents a tilt of the [001] out of the specimen surface.

A grain oriented electrical steel sheet includes the texture aligned with Goss orientation. In the grain oriented electrical steel sheet, when (α.sub.1 β.sub.1 γ.sub.1) and (α.sub.2 β.sub.2 γ.sub.2) represent deviation angles of crystal orientations measured at two measurement points which are adjacent on the sheet surface and which have an interval of 1 mm, the boundary condition BA is defined as |γ.sub.2−γ.sub.1|≥0.5°, and the boundary condition BB is defined as [(α.sub.2−α.sub.1).sup.2+(β.sub.2−β.sub.1).sup.2+(γ.sub.2−γ.sub.1).sup.2].sup.1/2≥2.0°, the boundary which satisfies the boundary condition BA and which does not satisfy the boundary condition BB is included.

An annealing separator for an oriented electrical steel sheet includes: a first component including a Mg oxide or a Mg hydroxide; and a second component including one kind among oxides and hydroxides of a metal selected from Al, Ti, Cu, Cr, Ni, Ca, Zn, Na, K, Mo, In, Sb, Ba, Bi, and Mn, or two or more kinds thereof.

Grain-oriented electrical steel sheet excellent in magnetic properties and excellent in adhesion of a primary coating to the steel sheet is provided. The grain-oriented electrical steel sheet is provided with a base steel sheet having a chemical composition containing C: 0.005% or less, Si: 2.5 to 4.5%, Mn: 0.050 to 1.000%, a total of S and Se: 0.005% or less, sol. Al: 0.005% or less, and N: 0.005% or less and having a balance of Fe and impurities and a primary coating having Mg.sub.2 SiO.sub.4 as a main constituent formed on a surface of the base steel sheet. A peak position of Al emission intensity obtained when conducting elemental analysis by glow discharge spectrometry from a surface of the primary coating in a thickness direction is present in a range of 2.0 to 12.0 μm from a surface of the primary coating to the thickness direction. A sum of perimeters of the Al oxides at the peak position of Al emission intensity is 0.20 to 1.00 μm/μm.sup.2, and a number density of Al oxides is 0.02 to 0.20/μm.sup.2.

A preparation method of glassless grain-oriented silicon steel includes the following operations. During a decarburization annealing, a thickness of an oxide film on a surface of strip is 1.5-2.5 μm; an atomic weight ratio of Si element and Fe element in the oxide film satisfies: Si/(Si+Fe)≥0.76; during a high-temperature annealing, a cooling stage includes sequentially: cooling with an inner cover when a temperature drops from 1200° C. to 500° C.; wherein a protective gas is a mixed gas containing nitrogen and hydrogen, and a volume percentage of the hydrogen in the mixed gas is >3%; cooling with the inner cover when the temperature drops from 500° C. to 200° C.; wherein the protective gas is nitrogen; and cooling in air by removing the inner cover when the temperature is <200° C.