An electrochemical electrode according to the present invention may prevent agglomeration and desorption of a catalyst even when a catalyst in a particle form is used, because a protective layer containing hydrogel is used, such that stability may be secured, thereby implementing an electrode having a long duration.

An electrochemical electrode according to the present invention may prevent agglomeration and desorption of a catalyst even when a catalyst in a particle form is used, because a protective layer containing hydrogel is used, such that stability may be secured, thereby implementing an electrode having a long duration.

An organic hydride production apparatus includes: an electrolyte membrane having proton conductivity; a cathode, provided on one side of the electrolyte membrane, that contains a cathode catalyst used to hydrogenate a hydrogenation target substance using protons to produce an organic hydride; an anode, provided opposite to the one side of the electrolyte membrane, that contains an anode catalyst used to oxidize water to produce protons; and an anode support, provided opposite to the electrolyte membrane side of the anode, that supports the anode. The anode support is formed of an elastic porous body of which the Young's modulus is greater than 0.1 N/mm.sup.2 and less than 43 N/mm.sup.2.

An organic hydride production apparatus includes: an electrolyte membrane having proton conductivity; a cathode, provided on one side of the electrolyte membrane, that contains a cathode catalyst used to hydrogenate a hydrogenation target substance using protons to produce an organic hydride; an anode, provided opposite to the one side of the electrolyte membrane, that contains an anode catalyst used to oxidize water to produce protons; and an anode support, provided opposite to the electrolyte membrane side of the anode, that supports the anode. The anode support is formed of an elastic porous body of which the Young's modulus is greater than 0.1 N/mm.sup.2 and less than 43 N/mm.sup.2.

A method of producing methanol from methane in which hot-electrons generated under an external electric field in a process taking place in a multi-layer heterostructure comprising a nanoporous layer drive the conversion from methane to methanol. The structure generates hot electrons by providing spatial enhancement of the electric field, and purges hot holes which are created when hot electrons depart. This combination enhances heterogeneous catalysis of the conversion reaction.

A method of producing methanol from methane in which hot-electrons generated under an external electric field in a process taking place in a multi-layer heterostructure comprising a nanoporous layer drive the conversion from methane to methanol. The structure generates hot electrons by providing spatial enhancement of the electric field, and purges hot holes which are created when hot electrons depart. This combination enhances heterogeneous catalysis of the conversion reaction.

The present invention realizes industrially excellent effects such that when electric power having a large output fluctuation, such as renewable energy, is used as a power source, electrolysis performance is unlikely to be deteriorated and excellent catalytic activity is retained stably over a longer period of time, and in addition, the present invention provides a technique that enables forming a catalyst layer of an oxygen generation anode, which gives such excellent effects, with a more versatile materials and by a simple electrolysis method. Provided are an alkaline water electrolysis method including supplying an electrolyte obtained by dispersing a catalyst containing a hybrid nickel-iron hydroxide nanosheet (NiFe-ns) being a composite of a metal hydroxide and an organic substance to an anode chamber and a cathode chamber, and using the electrolyte for electrolysis in each chamber in common, an alkaline water electrolysis method including supplying an electrolyte obtained by dispersing a catalyst containing the NiFe-ns to an anode chamber and a cathode chamber, and performing electrolytic deposition of the NiFe-ns in the electrolytic cell during operation to electrolytically deposit the NiFe-ns on a surface of an electrically conductive substrate having a catalyst layer formed on a surface of an oxygen generation anode, thereby recovering and improving electrolysis performance, and an alkaline water electrolysis anode.

A method and an electrocatalytic electrode for electrochemically reducing carbon dioxide to methanol are provided. An exemplary electrocatalytic electrode includes copper (I) oxide crystals electrodeposited over an atomically smooth copper electrode.

A method for making a metal oxyhydroxide electrocatalytic material comprises titrating a precursor solution with a (bi)carbonate salt, the precursor solution comprising a first metal salt and a solvent, wherein the titration induces reactions between the (bi)carbonate salt and the first metal salt to provide first metal carbonate species in the titrated precursor solution; and exposing the titrated precursor solution to microwave radiation to decompose the first metal carbonate species to form the metal oxyhydroxide electrocatalytic material and carbon dioxide. Mixed metal oxyhydroxide electrocatalytic materials such as nickel-iron oxyhydroxide may be formed. Also provided are the materials themselves, electrocatalytic systems comprising the materials, and methods of using the materials and systems.

The present invention relates to an electrode comprising a metal deposit of zinc and silver, a process for preparing such an electrode, an electrolysis device comprising such an electrode and a method for CO.sub.2 electroreduction to CO using such an electrode as a cathode.