A method for preparing an amorphous metal oxide film is provided. The method comprises providing an aqueous composition comprising a metal fluorine compound; and contacting a substrate with the aqueous composition at a temperature of less than about 100° C. to obtain said amorphous metal oxide film on the substrate. An amorphous metal oxide film, and use of the amorphous metal oxide film in various applications are also provided.

A glass-ceramic article is provided that includes a surface passivation layer. The passivation layer is an oxide layer and has a thickness of greater than or equal to 20 nm to less than or equal to 200 nm and a RMS surface roughness of less than or equal to 3 nm. The surface passivation layer may be formed with a liquid phase deposition process. The glass-ceramic article may include an easy to clean layer disposed on the surface passivation layer, and the glass-ceramic article may be chemically strengthened. The glass-ceramic article may be used in a consumer electronic product.

A method for making a beam splitter with photocatalytic coating is disclosed. First, a TiO.sub.2—SiO.sub.2 sol, a SiO.sub.2 sol, and an anatase TiO.sub.2 preform sol are prepared. A glass substrate having two opposite surfaces is provided. The two opposite surfaces of the glass substrate is coated with the TiO.sub.2—SiO.sub.2 sol, the SiO.sub.2 sol, and the anatase TiO.sub.2 preform sol by dip-coating, thereby forming a coated glass substrate with a multi-layer optical coating on each of the two opposite surfaces. The multi-layer optical coating comprises a TiO.sub.2—SiO.sub.2 coating, a SiO.sub.2 coating, and an anatase TiO.sub.2 preform coating. The coated glass substrate is subjected to an anneal process. The coated glass substrate is cut, thereby forming the beam splitter with photocatalytic coating.

A method for preparing a microstructure on the surface of glass by titanium oxide nanoparticle-assisted infrared nanosecond laser, including the following steps: (1) dropwise applying a titanium oxide nanoparticle hydrogel onto the surface of a glass sample; (2) pressing another piece of glass on the surface of the hydrogel, so the hydrogel is evenly distributed between the two pieces of glass, and allowing the two pieces of glass to stand horizontally for a period of time to air-dry the hydrogel; (3) separating the two pieces of glass to obtain a glass with a uniform titanium oxide nanoparticle coating; (4) forming a microstructure using an infrared nanosecond laser with a wavelength of 1064 nm; and (5) performing after-treatment, including ultrasonically cleaning the sample with acetone, absolute ethanol and deionized water respectively for 10 min to remove titanium oxide nanoparticles attached to the surface, to obtain a glass sample with the microstructure.

A method for producing a glass-like protective layer on an optionally pre-coated metal or glass substrate. The method comprises: (a) mixing one or more defined silicon compounds with NaOH and KOH, (b) adding water to the mixture obtained in (a) to hydrolyze the silicon compound(s), (c) adding at least one defined compound of formula MY.sub.m,
where M is Pb, Ti, Zr, Al or B, to the hydrolyzed mixture obtained in (b), wherein the molar ratio M/Si is from 0.01/1 to 0.04/1, to obtain a coating sol, (d) applying the coating sol obtained in (c) to the substrate, and (e) thermal densification of the coating sol applied in d) at a temperature of from 300° C. to 500° C. to form the glass-like protective layer.

A process for the preparation of an antimicrobial coating solution is described. The process comprises the steps of: (i) mixing a chelating agent with titanium alkoxide and fluoroacetic acid; and (ii) adding an aqueous solution to the mixture from step (i). The antimicrobial coating described is visible light activated. The coating is applied to surfaces and then heat treated to form a transparent layer on the surface. This is particularly advantageous where the surface is glass.

According to one or more embodiments, a pharmaceutical package may include a glass container and a coating. The glass container may include a first surface and a second surface opposite the first surface. The first surface may be an outer surface of the glass container. The coating may be positioned over at least a portion of the first surface of the glass container. The coating may include one or more polyimide compositions and one or more metal oxide compositions. The one or more polyimide compositions and the one or more metal oxide compositions may be mixed in the coating.

A coated glass article and of a system and method for forming a coated glass article are provided. The process includes applying a first coating precursor material to the first surface of the glass article and supporting the glass article via a gas bearing. The process includes heating the glass article and the coating precursor material to above a glass transition temperature of the glass article while the glass article is supported by the gas bearing such that during heating, a property of the first coating precursor material changes forming a coating layer on the first surface of the glass article from the first precursor material. The high temperature and/or non-contact coating formation may form a coating layer with one or more new physical properties, such as a deep diffusion layer within the glass, and may form highly consistent coatings on multiple sides of the glass.

A glass filler of the present disclosure includes glass having a composition, the composition including iron oxide. For the content in mass % of the iron oxide in the composition, 0.005≤FeO≤0.30 and 0.01≤T-Fe.sub.2O.sub.3≤0.80 (T-Fe.sub.2O.sub.3 represents total iron oxide calculated as Fe.sub.2O.sub.3) are satisfied. For the iron oxide in the composition, Fe.sup.2+/(Fe.sup.2++Fe.sup.3+), which represents the proportion by mass of Fe.sup.2+ to total iron, is 0.15 or more and 1.00 or less. The glass filler of the present disclosure is a glass filler having a new composition including a coloring component, the glass filler having a high visible transmittance and a controlled color which can be, for example, within a range of colors different from those of conventional glass fillers that have a low visible transmittance.

A glass ceramic item, intended in particular for use with at least one light source and/or at least one heating element, includes at least one substrate, such as a plate, made of glass ceramic, and having at least one light region. The substrate is coated with respect to the region with a paint consisting of at least one silicone resin and pigment(s). The content of the pigment(s) are greater than or equal to 1% and less than 10% by weight of the paint. A method for producing such an item is also included.