The present disclosure relates to a catalyst composition comprising: (a) nickel; (b) at least one promoter selected from Cu Zn, Mo, Co, Mg, Ce, Ti, Zr, Fe, Pd, Ag, Pt, or combinations thereof; and (c) a support material, wherein, the nickel loading is in the range of 6-19 wt % and the at least one promoter loading is in the range of 0.2-5 wt % with respect to the support material. The present disclosure further discloses a process for preparing a catalyst composition and a process each for the production of hydrogen gas and carbon nanotubes. Also disclosed herein, is use of a catalyst composition for obtaining hydrogen gas and carbon nanotubes.

The present disclosure relates to a catalyst composition comprising: (a) nickel; (b) at least one promoter selected from Cu Zn, Mo, Co, Mg, Ce, Ti, Zr, Fe, Pd, Ag, Pt, or combinations thereof; and (c) a support material, wherein, the nickel loading is in the range of 6-19 wt % and the at least one promoter loading is in the range of 0.2-5 wt % with respect to the support material. The present disclosure further discloses a process for preparing a catalyst composition and a process each for the production of hydrogen gas and carbon nanotubes. Also disclosed herein, is use of a catalyst composition for obtaining hydrogen gas and carbon nanotubes.

The present subject matter relates to co-producing H-CNG and CNTs. The process comprises adding catalyst to a first reactor (110) and activating the catalyst and performing a reaction to obtain H-CNG and CNTs. At a first predetermined time after reaction has progressed in the first reactor (110), catalyst is added to a second reactor (120), activated, and then the reaction proceeds simultaneously in the first reactor (110) and second reactor (120). The use of multiple reactors with staggered start times helps in the continuous co-production of H-CNG and CNTs. Catalyst preparation process is integrated with the co-production process for efficient heat recovery. The first and second reactors are fluidized bed reactors with cantilever trays having weirs for controlling the residence time of the catalyst in the reactor and thereby controlling the purity of CNTs produced.

The present subject matter relates to co-producing H-CNG and CNTs. The process comprises adding catalyst to a first reactor (110) and activating the catalyst and performing a reaction to obtain H-CNG and CNTs. At a first predetermined time after reaction has progressed in the first reactor (110), catalyst is added to a second reactor (120), activated, and then the reaction proceeds simultaneously in the first reactor (110) and second reactor (120). The use of multiple reactors with staggered start times helps in the continuous co-production of H-CNG and CNTs. Catalyst preparation process is integrated with the co-production process for efficient heat recovery. The first and second reactors are fluidized bed reactors with cantilever trays having weirs for controlling the residence time of the catalyst in the reactor and thereby controlling the purity of CNTs produced.

A system and a method for reduction or elimination of environmentally harmful or “greenhouse” gases in situations in which gaseous hydrocarbons are flared or vented from an oil and gas well are disclosed. The system configures to inject a chemically reactive, or dispersive, or reactive and dispersive atomized mist into a gas flow line leading to a flare stack. The mist reacts with the gas in the flow line to convert methane to hydrogen and carbon monoxide and to reduce other harmful gases, facilitating a clean-burning, compact flare of blue color due to the presence of primarily hydrogen, some carbon monoxide, and a small amount of residual methane. The hydrogen and carbon monoxide may be captured and stored before reaching the ignition point at the top of the flare stack.

Provided is a hydrogen supply system that supplies hydrogen. The hydrogen supply system includes: a dehydrogenation reaction unit that subjects a raw material including a hydride to a dehydrogenation reaction to obtain a hydrogen-containing gas; a heating mechanism that heats the dehydrogenation reaction unit by using electric power; and an electric power supply unit that supplies at least one of electric power based on renewable energy and electric power based on thermal power generation equipped with carbon dioxide capture and storage to the heating mechanism.

A production system includes a first reaction chamber and a second reaction chamber. The first reaction chamber is configured to receive a first hydrocarbon stream therein through an input port and to form carbon seeds and hydrogen gas therein via hydrocarbon pyrolysis of the first hydrocarbon stream. The second reaction chamber includes a first input port and a second input port. The second reaction chamber is configured to receive the carbon seeds through the first input port and a second hydrocarbon stream through the second input port, and to form carbon product elements and additional hydrogen gas in the second reaction chamber via hydrocarbon pyrolysis of the second hydrocarbon stream. The carbon product elements represent the carbon seeds with additional carbon structure grown on the carbon seeds.

A production system includes a first reaction chamber and a second reaction chamber. The first reaction chamber is configured to receive a first hydrocarbon stream therein through an input port and to form carbon seeds and hydrogen gas therein via hydrocarbon pyrolysis of the first hydrocarbon stream. The second reaction chamber includes a first input port and a second input port. The second reaction chamber is configured to receive the carbon seeds through the first input port and a second hydrocarbon stream through the second input port, and to form carbon product elements and additional hydrogen gas in the second reaction chamber via hydrocarbon pyrolysis of the second hydrocarbon stream. The carbon product elements represent the carbon seeds with additional carbon structure grown on the carbon seeds.

A hydrogen production apparatus includes: a first furnace configured to heat a mixed gas of a raw material gas, which contains at least methane, and hydrogen to 1,000° C. or more and 2,000° C. or less; and a second furnace configured to accommodate a catalyst for accelerating a reaction of a first gas generated in the first furnace to a nanocarbon material, and to maintain the first gas at 500° C. or more and 1,200° C. or less.

One or more reactants are flowed into thermal contact with a heating element in a reactor for a first time period. During a first part of a heating cycle, the one or more reactants are provided with a first temperature by heating with the heating element, such that one or more thermochemical reactions is initiated. The one or more thermochemical reactions includes pyrolysis, thermolysis, synthesis, hydrogenation, dehydrogenation, hydrogenolysis, or any combination thereof. The first heating element operates by Joule heating and has a porous construction that allows gas to flow therethrough. During a second part of the heating cycle, the one or more reactants are provided with a second temperature less than the first temperature, for example, by de-energizing the heating element. A duration of the first time period is equal to or greater than a duration of the heating cycle, which is less than five seconds.