A fuel processing system and method for a sulfur bearing fuel include a hydrodesulfurization reactor followed by an adsorbent bed for removing sulfur or sulfur containing species from the fuel. In certain embodiments, the adsorbent bed is a ZnO bed. In another embodiment, a fuel processing system and method for a sulfur bearing fuel include a steam reformer, a hydrodesulfurization reactor, and an adsorbent bed.

Process including the production of a hydrogen-containing synthesis gas by conversion of a hydrocarbon feedstock, wherein said process has a heat input provided by combustion of a plurality of process fuel streams and said plurality of process fuel streams comprises at least one fuel stream of ammonia. Combustion of said at least one fuel stream of ammonia is performed non-catalytically in at least one fired equipment.

Processes for converting a hydrocarbon-containing feed by pyrolysis and gasification/combustion. The hydrocarbon-containing feed and heated particles can be fed into a pyrolysis zone and contacted therein to effect pyrolysis of the hydrocarbons and produce a pyrolysis effluent. A gaseous stream rich in olefins and a particle stream rich in particles that include coke disposed thereon can be obtained from the pyrolysis effluent. A CO.sub.2-rich stream that includes, on a dry basis, CO.sub.2 at a concentration 90 vol %, based on the total volume of the CO.sub.2-rich stream, can be obtained from the gasification/combustion gas mixture.

A fuel processing system and method for a sulfur bearing fuel include a hydrodesulfurization reactor followed by an adsorbent bed for removing sulfur or sulfur containing species from the fuel. In certain embodiments, the adsorbent bed is a ZnO bed. In another embodiment, a fuel processing system and method for a sulfur bearing fuel include a steam reformer, a hydrodesulfurization reactor, and an adsorbent bed.

Systems and methods are provided for using oxycombustion to provide heat within a reverse flow reactor environment. The oxygen for the oxycombustion can be provided by oxygen stored in an oxygen storage component in the reactor. By using an oxygen storage component to provide the oxygen for combustion during the regeneration step, heat can be added to a reverse flow reactor while reducing or minimizing addition of diluents and while avoiding the need for an air separation unit. As a result, a regeneration flue gas can be formed that is substantially composed of CO.sub.2 and/or H.sub.2O without requiring the additional cost of creating a substantially pure oxygen-containing gas flow.

A fuel cell system is disclosed. The fuel cell system comprises: a fuel cell module including a plurality of unit cells for generating electrical energy by using oxygen of air and hydrogen of a reformed fuel gas; a first module including a burner part which burns an unreacted fuel gas and air discharged from the fuel cell module, an air-heating part which heats air through heat exchange with a hot combustion gas and a flame generated by the burner part and supplies the heated air to the fuel cell module, and a water vapor generation part which converts water, flowing through an inner portion thereof, into water vapor through heat exchange with a hot combustion gas generated by the burner part; and a second module which mixes a fuel supplied from an external fuel supply source and water vapor supplied from an water-vapor generator part, allows a water vapor reformation reaction to occur, and supplies a reformed fuel gas to the fuel cell module.

Integrated refinery processes and systems for generating hydrogen by direct decomposition of hydrocarbons. The integrated processes and systems can be used to capture carbon and sulfur in solid form, reducing carbon dioxide and sulfur oxide emissions. The processes include reacting sour gas with a metal-based sorbent in a reactor to produce sulfur-bearing solids and water, and to partially reform hydrocarbons in the sour gas to produce hydrogen-rich syngas; and cracking remaining hydrocarbons thermally with or without the presence of a catalyst to produce hydrogen and solid carbon.

The invention relates to a hydrogen plant for producing a hydrogen-comprising gas product comprisinga reformer system comprising at least one heat-recuperating reformer reaction unit (5) or a reformer system comprising two or more reformer units (5,22) in parallel, wherein at least one of said parallel reformer units (5) is present in the radiant section (12) of the reformer system, and at least one reformer unit (22) is located outside the radiant section (12) of the reformer system; a unit (8) configured to obtain hydrogen product gas; a carbon dioxide capture unit; the hydrogen plant further comprising a passage way configured to feed a hydrogen-comprising gas stream to the radiant section. The invention further relates to a process for producing a hydrogen-comprising gas product.

Systems and methods are provided for using a high heat capacity gas as at least a portion of the diluent during the regeneration step of a reverse flow reactor process. Instead of using nitrogen or air as the primary diluent gas, CO.sub.2 and/or H.sub.2O can be added as diluent gas for the regeneration step in the reaction cycle. Increasing the heat capacity of the diluent gas provides a reduction in the peak temperature within the reactor relative to the amount of fuel combusted during regeneration. This can allow for a reduction in the volume of diluent used during regeneration and/or an increase in the amount of fuel used. Reducing the volume of diluent can reduce the pressure drop during regeneration, which can provide a corresponding reduction in the amount of compression required for recycle of the diluent. Increasing the amount of fuel can allow for a corresponding increase in the amount of endothermic reaction performed during the reaction step.

A method and apparatus for reforming carbonaceous material into syngas containing hydrogen and CO gases is disclosed. In one embodiment, a hydrogen rich torch reactor is provided for defining a reaction zone proximate to torch flame. One input of the reactor receives input material to be processed. Further inputs may be provided, such as for example to introduce steam and/or gases such as methane, oxygen, hydrogen, or the like.