A coated article includes a substrate, a functional layer over at least a portion of the substrate, and a protective coating over at least a portion of the functional layer, wherein an uppermost layer of the functional layer is a metal oxide layer, and wherein the protective coating comprises a metal nitride layer and a metal oxynitride layer that is disposed between and in contact with at least part of the metal nitride layer and the metal oxide layer of the functional layer.

A thin film on a surface of a solid substrate, including: a) spraying on the surface: a colloidal suspension including solid nanoparticles (or colloids) of an inorganic compound dispersed in a solvent to obtain a wet layer of the colloidal suspension on the surface; or a suspension including an inorganic compound in polymeric form in a solvent, to obtain a wet layer of the suspension of the inorganic compound in polymeric form on the surface; or a solution or suspension of an organic polymer in a solvent, to obtain a wet layer of the solution or suspension of the organic polymer on the surface; b) drying the wet layer; c) optionally, heat-treating the wet layer that has undergone the drying step, whereby the thin film is obtained; wherein: the solvent comprises at least 95% by weight of water, and the drying is carried out in a static atmosphere.

The present invention provides a glass article including a photocatalyst film 1 containing silicon oxide particles 6 and titanium oxide particles 5, and a glass sheet 2. Assuming that the photocatalyst film 1 has a film thickness T, 80% or more of the titanium oxide particles are localized in a region between a surface of the glass sheet 2 and a position spaced from the surface by 0.6 T toward a surface of the photocatalyst film 1 in a thickness direction of the photocatalyst film 1. The glass article has an increased transmittance provided by enhancing the reflection-reducing function of the photocatalyst film 1 while maintaining the film strength and photocatalytic function of the photocatalyst film 1.

A method for preparing a microstructure on the surface of glass by titanium oxide nanoparticle-assisted infrared nanosecond laser, including the following steps: (1) dropwise applying a titanium oxide nanoparticle hydrogel onto the surface of a glass sample; (2) pressing another piece of glass on the surface of the hydrogel, so the hydrogel is evenly distributed between the two pieces of glass, and allowing the two pieces of glass to stand horizontally for a period of time to air-dry the hydrogel; (3) separating the two pieces of glass to obtain a glass with a uniform titanium oxide nanoparticle coating; (4) forming a microstructure using an infrared nanosecond laser with a wavelength of 1064 nm; and (5) performing after-treatment, including ultrasonically cleaning the sample with acetone, absolute ethanol and deionized water respectively for 10 min to remove titanium oxide nanoparticles attached to the surface, to obtain a glass sample with the microstructure.

A coated glass substrate is disclosed as well as a method of making the coated glass substrate. The coated glass substrate contains a glass substrate and a coating containing a hybrid network comprising at least two oxides. The coating exhibits a coefficient of friction of less than 0. 12 when measured according to ASTM D7027. The coating exhibits a critical scratch load of at least about 10 kg as measured according to ASTM test C1624-05.

A glass filler of the present disclosure includes glass having a composition, the composition including iron oxide. For the content in mass % of the iron oxide in the composition, 0.005FeO0.30 and 0.01T-Fe.sub.2O.sub.30.80 (T-Fe.sub.2O.sub.3 represents total iron oxide calculated as Fe.sub.2O.sub.3) are satisfied. For the iron oxide in the composition, Fe.sup.2+/(Fe.sup.2++Fe.sup.3+), which represents the proportion by mass of Fe.sup.2+ to total iron, is 0.15 or more and 1.00 or less. The glass filler of the present disclosure is a glass filler having a new composition including a coloring component, the glass filler having a high visible transmittance and a controlled color which can be, for example, within a range of colors different from those of conventional glass fillers that have a low visible transmittance.

A process of forming a mixed metal oxide solid is provided. The process includes the steps of obtaining a precursor composition comprising at least two metal or metalloid-containing compounds, the metal or metalloid of the at least two compounds being different, one from the other; and allowing the at least two metal or metalloid-containing compounds of the precursor composition to at least partially react by hydrolysis and/or condensation. The at least two metal or metalloid-containing compounds may have different points of zero charge (PZC). Further material or articles comprising a substrate or material coated with or otherwise in physical connection to the mixed metal oxide solid formed according to the process are also provided.

A coated article includes a substrate, a functional layer over at least a portion of the substrate, and a protective coating over at least a portion of the functional layer, wherein an uppermost layer of the functional layer is a metal oxide layer, and wherein the protective coating comprises a metal nitride layer and a metal oxynitride layer that is disposed between and in contact with at least part of the metal nitride layer and the metal oxide layer of the functional layer.

A sol-gel method for forming durable, scratch-resistant coatings on glass substrates. Zirconia coatings, for example, are formed from a solution of zirconium oxychloride octahydrate in an organic, polar, aprotic solvent such as dimethylformamide. Annealed coatings, which optionally include an additive such as graphene, have a low coefficient of friction and can exhibit high hardness and hydrophobicity.

A low-reflection coated glass sheet of the present invention includes a glass sheet and a low-reflection coating. The low-reflection coating is formed on at least a portion of one principal surface of the glass sheet, and contains a binder containing silica as a main component, fine silica particles bound by the binder, and fine titania particles bound by the binder. For the low-reflection coated glass sheet, a transmittance gain is 1.7% or more. The low-reflection coating contains 25 mass % to 43 mass % of the silica which is the main component of the binder, 40 mass % to 64 mass % of the fine silica particles, and 10 mass % to 20 mass % of the fine titania particles, based on the total mass of the low-reflection coating. As such, the low-reflection coated glass sheet of the present invention has high abrasion resistance and is capable of exhibiting photocatalytic properties and hydrophilicity when irradiated with light.