A system such as a hydrogen refueling station and a method are provided. The system includes a cryotank for storing a liquefied fuel having liquid and vapor phases, a pump for providing a first stream of the liquefied fuel in the liquid phase from the cryotank, a heat exchanger for converting at least a portion of the first stream to a gaseous fuel, a dispenser for dispensing at least a portion of the gaseous fuel to a receiving fuel tank, a refrigeration unit integrated with the heat exchanger, and a backup power unit. The refrigeration unit and the heat exchanger exchange heat with each other, and the refrigeration unit provides cooling capacity to a facility of environment where cooling is needed. The backup power unit generate electric power by using a second stream of the liquefied fuel in the vapor phase or in the liquid phase or both.

The present disclosure is directed towards the design of electrochemical cells for use in high pressure or high differential pressure operations. The electrochemical cells of the present disclosure have non-circular external pressure boundaries, i.e., the cells have non-circular profiles. In such cells, the internal fluid pressure during operation is balanced by the axial tensile forces developed in the bipolar plates, which prevent the external pressure boundaries of the cells from flexing or deforming. That is, the bipolar plates are configured to function as tension members during operation of the cells. To function as an effective tension member, the thickness of a particular bipolar plate is determined based on the yield strength of the material selected for fabricating the bipolar plate, the internal fluid pressure in the flow structure adjacent to the bipolar plate, and the thickness of the adjacent flow structure.

The present disclosure is directed towards the design of electrochemical cells for use in high pressure or high differential pressure operations. The electrochemical cells of the present disclosure have non-circular external pressure boundaries, i.e., the cells have non-circular profiles. In such cells, the internal fluid pressure during operation is balanced by the axial tensile forces developed in the bipolar plates, which prevent the external pressure boundaries of the cells from flexing or deforming. That is, the bipolar plates are configured to function as tension members during operation of the cells. To function as an effective tension member, the thickness of a particular bipolar plate is determined based on the yield strength of the material selected for fabricating the bipolar plate, the internal fluid pressure in the flow structure adjacent to the bipolar plate, and the thickness of the adjacent flow structure.

The invention provides a method of storing varying or intermittent electrical energy and one or more of hydrogen (H.sub.2) and oxygen (O.sub.2) with an energy apparatus, the method comprising: providing the first cell aqueous liquid, the second cell aqueous liquid, and electrical power from an external power source to the functional unit thereby providing an electrically charged functional battery unit and one or more of hydrogen (H.sub.2) and oxygen (O.sub.2) stored in said storage system, wherein during at least part of a charging time the functional unit is charged at a potential difference between the first cell electrode and the second cell electrode of more than 1.37 V.

The invention provides a method of storing varying or intermittent electrical energy and one or more of hydrogen (H.sub.2) and oxygen (O.sub.2) with an energy apparatus, the method comprising: providing the first cell aqueous liquid, the second cell aqueous liquid, and electrical power from an external power source to the functional unit thereby providing an electrically charged functional battery unit and one or more of hydrogen (H.sub.2) and oxygen (O.sub.2) stored in said storage system, wherein during at least part of a charging time the functional unit is charged at a potential difference between the first cell electrode and the second cell electrode of more than 1.37 V.

A hydrogen generator comprises an electrolytic module, a hydrogen water cup, an integrated passageway device and an automatic diversion device. The electrolytic module is configured to electrolyze water and generate gas comprising hydrogen. The hydrogen water cup is configured for containing liquid, and injecting the gas comprising hydrogen into the liquid to form hydrogen liquid. The integrated passageway device is stacked above the electrolytic module, and includes an inlet gas passageway, an outlet gas passageway and a gas communication passageway. The automatic diversion device is configured for selectively communicating the inlet gas passageway, the hydrogen water cup and the outlet gas passageway or selectively communicating the inlet gas passageway, the gas communication passageway and the outlet gas passageway.

A hydrogen generator comprises an electrolytic module, a hydrogen water cup, an integrated passageway device and an automatic diversion device. The electrolytic module is configured to electrolyze water and generate gas comprising hydrogen. The hydrogen water cup is configured for containing liquid, and injecting the gas comprising hydrogen into the liquid to form hydrogen liquid. The integrated passageway device is stacked above the electrolytic module, and includes an inlet gas passageway, an outlet gas passageway and a gas communication passageway. The automatic diversion device is configured for selectively communicating the inlet gas passageway, the hydrogen water cup and the outlet gas passageway or selectively communicating the inlet gas passageway, the gas communication passageway and the outlet gas passageway.

A device and a method for producing hydrogen and byproduct oxygen by using green electricity electrolyzed water are provided. The device comprises an oxygen purifying system, a heat exchange system, an air separation compression and expansion system, an air separation rectification system and a liquid oxygen storage system. The method comprises the following steps: first, purifying oxygen prepared by electrolyzing water by green electricity to remove impurities such as hydrogen, carbon monoxide, carbon dioxide and water in the oxygen, then feeding the pure oxygen into the heat exchange system, performing heat exchange liquefaction to obtain liquid oxygen, coupling the liquid oxygen generated by rectification of the air separation rectification system, and obtaining pressurized oxygen through the heat exchange system and the air separation compression and expansion system.

A device and a method for producing hydrogen and byproduct oxygen by using green electricity electrolyzed water are provided. The device comprises an oxygen purifying system, a heat exchange system, an air separation compression and expansion system, an air separation rectification system and a liquid oxygen storage system. The method comprises the following steps: first, purifying oxygen prepared by electrolyzing water by green electricity to remove impurities such as hydrogen, carbon monoxide, carbon dioxide and water in the oxygen, then feeding the pure oxygen into the heat exchange system, performing heat exchange liquefaction to obtain liquid oxygen, coupling the liquid oxygen generated by rectification of the air separation rectification system, and obtaining pressurized oxygen through the heat exchange system and the air separation compression and expansion system.

An electrochemical process implements, in a decoupled manner, a first step of electrolysis of an electrolyte to produce gaseous oxygen in a chamber and a second step of electrochemical conversion of H+ ions into gaseous hydrogen in a chamber which contains a liquid phase and a gas phase not dissolved in the liquid phase. Gaseous hydrogen produced in the conversion step is partly present in the gaseous headspace of chamber and as bubbles in the electrolyte, and partly dissolved in the electrolyte which is saturated with hydrogen. The electrolyte has at least one redox pair (A/B) forming at least one intermediate vector enabling the decoupling of the first and second steps. The interface between the gas and liquid phases is increased during the second step to accelerate the diffusion, from liquid phase to gas phase, of the dissolved hydrogen able to supersaturate the electrolyte. Pressurized gaseous hydrogen is then collected.