The invention relates to a catalyst useful in the steam reforming of hydrocarbons and oxygenated hydrocarbons. The invention provides a method for preparing a catalyst comprising heating a spinel of formula ANi.sub.xFe.sub.(1-X)CrO.sub.4 where A is Mn or Mg and x is from 0 to 0.75 under reducing conditions at a temperature of from 800 to 1500° C., and catalysts obtainable by said method.

Methods for dry reforming with a red mud catalyst support composition, one method including providing a methane feed and carbon dioxide feed to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H.sub.2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.

The present disclosure relates generally to a methanol reforming catalyst composition comprising a ZnO phase, present in the composition in an amount of 20-75 wt. %; a zinc-aluminum spinel phase, present in the composition in an amount of 20-60 wt. %; and a Cu dopant phase, present in the composition in an amount of 0.1-20 wt. %. In various embodiments, the methanol reforming catalyst can achieve stable high methanol conversion rates and high hydrogen production rates at high temperatures (>300° C.).

The presently disclosed embodiments relate to the utilization of coal-derived fine mineral matter in chemical recycling of plastics or of solid mixed plastic waste. The instantly disclosed mineral based catalyst benefits the processes of catalytic cracking, gasification and steam reforming to maximize carbon utilization and production of plastics of original quality from recycled or renewable feedstocks while reducing the plastic pollution in the environment. The catalyst can be based on inorganic fine mineral matter, a natural ancient mineral mixture found in coal deposits and containing a plurality of transition metals, such as iron, copper, and manganese, as well as calcium, barium, magnesium, potassium, sodium, which can act as co-catalysts. Addition of the catalyst can convert plastic to syngas at a faction of the energy of conventional technologies.

The presently disclosed embodiments relate to the utilization of coal-derived fine mineral matter in chemical recycling of plastics or of solid mixed plastic waste. The instantly disclosed mineral based catalyst benefits the processes of catalytic cracking, gasification and steam reforming to maximize carbon utilization and production of plastics of original quality from recycled or renewable feedstocks while reducing the plastic pollution in the environment. The catalyst can be based on inorganic fine mineral matter, a natural ancient mineral mixture found in coal deposits and containing a plurality of transition metals, such as iron, copper, and manganese, as well as calcium, barium, magnesium, potassium, sodium, which can act as co-catalysts. Addition of the catalyst can convert plastic to syngas at a faction of the energy of conventional technologies.

The present disclosure is concerned with metal oxide nanowires, and more specifically, to crystalline ruthenium oxide (RuO.sub.2) nanowires, sol-gel synthetic methods for preparing the nanowires, and methods of using the nanowires in metal catalyzed oxidation of small organic molecules.

Methods for dry reforming with a red mud catalyst support composition, one method including providing a methane feed and carbon dioxide feed to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H.sub.2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.

Provided is a hydrogen production reactor as a reactor producing a reforming gas including hydrogen, in which a burning unit and a reforming unit are sequentially arranged and spaced apart from each other in a concentric structure based on a raw material transfer pipe positioned at a central axis of the reactor, including a heating raw material transfer pipe supplying a raw material to the burning unit, a burning unit burning the supplied raw material and supplying heat to the reforming unit, a reforming raw material phase change pipe positioned within the burning unit and heating the supplied raw material, and a reforming unit reforming the phase-changed raw material supplied from the reforming raw material phase change pipe, wherein the reforming raw material phase change pipe is provided as a coil surrounding an outer circumferential surface of a lower end of the heating raw material transfer pipe.

A nanocomposite catalyst includes a support, a multiplicity of nanoscale metal oxide clusters coupled to the support, and one or more metal atoms coupled to each of the nanoscale metal oxide clusters. Fabricating a nanocomposite catalyst includes forming nanoscale metal oxide clusters including a first metal on a support, and depositing one or more metal atoms including a second metal on the nanoscale metal oxide clusters. The nanocomposite catalyst is suitable for catalyzing reactions such as CO oxidation, water-gas-shift, reforming of CO.sub.2 and methanol, and oxidation of natural gas.

Integrated liquid fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongated tube having a gas-permeable wall with internal and external surfaces. The wall encloses an unobstructed gaseous flow passageway. At least a portion of the wall has CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The liquid fuel CPOX reformer also can include a vaporizer, one or more igniters, and a source of liquid reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the CPOX reactor unit.