Bromine doping of silica glass is demonstrated. Bromine doping can be achieved with SiBr.sub.4 as a precursor. Bromine doping can occur during heating, consolidation or sintering of a porous silica glass body. Doping concentrations of bromine increase with increasing pressure of the doping precursor and can be modeled with a power law equation in which doping concentration is proportional to the square root of the pressure of the doping precursor. Bromine is an updopant in silica and the relative refractive index of silica increases approximately linearly with doping concentration. Bromine can be used as a dopant for optical fibers and can be incorporated in the core and/or cladding regions. Core doping concentrations of bromine are sufficient to permit use of undoped silica as an inner cladding material in fibers having a trench in the refractive index profile. Co-doping of silica glass with bromine and chlorine is also demonstrated.

One embodiment of the disclosure relates to a method of cleaning silica-based soot or an article made of silica-based soot, the method comprising the step of treating silica-based soot or the article made of silica-based soot with at least one of the following compounds: (i) a mixture of CO and Cl.sub.2 in a carrier gas such that the total concentration of CO and Cl.sub.2 in the mixture is greater than 10% (by volume, in carrier gas) and the ratio of CO:Cl.sub.2 is between 0.25 and 5; (ii) CCl.sub.4 in a carrier gas, such that concentration CCl.sub.4 is greater than 1% (by volume, in carrier gas). Preferably, the treatment by CCl.sub.4 is performed at temperatures between 600 C., and 850 C. Preferably, the treatment with the CO and Cl mixture is performed at temperatures between 900 C. and 1200 C. The carrier gas may be, for example, He, Ar, N.sub.2, or the combination thereof.

One aspect relates to a method for producing an optical blank from synthetic quartz glass by vitrifying and shaping a porous, cylindrical SiO.sub.2 soot body having a longitudinal axis, in a heating zone including a melt mold with bottom plate. The SiO.sub.2 soot body vitrified in the heating zone at a vitrification temperature so as to form a full cylindrical, completely vitrified, transparent quartz glass body. Subsequently, the vitrified quartz glass body is shaped by softening in the melt mold at a softening temperature so as to form a viscous quartz glass mass which partly fills the volume of the melt mold, and cooling the quartz glass mass and removal from the melt mold so as to form the optical blank. During shaping in the melt mold, the full cylindrical quartz glass body is brought into contact by way of controlled supply with a centering means of the bottom plate.

A heat treatment apparatus includes: a furnace core tube made of silica glass; a heater provided adjacent to the furnace core tube, the heater heating a heating region; and a moving mechanism supporting a porous glass base material and relatively moving the porous glass base material with respect to the heater in the furnace core tube in a state where the heating region is heated by the heater to make the porous glass base material pass through the heating region. The heat treatment apparatus includes a thin-walled part provided in a region adjacent to a portion located in the heating region in the furnace core tube, the thin-walled part having a thickness of glass less than that of the portion located in the heating region.

A glass body manufacturing apparatus includes: a first heating furnace including a furnace core tube accommodating the soot and a first heater, to supply a dehydration gas into the furnace core tube and heat the soot at a first treatment temperature lower than a softening point of the porous portion by the first heater; a second heating furnace including a structural body accommodating the soot and a second heater, to heat the soot at a second treatment temperature equal to or higher than the softening point by the second heater; and a conveyance container, connectable to each of the first and second heating furnaces while keeping airtightness with respect to the atmosphere, to accommodate and hold the soot, and convey the soot between the first and second heating furnaces.

A method for elongating a glass preform for an optical fiber is provided for producing a glass rod having a smaller diameter by elongating the glass preform having a large diameter, the method including: when the glass preform having a tapered transparent glass portion at one end of a straight body of the glass preform and a tapered portion including an opaque glass portion at another end is elongated, prior to the elongating, cutting a part of the tapered portion including the opaque glass portion, wherein a cut surface of the part is a lower end of the glass preform; and welding the cut surface of the tapered portion to a pulling dummy connected to a pulling mechanism in a elongating apparatus, wherein the cut surface is circular and has an outer diameter ranging from 135 mm to 160 mm.

This invention provides a manufacturing method for an optical fiber. In this invention, when the core layer loose body and the cladding layer loose body are deposited, the oxyhydrogen flame is used make a temperature of an interface between the core layer and the cladding layer rise, such that silicon dioxide at the interface appropriately contracts to form an isolation layer with a relatively high density. In addition, in this invention, a hollow glass tube is used as a target rod, and the hollow glass tube which is the target rod is directly connected with the core layer loose body. During the subsequent dehydration, not only a dehydration atmosphere penetrates from the outside to the inside of the cladding layer loose body, but also the dehydration atmosphere directly enters the core layer through the hollow glass tube.

A method of producing an optical fiber preform includes a silica glass body forming step of forming a silica glass body to be at least a portion of a core portion. The method includes an alkali-metal-doped silica glass body forming step of forming an alkali-metal-doped silica glass body doped with an alkali metal around the silica glass body such that the alkali-metal-doped silica glass body contacts the silica glass body. The method further includes a diffusing step of diffusing the alkali metal from the alkali-metal-doped silica glass body to the silica glass body by a heat treatment.

The optical fiber offered is capable of not only restraining the attenuation due to glass defects, but also reducing the increase of manufacturing cost. The optical fiber is made of silica glass and includes a core and a cladding. The cladding encloses the core and has a refractive index smaller than that of the core. When the core is divided into inner core and outer core at half of the radius of the core, the average chlorine concentration of the inner core is larger than that of the outer core. The core includes any of the alkali metal group.

The present disclosure provides a method for modification of surface of an initial optical fiber preform. The initial optical fiber preform is manufactured using at least one preform manufacturing process. The surface of the initial optical fiber preform is treated with 50-70 liters of chlorine per square meter of the surface of the initial optical fiber preform. The surface of the initial optical fiber preform is flame polished using a flame polishing module. The treatment of the surface of the initial optical fiber preform with chlorine and flame polishing of the surface of the initial optical fiber preform collectively converts the initial optical fiber preform into a modified optical fiber preform.