Described herein are electrodeposited corrosion-resistant multilayer coating and claddings that comprises multiple nanoscale layers that periodically vary in electrodeposited species or electrodeposited microstructures. The coatings may comprise electrodeposited metals, ceramics, polymers or combinations thereof. Also described herein are methods for preparation of the coatings and claddings.

Disclosed is a composite electroplating method for sintered NdFeB magnet, including: a process of pre-treating sintered NdFeB magnet, a process of electroplating the pre-treated sintered NdFeB magnet, and a process of cleaning and drying the electroplated sintered NdFeB magnet. The electroplating process forms a composite coating composed of a Zn coating, a Zn—Ni alloy coating, a Cu coating and a Ni coating on the surface of the sintered NdFeB magnet.

Disclosed is a composite electroplating method for sintered NdFeB magnet, including: a process of pre-treating sintered NdFeB magnet, a process of electroplating the pre-treated sintered NdFeB magnet, and a process of cleaning and drying the electroplated sintered NdFeB magnet. The electroplating process forms a composite coating composed of a Zn coating, a Zn—Ni alloy coating, a Cu coating and a Ni coating on the surface of the sintered NdFeB magnet.

A surface-treated metal plate including: a metal plate; and a nickel-cobalt binary alloy layer formed on the metal plate. When a part having a content ratio of oxygen atoms of 5 atomic % or more as measured by X-ray photoelectron spectroscopic analysis is an oxide coating film, the nickel-cobalt binary alloy layer contains the oxide coating film with a thickness of 0.5 to 30 nm on a surface thereof, and when a pressure cooker test including temperature increasing, retention for 72 hours under a water-vapor atmosphere at a temperature of 105° C. and a relative humidity of 100% RH, and temperature decreasing is performed, the amount of increase in the thickness of the oxide coating film is 28 nm or less.

A surface-treated metal plate including: a metal plate; and a nickel-cobalt binary alloy layer formed on the metal plate. When a part having a content ratio of oxygen atoms of 5 atomic % or more as measured by X-ray photoelectron spectroscopic analysis is an oxide coating film, the nickel-cobalt binary alloy layer contains the oxide coating film with a thickness of 0.5 to 30 nm on a surface thereof, and when a pressure cooker test including temperature increasing, retention for 72 hours under a water-vapor atmosphere at a temperature of 105° C. and a relative humidity of 100% RH, and temperature decreasing is performed, the amount of increase in the thickness of the oxide coating film is 28 nm or less.

A housing for a spark plug. The housing includes a bore along the longitudinal axis X of the housing, as the result of which the housing has an outer side and an inner side, and an electroplated or chemically applied nickel-containing protective layer situated on at least one portion of the outer side of the housing and a sealing layer situated on the nickel-containing protective layer. The sealing layer contains silicon. A first intermediate layer is applied between the housing and the nickel-containing protective layer and/or a second intermediate layer is applied between the nickel-containing protective layer and the sealing layer and/or a cover layer is applied on the sealing layer. The sealing layer may be free of chromium.

The invention relates to a process for producing a corrosion-inhibiting coating for substrates having a surface consisting of zinc, magnesium, aluminum or one of their alloys, wherein the surface to be treated is brought into contact in direct succession with two aqueous treatment solutions containing chromium(III) ions, metal ions of the substrate surface to be treated and at least one complexing agent. The first treatment solution has a pH in the range from 1.0 to 4.0, while the second treatment solution has a pH of from 3.0 to 12.0. The process of the invention produces a smaller amount of wastewater polluted with heavy metals.

The present invention belongs to the technical field of shoe spikes, and more particularly relates to a carborundum wear-resistant shoe spike. The carborundum wear-resistant shoe spike comprises a shoe spike main body and a nickel coating attached to the surface of the shoe spike main body; the surface of the shoe spike main body is also provided with a carborundum layer, and the nickel coating is disposed between the shoe spike main body and the carborundum layer. Compared with the prior art, the present invention lies in that the outer surface of the nickel coating is provided with the carborundum layer, and since the carborundum layer has the characteristics of good toughness, high hardness, good wear resistance and the like, the wear resistance property of the shoe spike can be greatly improved, and the service life of sports shoes using the shoe spike is prolonged.

The present invention belongs to the technical field of shoe spikes, and more particularly relates to a carborundum wear-resistant shoe spike. The carborundum wear-resistant shoe spike comprises a shoe spike main body and a nickel coating attached to the surface of the shoe spike main body; the surface of the shoe spike main body is also provided with a carborundum layer, and the nickel coating is disposed between the shoe spike main body and the carborundum layer. Compared with the prior art, the present invention lies in that the outer surface of the nickel coating is provided with the carborundum layer, and since the carborundum layer has the characteristics of good toughness, high hardness, good wear resistance and the like, the wear resistance property of the shoe spike can be greatly improved, and the service life of sports shoes using the shoe spike is prolonged.

A Ni-plated steel sheet according to an aspect of the present invention includes: a base steel sheet; an Fe—Ni diffusion alloy region disposed on the base steel sheet; and a Ni plating region disposed on the Fe—Ni diffusion alloy region, in which an average equivalent circle diameter of crystal grains made of Ni (fcc) in the Ni plating region measured in a cross section perpendicular to a rolled surface of the base steel sheet is 0.2 to 4.0 μm.